An example of fingerprint detection of greenhouse climate change

As an example of the technique of fingerprint detection of greenhouse climate change, a multivariate signal or fingerprint of the enhanced greenhouse effect is defined using the zonal mean atmospheric temperature change as a function of height and latitude between equilibrium climate model simulations with control and doubled CO₂ concentrations. This signal is compared with observed atmospheric temperature variations over the period 1963 to 1988 from radiosonde-based global analyses. There is a significant increase of this greenhouse signal in the observational data over this period.These results must be treated with caution. Upper air data are available for a short period only, possibly too short to be able to resolve any real greenhouse climate change. The greenhouse fingerprint used in this study may not be unique to the enhanced greenhouse effect and may be due to other forcing mechanisms. However, it is shown that the patterns of atmospheric temperature change associated with uniform global increases of sea surface temperature, with El NinoSouthern Oscillation events and with decreases of stratospheric ozone concentrations individually are different from the greenhouse fingerprint used here.     

Dense and diffuse gas in dynamically active clouds

We investigate the chemical and observational implications of repetitive transient dense core formation in molecular clouds. We allow a transient density fluctuation to form and disperse over a period of 1 Myr, tracing its chemical evolution. We then allow the same gas immediately to undergo further such formation and dispersion cycles. The chemistry of the dense gas in subsequent cycles is similar to that of the first, and a limit cycle is reached quickly (2–3 cycles). Enhancement of hydrocarbon abundances during a specific period of evolution is the strongest indicator of previous dynamical history. The molecular content of the diffuse background gas in the molecular cloud is expected to be strongly enhanced by the core formation and dispersion process. Such enhancement may remain for as long as 0.5 Myr. The frequency of repetitive core formation should strongly determine the level of background molecular enhancement.
We also convolve the emission from a synthesized dark cloud, comprised of ensembles of transient dense cores. We find that the dynamical history of the gas, and therefore the chemical state of the diffuse intercore medium, may be determined if a sufficient sample of cores is present in an ensemble. Molecular ratios of key hydrocarbons with SO and SO₂ are crucial to this distinction. Only surveys with great enough angular resolution to resolve individual cores, or very small groupings, are expected to show evidence of repetitive dynamical processing. The existence of non-equilibrium chemistry in the diffuse background may have implications for the initial conditions used in chemical models. Observed variations in the chemistries of diffuse and translucent regions may be explained by lines of sight which intersect a number of molecular cloud cores in various stages of evolution.     

西秦岭凤太矿集区丝毛岭金矿床地质地球化学特征

西秦岭凤太矿集区丝毛岭金矿床位于八卦庙造山型金矿床西侧5km左右,是一个新探明的剪切带型金矿。其成矿作用过程可分为早期石英-绢云母-硫化物阶段、中期多金属-硫化物阶段和晚期碳酸盐阶段。对早、中期的石英流体包裹体测试结果表明,丝毛岭金矿床成矿流体以富CO2、中温、低盐度为特征,总体上属于中温低盐度CO2-H2O体系,流体包裹体类型的多样性是流体不混溶性的产物。从早阶段到主成矿阶段成矿流体的温度、压力和盐度均有降低,硫逸度增高,有利于金的沉淀富集。H、O、S、C同位素研究结果,以及与八卦庙金矿床的对比分析表明,二者的成矿流体具有相似性和同源性,都是以深部来源为主的多源流体。由于丝毛岭金矿床产出的层位高于八卦庙金矿床,其成矿环境相对开放。     

Chemical effects of H2 formation excitation

The effects of the production on dust grain surfaces of molecular hydrogen in excited states have been investigated. On the assumption that all of the H₂ formed on the surface of grains has a sufficient level of excitation too vercome the energy barriers in the formation reactions for the important OH and CH⁺ radicals, we consider the likely abundances of excited H₂ (H₂ ^*), OH and CH⁺ in various situations. Two different models are employed; the first links the H₂ ^* abundance directly to that of H₂ using a steady-state approximation, whilst the second considers the time-dependence of H₂ ^*. The second model is applied to gas that has been subjected to a strong isothermal shock (specifically, the shock-induced collapse of a diffuse cloud), which results in an extreme (high density, high atomic hydrogen abundance) environment. In general, it is found that the presence of the excited H₂ has only marginal effects on the chemistry of interstellar clouds. However, in the isothermal shock model, the abundances of CH⁺ are significantly enhanced, but only on short timescales, whilst the effects on the OH abundances are smaller, but last longer. We conclude that other than in such exceptional environments there are no obvious chemical signatures of the formation of H₂ ^*. This revised version was published online in July 2006 with corrections to the Cover Date.     

The chemistry of transient dense cores

We investigate the chemistry of a transient density fluctuation, with properties similar to those of a dense core within a molecular cloud. We run a multipoint chemical code through a core's condensation from a diffuse medium to its eventual dispersion, over a period of ∼1 Myr. We find a significant enhancement of the chemical composition of the core material on its return to diffuse conditions, whilst the expansion of the core as it disperses moves this material out to large distances from the core centre. This process transports molecular species formed in the high-density regions out into the diffuse medium. Chemical enrichment of the cloud as a whole also occurs, as other cores of various sizes, life-spans and separations evolve throughout. Enrichment is strongly affected by freeze-out on to dust grains, which takes place in high-density, high visual extinction regions. As the core disperses after reaching its peak density and the visual extinction drops below a critical value, grain mantles are evaporated back into the gas phase, initiating more chemistry. The influence of the sizes, masses and cycle periods of cores will be large both for the level of chemical enrichment of a dark cloud and ultimately for the low-mass star formation rate. We also consider the case of a self-gravitating core, by holding its peak density conditions for a further 0.4 Myr. We find that the differences are generally small, and the resultant column densities do not provide definitive criteria for detection of this condition. However, increases in fractional abundances due to reinjection of mantle-borne species may provide a criterion for a negative detection.     

Global Climate Change — the Latest Assessment: Does Global Warming Warrant a Health Warning?

Global climate change is a qualitatively distinct, and very significant, addition to the spectrum of environmental health hazards encountered by humankind. Historically, environmental health concerns have focused on toxicological or microbiological risks to health from local exposures. However, the scale of environmental health hazards is today increasing; indeed, the burgeoning human impact on the environment has begun to alter global biophysical systems (such as the climate system). As a consequence, a range of larger-scale environmental hazards to human population health has emerged. This includes the health risks posed by climate change, stratospheric ozone depletion, loss of biodiversity, stresses on terrestrial and ocean food-producing systems, changes in hydrological systems and the supplies of freshwater, and the global spread of persistent organic pollutants. Appreciation of this scale and type of influence on human health entails an ecological perspective — a perspective that recognises that the foundations of long-term good health in populations reside in the continued stability and functioning of the biosphere's "life-supporting" ecological and physical systems. This revised version was published online in September 2006 with corrections to the Cover Date.