Temporal variability of selected dissolved elements in the lower Orinoco River,Venezuela

Monthly analyses of pH, conductance, alkalinity, total suspended solids, dissolved major cations (Na, K, Ca and Mg), and selected dissolved trace elements (Fe, Al, Mn, Cu, Zn and Cr) were conducted on waters of the lower Orinoco River from February 2004 to May 2006. The data show strong seasonal variability. Major cations had maximum concentrations at low water, and were correlated with pH, conductance and alkalinity because of the tributaries coming from the Andean zones, where the weathering of evaporites and carbonate shales controls water chemistry. K concentrations did not show any relation with evaporite weathering, probably because large amounts of K come from the Guayana Shield rivers as a consequence of feldspar weathering. The concentrations of dissolved Fe, Mn and Cu were highest during the high water stage. Concentrations of the elements K, Cr, Zn and Cu are correlated with each other but not with dissolved Fe and Al, which probably are complexed with humic and fulvic substances. Mn concentrations did not show relationships with other variables. Inter‐annual variability of dissolved elements is explained by temporal changes in precipitation. Copyright © 2008 John Wiley & Sons, Ltd.     

Interplanetary Nanodust Detection by the Solar Terrestrial Relations Observatory/WAVES Low Frequency Receiver

New measurements using radio and plasma-wave instruments in interplanetary space have shown that nanometer-scale dust, or nanodust, is a significant contributor to the total mass in interplanetary space. Better measurements of nanodust will allow us to determine where it comes from and the extent to which it interacts with the solar wind. When one of these nanodust grains impacts a spacecraft, it creates an expanding plasma cloud, which perturbs the photoelectron currents. This leads to a voltage pulse between the spacecraft body and the antenna. Nanodust has a high charge/mass ratio, and therefore can be accelerated by the interplanetary magnetic field to the speed of the solar wind: significantly faster than the Keplerian orbital speeds of heavier dust. The amplitude of the signal induced by a dust grain grows much more strongly with speed than with mass of the dust particle. As a result, nanodust can produce a strong signal despite its low mass. The WAVES instruments on the twin Solar TErrestrial RElations Observatory spacecraft have observed interplanetary nanodust particles since shortly after their launch in 2006. After describing a new and improved analysis of the last five years of STEREO/WAVES Low Frequency Receiver data, we present a statistical survey of the nanodust characteristics, namely the rise time of the pulse voltage and the flux of nanodust. We show that previous measurements and interplanetary dust models agree with this survey. The temporal variations of the nanodust flux are also discussed.     

Relationship between geo-structural evolution and development of karstic systems in the culminating area of Ouarsenis (West Algeria)

The Ouarsenis area is one of the most developed karstic systems of Algeria. It is a karst reservoir drinking water with a population of more than 50,000 people taking fully benefit from it. To understand the development of this karstic system, the local tectonic history of the four main mountain ranges of this culminating area (Ouarsenis) has been analyzed. Although previously identified primarily Cenozoic tectonic activities have been observed, a set of NW-SE joints intersecting the Jurassic limestone has been associated to a post-nappes tectonic events. Moreover, numerous joint sets oriented NNE/SSW have been identified almost over the entire culminating area. These joints are the direct consequence of the following stress history: (i) a NW/SE shortening responsible for a major overlap and the first fold (P1) phase, (ii) a second NNE/SSW shortening stage responsible for the second folding (P2) phase associated with 70° N sinistral strike-slip trend, (iii) a WNW/ESE extension phase resulting from the change of σ ₃ stress vertical axis, and (iv) a shearing stress creating a 120° N sinistral strike-slip fault. Only the late phases are responsible of the development of joints, which have been karstified later on. Indeed, significant families of karstified joints, i.e., 20° and 70° N have been found. These joints are related to the extensional and shearing modes, respectively, and linked to a particular in situ karstogenesis. Moreover, this study suggests an ancient establishment of the karstic systems in the Ouarsenis region in at least two stages: pre-figured and activated behaviors during the Cenozoic.     

