Surface complexation modeling of Cu(II) adsorption on mixtures of hydrous ferric oxide and kaolinite

Background  

The application of surface complexation models (SCMs) to natural sediments and soils is hindered by a lack of consistent models and data for large suites of metals and minerals of interest. Furthermore, the surface complexation approach has mostly been developed and tested for single solid systems. Few studies have extended the SCM approach to systems containing multiple solids.     

Anisotropy: High energy cosmic rays and the thermal background radiation

The motion of a large (100 Mpc radius) volume of local matter with respect to the frame in which the thermal cosmic background radiation (CBR) appears isotropic is shown to produce a contribution to anisotropy in the arrival directions of the highest energy (>10¹⁹ eV) cosmic rays. The magnitude of the effect predicted is 1%, below that currently observed and below the sensitivity of present experiments.     

Site Effects Study in the Serravalle Village (NE Italy) by Means of Spectral Ratios Analyses Relatively to Multiple Reference Sites

The area of Serravalle, sited in the northern part of the town of Vittorio Veneto (TV), NE Italy, has been the target of a seismic microzonation campaign. 10 seismic stations have been deployed for a 7 months period to record in continuous mode. Three stations were installed on bedrock outcrops and seven on sedimentary sites with variable cover thickness. Spectral analyses have been performed on the collected data-set using the Generalized Inversion Technique (GIT, e.g. Andrews, 1986). In particular, spectral ratios have been calculated for each station relatively to the average of the three reference, bedrock sites. The spectral ratios provide quantitative estimates of the seismic motion amplifications which occur in each of the monitored sites. Two sites show high values of amplification, 5 times larger than signal amplitude at the reference sites, in correspondence of well discernible peak frequencies of 5 Hz. Results for the other stations show smaller amounts of site amplification spreading over a broad range of frequencies. Sites where the highest amplifications were recorded all lie on the left bank of the Meschio River and in areas farther away from its outlet into the plain correlating with the presence of thick layers of Quaternary deposits.     

On the Intensity Virtual Area Characterization in the Intensity Distribution Modelling by Macroseismic Planes

A procedure is proposed for the reconfiguration of the macroseismic planes relative to earthquakes that, being characterized by a reduced number of points of observed intensity due to a lack of information, or having the epicenter very close to the coastline, are characterized by an incomplete distribution of observed intensity levels. The design of a plurality of virtual areas, through which a distribution of intensity consistent with an anisotropic model of attenuation is depicted, allows a reliable determination of macroseismic parameters of the same seismic event.     

Macroseismic Intensity Modelling of Earthquakes in Southern Spain: Attenuation and Tectonic Implications

A modelling of the observed macroseismic intensity of historical and instrumental earthquakes in southern Spain is proposed, with the aim of determining the macroseismic parameters for seismic hazard evaluation in a region in which the characterization of intensity distribution of seismic events shows different levels of difficulty referable to the complex faults system of the area in study. The adopted procedure allows an analytical determination of epicenters and principal attenuation directions of earthquakes with a double level of verification with reference to the maximum shaking area and structural lineaments of the region, respectively. The analyses, carried out on a suitable number of events, highlight, therefore, some elements for a preliminary characterization of a seismic zonation on the basis of the consistency between seismic intensity distribution of earthquakes and corresponding structural framework.     

Gravimetric and magnetic fabric study of the Sintra Igneous complex: laccolith-plug emplacement in the Western Iberian passive margin

International Journal of Earth Sciences - The geometry and emplacement of the ~ 96 km2, Late Cretaceous Sintra Igneous complex (SIC, ca. 80 Ma) into the West Iberian passive...     

Late Pleistocene and Holocene Afromontane vegetation and headwater wetland dynamics within the Eastern Mau Forest,Kenya

The Mau Forest Complex is Kenya's largest fragment of Afromontane forest, providing critical ecosystem services, and has been subject to intense land use changes since colonial times. It forms the upper catchment of rivers that drain into major drainage networks, thus supporting the livelihoods of millions of Kenyans and providing important wildlife areas. We present the results of a sedimentological and palynological analysis of a Late Pleistocene–Holocene sediment record of Afromontane forest change from Nyabuiyabui wetland in the Eastern Mau Forest, a highland region that has received limited geological characterization and palaeoecological study. Sedimentology, pollen, charcoal, X-ray fluorescence and radiocarbon data record environmental and ecosystem change over the last ~16 000 cal a bp. The pollen record suggests Afromontane forests characterized the end of the Late Pleistocene to the Holocene with dominant taxa changing from Apodytes, Celtis, Dracaena, Hagenia and Podocarpus to Cordia, Croton, Ficus, Juniperus and Olea. The Late Holocene is characterized by a more open Afromontane forest with increased grass and herbaceous cover. Continuous Poaceae, Cyperaceae and Juncaceae vegetation currently cover the wetland and the water level has been decreasing over the recent past. Intensive agroforestry since the 1920s has reduced Afromontane forest cover as introduced taxa have increased (Pinus, Cupressus and Eucalyptus).     

Reproductive biology of Parazoanthus axinellae (Schmidt, 1862) and Savalia savaglia (Bertoloni, 1819) (Cnidaria,Zoantharia) from the NW Mediterranean coast

Despite the wide distribution of zoanthids, little is known about their pattern of reproduction. Here we investigate the reproductive biology of two Mediterranean species, the common Parazoanthus axinellae (Schmidt) and the rare Savalia savaglia (Bertoloni). For both species, samples were collected during an annual cycle, from January to December 2005, in the Western Mediterranean (Ligurian Sea, Italy). Both species are gonochoric. In P. axinellae the sex‐ratio (n colonies = 30) showed a slight predominance of male colonies (M/F = 1.35), whereas in the population of S. savaglia (n colonies = 15) a predominance of females was found (M/F = 0.3). In P. axinellae the first gametocytes were visible in March, whereas in S. savaglia they became visible in May. Both species reproduce at the end of autumn when seawater temperature begins to decrease. Parazoanthus axinellae (10 m depth) spawns eggs and sperms in November, whereas S. savaglia (67 m depth) spawns in December. In P. axinellae sexes were segregated on a rocky wall, with males occurring deeper, whereas male and female colonies of S. savaglia were irregularly dispersed in the population. The maximum number of oocytes differed between the species, being higher in P. axinellae than in S. savaglia.