The history and impact of air pollution at Čertovo Lake,southwestern Czech Republic

This multi-disciplinary investigation documents the longterm effects of atmospheric pollution of metals and acids on a geologically sensitive catchment in the umava Mountains, southwestern Czech Republic, a region with a long history of human disturbance. A 30 cm long sediment core (I) from ertovo Lake was analyzed for natural and artifical radionuclides, metals, diatoms, chrysophytes, and pollen in sediments accumulated during the last 200 years. A second core (II), extending to 95 cm, included sediment judged to be free of atmospheric deposition of pollutants associated with the Industrial Revolution. Chronostratigraphic markers include several changes in the pollen assemblages corresponding to well-documented changes in land-use, and distinct distributions of ¹³⁷Cs, ¹³⁴Cs and ²⁴¹Am from weapons testing and the 1986 nuclear accident at Chernobyl, Russia. These markers corroborate the ²¹⁰Pb dating and, together, produce a reliable chronology extending back nearly to 1800 A.D.Stratigraphic profiles of Cu, Pb, and Zn in Core I are unlike any previously reported in the literature. Concentrations of Cu, Pb, and Zn remain generally above 100, 400, and 200 g g^-1, respectively, for the 200 years represented by Core I. These values are unusually high for sediments from a watershed with no known heavy-metal ore bodies. Accumulation rates for Cu, Pb, and Zn, which include both atmospheric and watershed contributions, are also high (ca 1, > 1 and > 1 g cm^-2 yr^-1, respectively) for the same period, although the anthropogenic contribution of Zn rose from nearly zero at 1800 A.D. The Cu and Pb accumulation rates rose dramatically about 1640 A.D.Accumulation rates of anthropogenically-derived Be, a relatively abundant element in the soft coals of the region, are also elevated by about 0.01 g cm^-2 yr^-1 in sediments of this period. Vanadium accumulation rates increased only since 1980 A.D., presumably along with increased consumption of oil.Diatom assemblages illustrate that the lake was acidic (pH between 4.5 and 5) through at least the past 200 years. The pH declined significantly (from ca 5 to 4) between 1960 and 1985 with a slight increase to 4.5 in the last few years. Recent diatom and chrysophyte assemblages suggest high trace metal concentrations, consistent with the present lake-water chemistry.     

Numerical modelling of desiccation cracking

The ability to model and predict the formation of desiccation cracks is potentially beneficial in many applications such as clay liner design, earth dam construction, and crop science, etc. However, most studies have focused on statistical analysis of crack patterns and qualitative study of contributing factors to crack development rather than prediction. Because it is exceedingly difficult to capture the nonlinear processes during desiccation in analytical modelling, most such models handle crack formation without considering variation of material properties with time, and are unattractive to use in realistic modelling. The data obtained from laboratory experiments on clay soil desiccating in moulds were used as a basis to develop a more refined model of desiccation cracking. In this study, the properties, such as matric suction, stiffness and tensile strength of soil, and base adhesion, could be expressed approximately as functions of moisture content. The initial conditions and the development of suction due to desiccation and the varying material properties were inputted to UDEC, a distinct element code, using its internal programming language FISH. The model was able to capture some essential physical aspects of crack evolution in soil contained in moulds with varying lengths, heights, and materials of construction. Extension of this methodology is potentially beneficial not only for modelling desiccation cracking in clay, but also in other systems with evolving material properties such as concrete structures and road pavements. Copyright © 2010 John Wiley & Sons, Ltd.     

Indices based assessment of built-up density and urban expansion of fast growing Surat city using multi-temporal Landsat data sets

GeoJournal - The population growth in urban areas leads to the expansion of built-up area which leads to a number of serious problems like environmental pollution, destruction of urban ecology,...     

Paleolimnological reconstructions of Rouyn-Noranda lakes within the zone of influence of the Horne Smelter,Québec,Canada

Diatoms were identified and enumerated from a surface sediment calibration set of 50 lakes in northwestern Québec. The relationship between species composition and environmental variables was examined using canonical correspondence analysis (CCA). Forward selection and Monte Carlo permutation tests in CCA indicated that diatom species distributions in the data set are most strongly correlated to lakewater pH. A strong (r ² _boot = 0.83) weighted averaging calibration model, that includes bootstrapped error estimates, was developed for inferring past lakewater pH. Using this model, temporal changes in pH were reconstructed for two kettle lakes, Lac de la Pépinière and Lac Perron. Based on limnological data, both the study lakes were expected to have recently acidified due to increased acidic precipitation and increases in anthropogenic metal loading. However, our long-term pH inference data indicate that these lakes were naturally acidic during pre-industrial times. Nonetheless, the rate of acidification, particularly in Lac de la Pépinière, has accelerated in the last ∼75 years. These long-term pH records developed for the dilute lakes in northwestern Québec suggest that the region has received increased atmospheric pollutants from the nearby Horne smelter in Rouyn-Noranda. The pH inference profiles are markedly different from many other paleolimnological studies in acid-sensitive regions of Canada that have become acidic primarily as a result of industrial activities. Electronic supplementary material The online version of this article (doi: ) contains supplementary material, which is available to authorized users.     

Photocatalytic Activity of Combustion Synthesized Nanocrystalline CeAlO3

The photocatalytic activity of combustion synthesized nanocrystalline CeAlO₃ was determined for the degradation of four anionic and four cationic dyes. The perovskite oxide showed high‐photocatalytic activity and a complete degradation of all the dyes was possible within 2 h. The photocatalytic activity of the compound was comparable with the activity of the commercial Degussa P‐25 TiO₂ catalyst. The degradation of dyes was found to follow first order kinetics and the first order degradation rate constants were determined.     

