常压法合成Methomyl的研究

提出一种合成Methomyl的改良法。该方法的特点是反应可在常压下进行。对常压反应的优宜条件作了系统研究,并讨论了反应机理。     

δ13c-δ18O Covariance:An Effective Indicator of Hydrological Closure for Lakes?

The correlation between the Δ13c and 18O in primary carbonates is affected by several factors such as hydrological balance, total CO2 concentrations, climatic condition and lake productivity.The influence of these factors on the Δ13c-δ18 correlation may be different on different time scales. In this paper, two different-type lakes in southwestern China, Lake Erhal and Lake Chenghai, are selected to investigate the influence of climatic pattern on the Δ13c-Δ18o correlation and to evaluate the reliability of the Δ13c-Δ18o covariance as an indicator of hydrological closure. The results show that there exists good correlation between the Δ13c and Δ18o in Lake Erhai (overflowing open lake) and inLake Chenghal (closed lake). This suggests that the Δ13c-Δ18o covariance may be not an effective indicator of hydrological closure for lakes, especially on short time scales. On the one hand, a hydrologically open lake may display covariant Δ13c and δ18 as a result of climatic influence. The particular alternate warm-dry and cold-wet climatic pattern in southwestern China may be the principal cause of the Δ13c-δ18 covariance in Lake Erhai and Lake Chenghal. On the other hand, a hydrologically closed lake unnecessarily displays covariant trends between Δ13c and δ18 because of the buffering effect of high CO2 concentration on the Δ13c shift in hyper-alkaline lakes. We should be the buffering feeect of high CO2 concentration on the 13Cshift in hyper-alkaline lakes.We should be prudent when we use the covariance between 13C and 18O to judge the hydrological closure of lake.     

飞机下投探空在台风探测中的应用

在海洋探测方面,利用飞机进行下投探空拥有巨大的潜力去弥补全球高空探测网的空白。台风形成后,飞机飞入台风中心或绕台风飞行,下投配有全球卫星定位(GPS)装置的"探空仪",探空仪上安装有温度、气压、湿度传感器,通过GPS定位测风,对台风实施立体观测。多年来,飞机下投探空能够充分掌握台风的整体气象要素分布结构,从而提高对台风强度和移动路径等预报的准确性,飞机下投探空在国际上已经从科学试验转变成业务应用,并且形成新型的探测技术——目标观测。本文主要总结了国际上利用飞机搭载下投式探空仪进行台风探测的发展历程,为我国开展下投探空,特别是台风监测提供可借鉴的经验。     

New Damage-locating Method for Bridges Subjected to a Moving Load

A new damage-locating method for bridges subjected to a moving load is presented, and a new ‘moving load damage-locating indicator＇ （MLDI） is introduced. A vehicle is modeled as a moving load, the bridge is simplified as an Euler-Bernoulli beam, and the damage is simulated by a reduction of stiffness properties of the elements. The curvature and MLDI values at each node of the baseline model （undamaged） and the damage model are computed respectively. Then the damage or damages can be located from a sudden change of the MLDI value. The feasibility and effectiveness of the proposed method are validated by numerical simulation. The results indicate that the method is effective, being able to not only locate a single damage accurately, but also locate multiple damages in simply-supported bridges, including multiple damages in continuous bridges. The results also indicate that the MLDI can accurately locate damages under 5% measurement noise.     

Distributions of Picophytoplankton and Phytoplankton Pigments Along a Salinity Gradient in the Changjiang River Estuary,China

We investigated the abundance of different picophytoplankton groups and the phytoplankton pigment ratio in relation to environmental factors such as nutrients and suspended solids along a salinity gradient in the Changjiang River Estuary.The average numbers of Synechococcus spp.（Syn） and picoeukaryotes （Euk） were （2.7 ±5.1）×l03 and （1.1±1.4）×l03 cells mL-1,respectively.Prochlorococcus spp.（Pro） was only found in the high-salinity brackish water with the concentration of 3.0× 10^3 cells mL-1.Syn and Euk numbers both tended to increase offshore and Syn showed a larger variation in cell abundance than Euk.The contribution of picophytoplankton to total phytoplankton biomass increased with increasing salinity and decreasing nutrient concentrations from the estuary to the open ocean.The response of different picophytoplankton groups to environmental variables was different.Water temperature was more important in its control over Euk than over Syn,while nutrients were more important in their influence over Syn than over Euk.Phytoplankton pigment ratios were different in the three different ecological zones along the salinity gradient （i.e.,freshwater zone with 0-5 range,fresh and saline water mixing zone with 5-20 range,and high-salinity brackish water zone with 20-32 range）,where three different phytoplankton communities were discovered,suggesting that phytoplankton pigment ratios can be considered as a complementary indicator of phytoplankton community structure in the Changjiang River Estuary.     

