Trends in 1,4-Dioxane Analyses: Implications for Identification and Characterization of Contaminated Groundwater Sites

1,4-Dioxane is a contaminant of emerging concern, and there is significant uncertainty about how its environmental occurrence in groundwater is being assessed given the various analytical methods available. This study compiled public sampling records from 2000 to 2019 that included >106,000 analyses of 1,4-dioxane from 822 different U.S. sites. The 1,4-dioxane detection frequency in the entire dataset (including all methods) was 45%, and the median detected concentration was 10 μg/L, highlighting the dilute nature of 1,4-dioxane in environmental media and the importance of selecting methods with adequate sensitivity. The annual distribution of samples analyzed by each method type confirmed a shift towards methods designed for semi-volatile compounds (Method 8270 and Method 8270 SIM) that exhibited consistently lower reporting limits (median reporting limit for each year typically ≤1 μg/L). In contrast, the method designed for volatile compounds (Method 8260) exhibited less sensitivity for 1,4-dioxane (median reporting limit per year between 40 and 100 μg/L) and its use declined significantly over time with increasing use of the moderately sensitive Method 8260 SIM in later years. This shift contributed to an increase in the 1,4-dioxane detection frequency over time, with a strong correlation between the annual detection frequency and the median reporting limit. Sites where 1,4-dioxane was analyzed but not detected overwhelmingly used less-sensitive methods that may not have been adequate for the expected concentration levels. Given the sub-μg/L groundwater criteria issued for 1,4-dioxane by some regulatory agencies, more sensitive and accurate methods will be increasingly needed to assess compliance.     

Radar measurements of Martian topography and surface properties: The 1971 and 1973 oppositions

The Goldstone radar system was used at a wavelength of 12.6 cm to probe the Martian surface during the 1973 opposition. Measurements of range and reflected power were made at least weekly between July 12 and November 24. Surface cells isolated by the radar system were 8 km E-W × 110 km N-S. Altitudes were calculated from signal time delays measured relative to a triaxial ellipsoid and were combined with altitudes measured during the 1971 opposition. Contours of constant altitude were calculated at 200 m intervals between latitudes ?14° and ?22°. These contours are presented in conjunction with Mars charts derived from Mariner 9 television pictures. Reflected power was measured at angles of incidence between ?5° and +5°. These measurements were combined with those obtained during the 1971 opposition. Predictions of the reflected power versus the angle of incidence were calculated from the exponential surface model of Hagfors. The predictions were fit to the data in a least-squares sense, using a nonlinear iterative procedure, to yield estimates of surface roughness and reflectivity. The smoother regions exhibit a typical reflectivity of 8.2%. A tendency for the reflectivity to decrease with increasing roughness was observed.     

北吕宋岛菲律宾活动带蛇绿岩及其上覆浊积岩的放射虫研究新进展

The basement of the Philippine Mobile Belt (PMB) is mainly composed of ophiolites that are mostly overlain by Paleogene to Miocene turbidites in central Luzon. To clarify the geological development of the PMB with respect to the initial stage of the arc volcanism (eg. Yumul et al., 2003, 2008; Dimalanta and Yumul, 2003; Suzuki et al., 2011), radiolarian dating was examined in siliceous sediments associated with the ophiolites and turbidites. The samples were collected from sites identified with the Zambales and Montalban ophiolites, basic tuff phyllites in NW Din-galan, and their overlying formations.     

Relationship of diagenetic chlorite rims to depositional facies in Lower Cretaceous reservoir sandstones of the Scotian Basin

The relationship between diagenetic chlorite rims and depositional facies in deltaic strata of the Lower Cretaceous Missisauga Formation was investigated using a combination of electron microprobe, bulk geochemistry and X‐ray diffraction data. The succession studied comprises several stacked parasequences. The delta progradational facies association includes: (i) fluvial or distributary channel sandstones (some with tidal influence); (ii) thick‐bedded delta‐front graded beds of sandstone interpreted as resulting from fluvial hyperpycnal flow during floods and storms; and (iii) more distal muddier delta‐front and prodeltaic facies. The transgressive facies association includes lag conglomerate, siderite‐cemented muddy sandstone and mudstone, and bioclastic sandy limestone. Chlorite rims are absent in the fluvial facies and best developed in thick sandstones lacking mudstone baffles. Good quality chlorite rims are well correlated with Ti in bulk geochemistry. Ti is a proxy for Fe availability, principally from the breakdown of abundant detrital ilmenite (FeTiO₃). Under conditions of sea floor diagenesis, the abrupt decrease in sedimentation rate at transgressive surfaces caused progressive shallowing of the sulphate‐depletion level and of the overlying Eh‐controlled diagenetic zones, resulting in conditions suitable for diagenetic formation of berthierine to migrate upwards through the packet of reservoir sandstones. This early diagenetic berthierine suppressed silica cementation and later recrystallized to chlorite. Thick euhedral outer chlorite rims were precipitated from formation water in sandstone lacking muddy baffles on this chlorite substrate and inhibited late carbonate cementation. This study thus shows that the preservation of porosity by chlorite rims is a two‐stage process. Rapidly deposited delta‐front turbidite facies create early diagenetic conditions that eventually lead to the formation of chlorite rims, but the best quality chlorite rims are restricted to sandstones with high permeability during burial diagenesis.     