Provenance analyses of the heavy-mineral beach sands of the Annaba coast,northeast Algeria,and their consequences for the evaluation of fossil placer deposit

The paper presents the first study of heavy-mineral sand beaches from the Mediterranean coast of Annaba/Algeria. The studied beaches run along the basement outcrops of the Edough massif, which are mainly composed by micaschists, tourmaline-rich quartzo-feldspathic veins, gneisses, skarns and marbles. Sand samples were taken from three localities (Ain Achir, Plage-Militaire and El Nasr). The heavy-mineral fraction comprises between 74 and 91 vol%. The garnets of the beaches are almandine rich and tourmalines vary with respect to their location from schorl to dravite. Tourmaline at Ain Achir and the Plage-Militaire is schorlits, while at El Nasr beach dravite is ubiquitous. The World Shale Average normalised REE of the sands and the basement outcrops reveal: (i) Ain Achir beach: REE pattern of sand and the coastal rocks from the studied beaches reflects a multiple sources; (ii) Plage-Militaire: the sand and the coastal outcrops show similar LREE and a strong enrichment in HREE, suggesting the presence HREE-rich phases found as inclusions in staurolite; (iii) El Nasr: two types of sand patterns are found: one with flat REE pattern similar to the proximal rocks and other one enriched in HREE suggesting a mixed source.     

Geothermometry and circulation depth of groundwater in Semnan thermal springs,Northern Iran

Semnan thermal springs with high TDS and moderate temperature are located northwest of Semnan, the northern part of Iran. The spatial and temporal variations of physicochemical characteristics of the thermal and cold springs were investigated for the recognition of origin and dominant hydrogeochemical processes. Results show that the thermal springs have the same origin, but due to different ascending flow paths and different conductive cooling mechanism, their temperatures vary. The chemical composition of thermal waters is controlled by dolomite, halite and sulfate minerals dissolution and calcite precipitation and bacterial sulfate reduction. The concentration of major and trace elements in the thermal springs does not change in wet and dry seasons notably because they are derived from old groundwater with deep circulation and high temperature. Seasonal change in the concentration of some trace elements is due to the seasonal variation of pH, Eh, temperature and dilution by shallow waters. Decreasing SO₄ and carbonate saturation index and increasing Na/Cl ratios and Ca content in the dry season show dilution effect caused by the previous heavy rainfall events. The temperature of the heating reservoir based on K–Mg, chalcedony, quartz and chemical equilibrium approach was approximately estimated in the range of 60–80 °C. Hydrogeologically, a conceptual model was suggested for the thermal springs. The general groundwater flow direction is probably from the dolomite Lar Formation in Chenaran anticline toward the adjacent syncline in a confined condition, and then a thrust fault acts as a conduit and redirects the thermal water to the emerging springs at the surface.     

Detection of Interstellar Dust with STEREO/WAVES at 1 AU

Most in situ measurements of cosmic dust have been carried out with dedicated dust instruments. However, dust particles can also be detected with radio and plasma wave instruments. The high velocity impact of a dust particle generates a small crater on the spacecraft, and the dust particle and the crater material are vaporised and partly ionised. The resulting electric charge can be detected with plasma instruments designed to measure electric waves. Since 2007 the STEREO/WAVES instrument has recorded a large number of events due to dust impacts. Here we will concentrate on the study of those impacts produced by dust grains originating from the local interstellar cloud. We present these fluxes during five years of the STEREO mission. Based on model calculations, we determine the direction of arrival of interstellar dust. We find that the interstellar dust direction of arrival is ～260^°, in agreement with previous studies.