Damage localization of marine risers using time series of vibration signals

Based on dynamic response signals a damage detection algorithm is developed for marine risers. Damage detection methods based on numerous modal properties have encountered issues in the researches in offshore oil community. For example, significant increase in structure mass due to marine plant/animal growth and changes in modal properties by equipment noise are not the result of damage for riser structures. In an attempt to eliminate the need to determine modal parameters, a data-based method is developed. The implementation of the method requires that vibration data are first standardized to remove the influence of different loading conditions and the autoregressive moving average (ARMA) model is used to fit vibration response signals. In addition, a damage feature factor is introduced based on the autoregressive (AR) parameters. After that, the Euclidean distance between ARMA models is subtracted as a damage indicator for damage detection and localization and a top tensioned riser simulation model with different damage scenarios is analyzed using the proposed method with dynamic acceleration responses of a marine riser as sensor data. Finally, the influence of measured noise is analyzed. According to the damage localization results, the proposed method provides accurate damage locations of risers and is robust to overcome noise effect.     

长江中华绒螯蟹的资源与养殖现状及其种质保护

根据中华绒螯蟹的资源及其养殖现状,分析了我国目前各水系河蟹的种质变异及其河蟹幼蟹培育和成蟹养殖中存在的问题,针对中华绒螯蟹 种质保护的要求,就防止河蟹幼蟹性早熟及和蟹养殖的遗传污染与种质混杂等问题,提出了对长江河蟹品质保持的初步设想。     

就业视域下测绘类专业多层次人才培养模式探讨——以中国矿业大学为例

人才作为学科的核心要素,直接检验学科建设效果。本文通过分析近7年来测绘类专业就业数据发现,其就业率都在97%以上,形成了升学出国、测绘类民营企业、国有企业就业“三分天下”的局面;就业地区主要集中在东部沿海地区、北部沿海地区和长江中游地区。测绘类专业发展面临国家战略、能源革命、高教改革、科技发展、国际合作等新形势和机遇,提出了4类分层的人才结构培养方向和能力目标,始终坚持打造矿业特色测绘类专业世界标杆,从而提升了人才培养水平的对策和措施。     

Effects of river damming on biogenic silica turnover: implications for biogeochemical carbon and nutrient cycles

Rivers link terrestrial ecosystems and marine ecosystems, and they transport large amounts of substances into oceans each year, including several forms of silicon (Si), carbon (C), and other nutrients. However, river damming affects the water flow and biogeochemical cycles of Si, C, and other nutrients through biogeochemical interacting processes. In this review, we first summarize the current understanding of the effects of river damming on the processes of biogeochemical Si cycle, especially the source, composition, and recycling process of biogenic silica (BSi). Then, we introduce dam impacts on the cycles of C and some other nutrients. Dissolved silicon in rivers is mainly released from phytolith dissolution and silicate weathering. BSi in suspended matter or sediments in most rivers mainly consists of phytoliths and mainly originates from soil erosion. However, diatom growth and deposition in many reservoirs formed by river interception may significantly increase the contribution of diatom Si to total BSi, and thus significantly influence the biogeochemical Si, C, and nutrient cycles. Yet the turnover of phytoliths and diatoms in different rivers formed by river damming is still poorly quantified. Thus, they should be further investigated to enhance our understanding about the effects of river damming on global biogeochemical Si, C and nutrient cycles.     

Nitrous oxide (N<Subscript>2</Subscript>O) emissions from a mesotrophic reservoir on the Wujiang River,southwest China

Aquatic ecosystems have been identified as a globally significant source of nitrous oxide (N₂O) due to continuous active nitrogen involvement, but the processes and influencing factors that control N₂O production are still poorly understood, especially in reservoirs. For that, monthly N₂O variations were monitored in Dongfeng reservoir (DFR) with a mesotrophic condition. The dissolved N₂O concentration in DFR displayed a distinct spatial–temporal pattern but lower than that in the eutrophic reservoirs. During the whole sampling year, N₂O saturation ranging from 144% to 640%, indicating that reservoir acted as source of atmospheric N₂O. N₂O production is induced by the introduction of nitrogen (NO₃ ^?, NH₄ ⁺) in mesotrophic reservoirs, and is also affected by oxygen level and water temperature. Nitrification was the predominate process for N₂O production in DFR due to well-oxygenated longitudinal water layers. Mean values of estimated N₂O flux from the air–water interface averaged 0.19 µmol m^?2 h^?1 with a range of 0.01–0.61 µmol m^?2 h^?1. DFR exhibited less N₂O emission flux than that reported in a nearby eutrophic reservoir, but still acted as a moderate N₂O source compared with other reservoirs and lakes worldwide. Annual emissions from the water–air interface of DFR were estimated to be 0.32 × 10⁵ mol N–N₂O, while N₂O degassing from releasing water behind the dam during power generation was nearly five times greater. Hence, N₂O degassing behind the dam should be taken into account for estimation of N₂O emissions from artificial reservoirs, an omission that historically has probably resulted in underestimates. IPCC methodology should consider more specifically N₂O emission estimation in aquatic ecosystems, especially in reservoirs, the default EF5 model will lead to an overestimation.