Mesozoic Evaniidae (Insecta: Hymenoptera) in Spanish Amber: Reanalysis of the Phylogeny of the Evanioidea

<正>One new genus and five new species of the family Evaniidae are described from the Early Cretaceous (Albian)Spanish amber of Penacerrada-Ⅰ(Province of Burgos),San Just and Arroyo de la Pascueta(both in the Province of Teruel):Cretevania alonsoi sp.nov.,C.montoyai sp.nov.,C.alcalai sp.nov.,C.rubusensis sp.nov.,and Iberoevania roblesi gen.and sp.nov.Taxonomic changes include Cretevania pristina(Zhang and Zhang,2000) comb.nov.,C.exquisita(Zhang,Rasmtsyn,Wang and Zhang,2007)comb.nov.,C.vesca(Zhang,Rasnitsyn,Wang and Zhang,2007)comb.nov.,and C.cyrtocerca(Deans,2004)comb.nov.,as a result of the reinterpretation of the genera Procretevania and Eovernevania.The new well preserved specimens of the genus Cretevania,together with the characters shown by the type specimens of the synonymized genera,give new information about their anatomical characters of taxonomical importance,and the genus Cretevania Rasnitsyn,1975 is re-diagnosed.The holotypes of the Russian species in amber have been revised.A cladistic analysis of fossil and extant groups of the superfamily Evanioidea is included.Cretevania had a wide palaeogeographic distribution,with the highest diversity known from Spain.The 13 known Cretevania species show a high interspecific variation mainly in wing characteristics,and a wide range of body and wing size.     

Martian topography and surface properties as seen by radar: The 1971 opposition

Taking advantage of the favorable opposition of 1971, the Goldstone radar system, operating at 2388MHz, was used to scan the Martian surface. Measurements of altitude and reflected power were taken approximately every 3 days. Each measurement represents an area 8km E-W × 80km N-S, the highest resolution attained to date. Altitude measurements obtained on different observing days were combined to produce altitude profiles for three complete rotations, each at different latitudes. Large-scale variations in altitudes cover a range of 14km. Altitude changes of 5 in 30km of longitude were observed. The altitude profiles show the heavy cratering of the surface, and several large craters (50–100km) 1–2 km deep are easily seen. Reflected power for different angles of incidence was measured, yielding the scattering properties of the surface as a function of longitude. Correlation was found between the peak intensity of the reflected signal and the width of the scattering function. The average relationship between the intensity and the width suggests a power reflection coefficient of at least 0.064 ± 0.012. Departures from the average are interpreted as deviations in the reflection coefficient from the mean value. These variations are presented as a function of longitude for each of the three rotations.     

A local spatial decision support system for developing countries based on MCA,fuzzy sets and OWA – case study of a municipality in Cuba

This paper presents a Spatial Decision Support System for local governments of developing countries. It allows municipality government, enterprises, scientific community and civil society to address decision problems using GIS. The framework is supported by four modules of information technologies: Environmental Decision Support Database, Data Manipulation, Decision Support, and Mapping. A case study is presented covering the implementation of this framework in one municipality of Cuba. An example of land suitability planning for coconut crops is used to evaluate the system performance and usability. Results show local municipalities are able to use this framework to solve local decision problems using state of the art decision making even with low infrastructure development.     

Radar studies of the Martian surface at centimeter wavelengths: The 1975 opposition

The Goldstone radar system was operated at wavelengths of 3.5 and 12.6 cm to probe the Martian surface during the 1975 opposition. Regions studied in detail by range-Doppler techniques are Syrtis Major, Sinus Meridiani, and the crater Schiaparelli. Average rms slopes of 1.6° and 1.1° were measured in Syrtis Major at 3.5 and 12.6 cm, respectively, while the average reflectivity was 0.064 ± 0.02 at both wavelengths. No wavelength dependence of surface roughness was seen in Sinus Meridiani, where rms surface slopes averaged 1.8° and the reflectivity was 0.08 ± 0.02. The regions around Schiaparelli were probed at a 12.6-cm wavelength. The echo from the bottom of the crater was undetectable. Hence _ρ0C < 25, where _ρ0 is the reflectivity and C is the Hagfors roughness parameter. Operating at 3.5 cm during May and June of 1976, 149 continous-wave echo spectra were obtained near latitude 18°, sampling most longitudes including the early Viking landing sites A1 and A2. The average total radar cross section is 4.8% of the geometrical cross section. The diffuse component was estimated to be 1.9%, leaving 2.9% to the average quasi-specular component. The average rms slope is 4.1°. Six spectra obtained at site A1 indicate that rms slopes are 5 to 9° between latitudes 17 and 19°. Three spectra obtained at s site A2 indicate an rms slope of 3.9°.     

Research and Application of In‐seam Seismic Survey Technology for Disaster‐causing Potential Geology Anomalous Body in Coal Seam

In order to effectively detect potential geology anomalous bodies in coal bearing formation, such as coal seam thickness variation, small faults, goafs and collapse columns, and provide scientific guidance for safe and efficient mining, the SUMMIT-II EX explosion-proof seismic slot wave instrument, produced by German DMT Company, was used to detect the underground channel wave with the help of transmission method, reflection method and transflective method. Region area detection experiment in mining face had been carried out thanks to the advantage of channel wave, such as its great dispersion, abundant geology information, strong anti-interference ability and long-distance detecting. The experimental results showed that: (1) Coal seam thickness variation in extremely unstable coal seam has been quantitatively interpreted with an accuracy of more than 80% generally; (2) The faults, goafs and collapse columns could be detected and predicted accurately; (3) Experimental detection of gas enrichment areas, stress concentration regions and water inrush risk zone has been collated; (4) A research system of disaster-causing geology anomalous body detection by in-seam seismic survey has been built, valuable and innovative achievements have been got. Series of innovation obtained for the first time in this study indicated that it was more effective to detect disaster-causing potential geology anomalies by in-seam seismic survey than by ground seismic survey. It had significant scientific value and application prospect under complex coal seam conditions.