川西亚高山三个森林群落的湿林冠蒸发速率

于3个假说和林冠上方2m处的气象变量，采用Penman-Monteith组合模型估算了一个生长季节内川西亚高山林区分别以云杉(SF)、冷杉(FF)和白桦(BF)为优势树种的3个林分的湿林冠蒸发速率(Er)。研究结果表明，SF、FF和BF的湿林冠蒸发量(E)分别为44．51mm、88．51mm和57．8mm，分别占总降雨量的9．2％、16．6％和10．2％。与SF和BF相比，FF具有最高的月平均Er和蒸发比例。SF、FF和BF的平均Er分别为0．097mm／h(变化范围：0．028-0．487mm／h)、0．242mm／h(变化范围：0．068～0．711mm／h)和0．149mm／h(0．060～0．576mm／h)。最高和最低的月平均Er分别在6月(SF、FF和BF分别为0．120mm／h、0．317mm／h和0．169mm／h)和10月(SF、FF和BF分别为0．083mm／h、0．187mm／h和0．101mm／h)。8：00至16：00期间的平均点Er显著高于0：00至8：00以及16：00至0：00期间的平均Er。Er显著的日变化和月变化主要归因于林冠上方的太阳辐射、空气温度和相对湿度的变化。     

崇明岛东滩湿地芦苇光合作用对土壤水盐因子的响应

2015年3~10月,在崇明岛东滩湿地设置7块采样地,以不同水盐条件下生长的芦苇(Phragmites australis)为材料,应用便携式光合系统分析仪(Li-6400),对芦苇的光响应特征进行实地测定,探讨芦苇光合过程对干旱和盐胁迫的响应机理。结果表明:1各月采样日的水位与土壤电导率显著负相关(n=420,p0.01),适当增加土壤水位,有利于降低土壤电导率,从而缓解植物盐胁迫伤害;28月21日的芦苇叶片净光合速率、蒸腾速率和气孔导度与水位显著正相关(n=42,p0.01),而与土壤电导率显著负相关(n=42,p0.01);胞间CO2浓度与水位和土壤电导率不相关。当水位高于-50 cm,净光合速率随着水位下降而降低,非气孔因素可能是净光合速率下降的主要原因;当水位低于-50 cm时,土壤电导率高于10 m S/cm,叶片蒸腾速率快速降低,水分利用效率不断提高,芦苇叶片以较低的净光合速率来适应干旱胁迫和盐胁迫;芦苇叶片通过降低最大净光合速率、暗呼吸速率、光补偿点和光饱和点等光合生理特征来适应干旱胁迫和盐胁迫;芦苇叶片净光合速率和最大净光合速率对土壤水盐因子具有高度相关性,可以作为土壤水盐胁迫程度的反应指标。因此,在芦苇快速生长阶段,合理调控水位,对芦苇光合作用具有重要意义。     

EWT-Elman组合模型短期电离层TEC预报

针对电离层总电子含量(TEC)非线性、高噪声的特点,建立基于经验小波变换(EWT)和Elman神经网络的短期电离层组合预报模型。运用该模型对不同地磁环境的电离层TEC时间序列进行建模预报,结果表明,EWT-Elman组合模型可反映电离层TEC的变化特征,地磁平静期预测平均相对精度为93%,均方根误差为1.04 TECu;地磁扰动期预测平均相对精度为92.4%,均方根误差为2.18 TECu。单一Elman模型、EMD-Elman组合模型以及EWT-BP组合模型在地磁平静期平均相对精度最高为90.7%,均方根误差最小为1.33 TECu;地磁扰动期平均相对精度最高为90.7%,均方根误差最小为2.57 TECu。对比其他模型,本文方法预测效果最优。     

冀北侏罗系上统火山岩中宇宙尘的发现及其地质意义

在冀北丰宁、沽源、赤城一带的上侏罗统火山岩中发现有不同形态的铁质及玻璃质微球粒。经电镜扫描及外貌结构构造的鉴定，显示有熔融、碰撞、逸气、旋纹、冷疑、收缩等特征；经电子探针及Ｘ射线粉晶衍射分析，认为是宇宙尘。对其进行研究不仅有重要的地质意义，而且有找矿意义。     

Precise and Accurate In Situ Determination of Lead Isotope Ratios in NIST,USGS, MPI‐DING and CGSG Glass Reference Materials using Femtosecond Laser Ablation MC‐ICP‐MS

Lead isotope ratio data were obtained with good precision and accuracy using a 266 nm femtosecond laser ablation (fLA) system connected to a multi‐collector ICP‐MS (MC‐ICP‐MS) and through careful control of analytical procedures. The mass fractionation coefficient induced by 266 nm femtosecond laser ablation was approximately 28% lower than that by 193 nm excimer laser ablation (eLA) with helium carrier gas. The exponential law correction method for Tl normalisation with optimum adjusted Tl ratio was utilised to obtain Pb isotopic data with good precision and accuracy. The Pb isotopic ratios of the glass reference materials NIST SRM 610, 612, 614; USGS BHVO‐2G, BCR‐2G, GSD‐1G, BIR‐1G; and MPI‐DING GOR132‐G, KL2‐G, T1‐G, StHs60/80‐G, ATHO‐G and ML3B‐G were determined using fLA‐MC‐ICP‐MS. The measured Pb isotopic ratios were in good agreement with the reference or published values within 2s measurement uncertainties. We also present the first high‐precision Pb isotopic data for GSE‐1G, GSC‐1G, GSA‐1G and CGSG‐1, CGSG‐2, CGSG‐4 and CGSG‐5 glass reference materials obtained using the femtosecond laser ablation MC‐ICP‐MS analysis technique.     