     

Features of interaction between lake water and springs,and evaluation of hydrochemical composition of water in Ifni Lake (High Atlas Mountains,Morocco, north of Africa)

The National Park of Toubkal is located in the High Moroccan Atlas Mountains, one of the regions sheltering the highest summits of North Africa (Mount Toubkal with an elevation of 4167 m). The park is characterized by very important water resources, including Ifni Lake, which is the highest natural lake in Morocco (with an elevation of 2320 m). This lake is located on the southern side of Mt. Toubkal. This area has never been the object of an environmental or hydrological study. The objective of the current study was the characterization of Ifni Lake and the spring waters located in this area, as the basis of a framework to protect natural resources in northern Africa. The hydrochemical composition of water determines its origin and relationship with its catchment. Hydrochemical studies were carried out to assess the ions water composition, and processes governing the hydrochemistry of Ifni Lake water and the springs in the study area. A total of 20 water samples were collected in 2013 and analyzed for various parameters such as pH, electrical conductivity, and major ions. The physico-chemical analysis of the Ifni Lake water showed that this is the least mineralized water studied in this region, having a bicarbonate, calcium, and magnesium as dominate ions. Also there is a relationship between the hydrochemical composition of Ifni Lake and spring waters.     

A preliminary study of freshwater meiofaunal communities at Greenwich Island,South Shetland Islands,Antarctica

Meiofaunal communities of three small, shallow freshwater habitats sampled during the austral summer of 2013 in Greenwich Island, South Shetland Islands, Antarctica, are reported. Communities are domin...     

Nano dust impacts on spacecraft and boom antenna charging

High rate sampling detectors measuring the potential difference between the main body and boom antennas of interplanetary spacecraft have been shown to be efficient means to measure the voltage pulses induced by nano dust impacts on the spacecraft body itself (see Meyer-Vernet et al. in Sol. Phys. 256:463, 2009). However, rough estimates of the free charge liberated in post impact expanding plasma cloud indicate that the cloud’s own internal electrostatic field is too weak to account for measured pulses as the ones from the TDS instrument on the STEREO spacecraft frequently exceeding 0.1 V/m. In this paper we argue that the detected pulses are not a direct measure of the potential structure of the plasma cloud, but are rather the consequence of a transitional interruption of the photoelectron return current towards the portion of the antenna located within the expanding cloud.     

Lacustrine sediments provide geochemical evidence of environmental change during the last millennium in southeastern Brazil

A 172 cm-long sediment core was collected from a small pristine lake situated within a centripetal drainage basin in a tropical karst environment (Ribeira River valley, southeastern Brazil) in order to investigate the paleoenvironmental record provided by the lacustrine geochemistry. Sediments derived from erosion of the surrounding cambisoils contain quartz, kaolinite, mica, chlorite and goethite. Accelerator mass spectroscopy (AMS) ¹⁴C dating provided the geochronological framework. Three major sedimentary units were identified based on the structure and color of the sediments: Unit III from 170 to140 cm (1030±60–730±60 yr BP), Unit II from 140 to 90 cm (730±60–360±60 yr BP) and Unit I from 90 to 0 cm (360±60–0 yr BP). Results of major and trace element concentrations were analysed through multivariate statistical techniques. Factor analysis provided three factors accounting for 72.4% of the total variance. F1 and F2 have high positive loadings from K, Ba, Cs, Rb, Sr, Sc, Th, light rare earth element (LREE), Fe, Cr, Ti, Zr, Hf and Ta, and high negative loadings from Mg, Co, Cu, Zn, Br and loss on ignition (LOI). F3, with positive loadings from V and non-metals As and Sb, accounts for a low percentage (9.7%) of the total variance, being therefore of little interpretative use. The profile distribution of F1 scores reveals negative values in Units I and III, and positive values in Unit II, meaning that K, Ba, Cs, Rb, Sr, Sc, Th, LREE, Fe, Cr, Ti, Zr, Hf and Ta are relatively more concentrated in Unit II, and Mg, Co, Cu, Zn and Br are relatively more abundant in Units I and III. The observed fluctuations in the geochemical composition of the sediments are consistent with slight variations of the erosion intensity in the catchment area as a possible response to variations of climatic conditions during the last millennium.