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1.
Methods are described for the complexometric determination of calcium and magnesium in seawater, using an amalgamated silver electrode for end-point detection. In the presence of a small amount of mercury(II)-chelonate, the amalgamated silver electrode serves as a pM indicator during the complexometric titration, the Hg complex being stronger than Ca, Mg and Sr complexes. Calcium is determined by titration with EGTA, calcium+magnesium+strontium by titration with EDTA and magnesium is obtained by difference. Average values of 0.02120 (standard deviation 0.00004) for Ca:Cl‰ and 0.06671 (standard deviation 0.00014) for Mg:Cl‰ were obtained for samples from tropical North Atlantic Ocean. 相似文献
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The use of rogation ceremony records in climatic reconstruction: a case study from Catalonia (Spain)
The use of rogation ceremonies due to environmental causes constitutes an important source of information in paleoclimatic reconstructions. Their specific characteristics and full documental records permit highly reliable series to be reconstructed with daily, monthly, seasonal or annual resolution over periods of several centuries (3–4 centuries in the case of Catalonia). The levels of intensity, reflected in the type of religious ceremony enacted, allows quantification. Comparative analysis is made possible by the similarity of the mechanisms developed in different localities. The use of these series in paleoclimatological studies is a promising line of research, particularly as regards the pro pluvia rogations celebrated in the Mediterranean countries and in South America. 相似文献
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Mariano Barriendos Javier Martín-Vide Juan Carlos Peña Roberto Rodríguez 《Climatic change》2002,53(1-3):151-170
Meteorological observations in the city of Cádiz are acknowledged as having been made from the middle of the 18th century onwards although they were only recorded and preserved in documentary form from 1789 onwards. Data readings were taken at the new Naval Observatory in San Fernando, ten kilometres from Cádiz, from 1797 onwards. Continuous series for temperature and atmospheric pressure at a daily resolution have been compiled and constructed from 1817 until 1996. The data series is composed of thrice daily observations made at Cádiz (1821–1880) by local observers and hourly data from Naval Observatory at San Fernando (1870–1996). 相似文献
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Linear discriminant analysis to describe the relationship between rainfall and landslides in Bogotá, Colombia 总被引:1,自引:0,他引:1
Alfonso Mariano Ramos-Cañón Luis Felipe Prada-Sarmiento Mario Germán Trujillo-Vela Juan Pablo Macías Ana Carolina Santos-R 《Landslides》2016,13(4):671-681
Bogotá is located in the central Andean region of Colombia, which is frequently affected by landslide processes. These processes are mostly triggered during the rainy season in the city. This fact remarks the importance of determining what rain-derived parameters (e.g. intensity, antecedent rain, daily rain) are better related with the occurrence of landslides. For this purpose, the linear discriminant analysis (LDA), a technique derived from multivariate statistics, was used. The application of this type of analysis led to obtain simple mathematical functions that represent the probability of occurrence of landslides in Bogotá. The functions also allow to identify the most relevant variables derived from records of rainfall linked to the generation of landslides. A proof of concept using the proposed methodology was done using historic rainfall data from a 9-km2 area of homogenous climatology and geomorphology in the south part of Bogotá. Landslides needed to be grouped for the LDA. Each one of these grouping categories represents landslides that occurred in similar geomorphologic conditions. Another set of events with no landslides was generated synthetically. Results of the proof of concept show that rainfall parameters such as normalized rainfall intensity I MAP, normalized daily rainfall R MAP and rainy-days normal RDN have the best statistical correlation with the landslides observed in the zone of analysis. 相似文献
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Laboratory experiments on simulated faults in rocks clearly show the temperature dependence of dynamic rock friction. Since rocks surrounding faults are permeable, we have developed a numerical method to describe the thermo-mechanical evolution of the pre-seismic sliding phase which takes into account both the rate-, state- and temperature-dependent friction law and the heat advection term in the energy equation. We consider a laminar fluid motion perpendicular to a vertical fault plane and assume that fluids move away from the fault plane. A semi-analytical temperature solution which accounts for the variability of slip velocity and stress on the fault has been found. This solution has been generalized to the case of a time varying fluid velocity and then was used to include the thermal pressurization effect. After discretizing the temperature solution, the evolution of the system is obtained by the solution of a system of first order differential equations which allows us to determine the evolution of slip, slip rate, friction coefficient, effective normal stress, temperature and fluid velocity. The numerical solutions are found using a Runge-Kutta method with an adaptative stepsize control in time. When the thermal pressurization effects can be neglected, the heat advection effect gives rise to a delay, with respect to the purely conductive case, of the earthquake occurrence time. This delay increases with increasing permeability H of the system. When the thermal pressurization effects are taken into account the situation is opposite, i.e. the onset of instability tends to precede that of the purely conductive case. The advance in the time of occurrence of instability increases with increasing coefficient of thermal pressurization. In the small permeability range (H ≤ 10?18 m2), the seismic moment and nucleation length of the pre-seismic phase are significantly smaller than those predicted by the purely conductive model. 相似文献
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Going quantitative with 4D seismic analysis 总被引:1,自引:0,他引:1
It is demonstrated that time‐lapse seismic signatures can be directly calibrated with historical data from producing and injecting wells via a reservoir simulator, material balance calculation or simply using the hard data. When this procedure is applied to a field over which two or more repeat surveys have been shot at different calendar times, the correlation coefficients that link the seismic difference signatures to the reservoir's pressure and saturation variations are determined. By utilizing several seismic attributes that respond differently to reservoir perturbations, pressure and saturation changes are then independently estimated. The approach is tested on synthetic data and then on data from the Schiehallion Field on the UK continental shelf, with favourable results. 相似文献
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We evaluated the distribution of waterfowl in relation to a seagrass (Ruppia maritima) patch, to infauna, and on its relationship with substrate characteristics. An experiment performed in the Mar Chiquita coastal lagoon (37°46′S, 57°27′W; Argentina) was used to evaluate the effect of herbivory on widgeon grass,R. maritima. Control plots of equal size, located between bird exclosures, were exposed to herbivory. The experiment ran for 31 d, starting on December 1, 1994. Censuses showed that black-necked swan ( $\bar x = 50$ birds ha?1, SD = 37, n = 10) and coots ( $\bar x = 42$ birds ha?1, SD = 28, n = 10) were the most important (always present) of the waterfowl seen feeding onR. maritima. The results of the experiment showed greater leaf lengths, lower belowground (rhizomes and roots) biomass, greater aboveground (leaves and shoots) biomass, and greater abundance of the polychaeteHeteromastus similis in exclosure plots. There were no exclosure effects on total biomass (belowground plus aboveground), reproductive parts (fruits and pre- and postpollination flowers), or abundance of most benthic infauna. Topographic surveys showed that sediment surface was higher within theR. maritima patches, but there were no significant differences in granulometric composition. Surveys also showed that bird distribution was strongly associated with the presence ofR. maritima. 相似文献
10.
Cathodoluminescence observations give information on the presence of europium in several minerals including apatite, fluorite, strontianite, and scheelite. Information on the oxidation state of the crystallization environment and on the partitioning of europium between coexisting mineral pairs may be obtained.The apatite in carbonatites and genetically related igneous rocks almost always contains europium in the divalent state. Occasionally both divalent and trivalent europium are observed.Europium is preferentially incorporated into strontianite when it crystallizes together with apatite in these same rocks. Similar results are found for fiuorite. 相似文献