大青山地区2.5 Ga紫苏花岗岩——对深熔石榴花岗岩成因模式的启示

华北克拉通北缘西部陆块早前寒武纪基底分布广泛,现有的研究普遍认为经历 2.5 Ga,2.45~2.37 Ga,1.95 Ga和1.85 Ga变质热事件影响。华北克拉通北缘阴山陆块中2.5 Ga的紫苏花岗岩研究已经成为了揭示华北克拉通北缘早前寒武纪构造演化的一个热点,但孔兹岩带中却鲜少有新太古代晚期构造热事件的相关报道。近年来,相继从大青山地区的孔兹岩带石榴黑云母片麻岩中分辨出一期具有2.45~2.37 Ga变质锆石年龄的大青山表壳岩,同时出露与其成因关系密切的深熔石榴花岗岩,但其深熔成因的模式存在争议。本文对大青山地区新发现的新太古代晚期紫苏花岗岩、石榴花岗岩及其围岩的野外空间产出关系和锆石年代学进行对比分析,为探究深熔石榴花岗岩成因模式提供重要的启示。     

复数域总体最小二乘平差

在复数域最小二乘的基础上提出了复数域总体最小二乘平差方法,推导了复数域总体最小二乘和复数混合总体最小二乘的相关公式。通过算例比较分析了复数观测值的残差的模的平方和最小(平差准则1)下及残差的实部和虚部的平方和分别最小(平差准则2)下的复数最小二乘、复数观测值和系数矩阵的残差的模的平方和最小(平差准则3)下及残差的实部和虚部的平方和分别最小(平差准则4)下的复数总体最小二乘方法的优劣。试验结果表明:平差准则1下复数最小二乘较平差准则2下得到的结果更加合理,平差准则3下复数总体最小二乘较平差准则4下得到的结果更为准确;当顾及系数矩阵误差时,平差准则3下复数总体最小二乘要优于平差准则1下复数最小二乘。     

Standard-sample bracketing calibration method combined with Mg as an internal standard for silicon isotopic compositions using multi-collector inductively coupled plasma mass spectrometry

Silicon isotope analysis traditionally uses a standard-sample bracketing (SSB) method that relies upon greater instrument stability than can be consistently expected. The following proposed method reduces the level of instrumental stability required for the analysis process and provides a valid solution for high-precision and accurate studies of Si isotopic compositions. Rock samples were dissolved by using alkali fusion and acidification. Silicon isotopes were purified with an ion exchange resin. Interfering peaks for isotopes were separated by using a Nu Plasma 1700 multi-collector inductively coupled plasma mass spectrometry (MS) system in high-resolution mode (M/ΔM > 8000 RP). Two magnesium isotopes (²⁵Mg and ²⁶Mg) and three silicon isotopes (²⁸Si, ²⁹Si, and ³⁰Si) were analyzed in the same data collection cycle. Mg isotopes were used as an internal standard to calibrate the mass discrimination effects in MS analysis of Si isotopes in combination with the SSB method in order to reduce the effects of MS interference and instrumental mass discrimination on the accuracy of measurements. The conventional SSB method without the Mg internal standard and the proposed SSB method with Mg calibration delivered consistent results within two standard deviations. When Mg was used as an internal standard for calibration, the analysis precision was better than 0.05 ‰ amu.     

Natural Clinopyroxene Reference Materials for In Situ Microanalysis

Two clinopyroxene megacrysts, DMP-2 and DMP-3, were collected from Cenozoic alkali basalts in the Hannuoba region of China. They were characterised for major and trace element compositions for in situ microanalysis. EPMA and LA-ICP-MS analyses indicate homogeneity in the element mass fractions in both clinopyroxene samples. Bulk analyses using various techniques (XRF, ICP-OES and solution ICP-MS) also reveal good consistency in their major and trace element data. They, thus, can be used as potential reference materials for elemental in situ microanalysis. Accordingly, element mass fractions are recommended for thirty-two elements.     

基于AHP-熵-TOPSIS对极轨气象卫星应用系统健康程度评价指标体系

以实现对极轨气象卫星应用系统健康程度进行综合评价为目的,提出结合主观分析的层次分析法(Analytic Hierarchy Process,AHP)和客观分析的熵权法(Entropy Weight,EW)确定待评价系统指标值的综合权重,再采用逼近理想解排序法(Technique for Order Preference by Similarity to an Ideal Solution,TOPSIS)对系统的指标进行多角度评价排序来作为最终评价结果。本文根据连续5个月3颗极轨气象卫星在实际业务系统运行中异常指标样本进行实证分析。结果表明该方法较为全面考虑了影响应用系统的多种因素,避免了单一判据的局限性,并对各指标的重要性进行综合对比分析,使得评价结果更科学准确,可以作为构建极轨气象卫星应用系统健康程度评价指标体系的一种方法。