Abundance analysis of the long period southern cepheid RZ Vel

The long period classical cepheid RZ Vel (HD 73502) is known to be a member of an OB association, Vel OB1 in Vela, and a high metallicity is ascribed to it by the photometric work of Eggen (1982). We have done an abundance analysis for this long period (P = 20.4 days) and hence young (age ≈ 1.80×10⁷ yr) classical cepheid using high resolution CCD spectra with good S/N ratio. We have used a detailed model atmosphere method to derive the abundances of the light elements C, O, A1, S and of many Fe-peak elements and a few s-process elements. Our present work indicates near solar abundance for most of the elements for RZ Vel and hence we do not confirm the high metallicity derived photometrically by Eggen (1982) for this star     

中国典型等降水量线年代际空间演变

基于1960-2013年中国573个气象站的月降水量数据,选用普通克里金插值法生成典型等降水量线(200、400,800 mm),从等降水量线移动距离和移动趋势的角度分析了中国近54年典型等降水量线的时空演变特征。结果表明:(1) 200、400,800 mm等降水量线近54年的空间分布大致呈东北-西南走向,且从西北到东南有序排列。(2) 200 mm等降水量线在宁夏平原和西藏中西部波动强烈,且均有向东和向南偏移趋势。200 mm等降水量线在宁夏平原20世纪70、80年代、21世纪初东移,20世纪90年代、21世纪10年代初西移。西藏中西部自20世纪80年代起200 mm等降水量线有西移和北移态势,新疆北部200 mm等降水量线范围不断扩大。(3) 400 mm等降水量线在华北中东部波动强烈,20世纪70年代、21世纪00年代东移,20世纪80、90年代和21世纪10年代初西移,且整体有向东和向南的偏移趋势,但年代际波动大。(4) 800 mm等降水量线在秦岭-淮河一线波动强烈,20世纪80年代、21世纪00年代北移,20世纪70、90年代、21世纪10年代初南移,且纬度降低趋势较明显。     

The synthesis of26Al during combined hydrogen and helium-burning reactions

We have studied the synthesis of²⁶Al during combined hydrogen and helium-burning processes in high temperature and density conditions. The possible sites for these processes are believed to be the neutron star surfaces where the density ranges from =10⁴–10⁷ g cm^–3 and temperature range from 10⁸–8×10⁸ K. The screening effect which leads to an enhancement of nuclear reaction rates is taken into account whenever necessary. A detailed calculation of the abundances of²⁶Al and²⁷Al isotopes is presented here. Finite amounts of²⁶Al is found to be produced atT=2×10⁸ K and =10⁸ g cm^–3 due to these combined reactions. This situation is likely to be realized during the -ray burst events on neutron star surface. The amount of material processed in the burst sources is very little compared to the amount of material processed in Novae or Supernovae. Thus it is suggested that rather than contributing to the overall amount of²⁶Al, -ray bursts are likely to contribute more significantly to the inhomogeneity of²⁶Al distribution in interstellar medium.     

Prediction of Anopheles minimus habitat in India—a tool for malaria management

This paper reports research to predict the distribution of An. minimus, a malaria vector in forest fringe areas using GIS to support precision surveys for malaria control. Because An. minimus is a forest‐associated species, generalized thematic maps (1:6?000?000) of forest cover, soil type, altitude, rainfall and temperature were used. Digitization, overlaying, integration and analysis of thematic maps were done using Arc/Info 8.1 NT and Arc/View 3.2 (GIS, ESRI) software. GIS delineated favourable areas for An. minimus where the species is likely to be found, and precision surveys can be conducted. Precision field surveys in selected locations of favourable/non‐favourable areas were carried out. The species could be found in all locations designated as a favourable area and was absent in non‐favourable areas. In two districts, one where the species is reported to have disappeared in the early 1950s and the other where it was not reported in earlier surveys, GIS helped in precision surveys, and An. minimus was found. The technique can quickly cover vast and inaccessible areas and is easy to duplicate in other parts of the world to assist cost‐effective control of malaria. It can also delineate areas favourable for any species of flora and fauna to help precision surveys.     

Heavy metals contamination and assessment in gas station dust of Xi’an,a mega-city of China

The dust samples from 30 gas stations located in Xi’an are analyzed for Mn, Ni, Co, Cr, Cu, Cd, Pb and Zn by using atomic absorption spectrometry. The concentration, spatial distribution, source and the contamination levels provide scientific basis for urban planning and environmental renovation in Xi’an. The results indicate that the mean values of Ni, Cr, Co, Cu, Pb, Zn and Cd in the dust are 1.15, 1.19, 8.13, 3.94, 4.42, 5.09 and 15.62 times higher than the corresponding background values of Shaanxi soil, respectively. The high concentration of heavy metals is located in the inner and second ring road of Xi’an, China. Furthermore, the contents of metals in the south are higher than in the north. In addition, the concentrations of the gas station dust metals in the west are higher than in the east, particularly in the southwest. Three main sources of heavy metals of gas station dusts are identified in Xi’an. Mn and Ni mainly originate from a natural source; Cr, Cu, Pb, Cr and Zn mainly originate from traffic flow; and Co is mainly from industrial sources. The results of the potential ecological risk assessment indicate that the potential ecological risk index (RI) of Co is moderate; Cd is very high ecological risk, and the other analyzed metals belong to low ecological risk. The mean RI value of eight heavy metals in the gas station dusts from Xi’an is considerable ecological risk.