Reevaluation of formation of metal nodules in ordinary chondrites

Abstract— Compositions of four metal nodules from two ordinary chondrites, WIS91627 (H3.7) and Juin (H5), were determined by instrumental and radiochemical neutron activation analyses. Compared with bulk metal fractions, the metal nodules are characterized by strong and variable depletion of the refractory siderophile elements Re, Os, Ir, Ru, Pt and Rh but normal W and Mo, some fractionation of Co from Ni, and low Cu concentrations. These characteristics are difficult to explain by shock-induced vaporization followed by fractional condensation, a mechanism suggested by Widom et al. (1986). We propose formation of metal nodules during metamorphism in the parent body. Refractory siderophile elements, such as Ir, Os, Rh, etc., are partly locked up in noble metal nuggets and cannot participate in kamacite formation. The occurrence of metal nodules in both equilibrated and unequilibrated ordinary chondrites suggests that diffusion along grain boundaries was important in the development of kamacite and taenite in ordinary chondrites.     

A new metal‐rich chondrite grouplet

Abstract— A new grouplet of primitive, metal‐rich chondrites, here called the CB (C, carbonaceous; B, bencubbinite) chondrites, has been recognized. It includes Bencubbin, Weatherford, Hammadah al Hamra (HH) 237 and Queen Alexandra Range (QUE) 94411, paired with QUE 94627. Their mineral compositions, as well as their oxygen and nitrogen isotopic compositions, indicate that they are closely related to the CR and CH chondrites, all of which are members of the more inclusive CR clan. CB chondrites have much greater metal/silicate ratios than any other chondrite group, widely increasing the range of metal/silicate fractionation recorded in solar nebular processes. They also have the greatest moderately volatile lithophile element depletions of any chondritic materials. Metal has compositional trends and zoning patterns that suggest a primitive condensation origin, in contrast with metal from other chondrite groups. CB chondrites, as well as other CR clan chondrites, have much heavier nitrogen (higher ¹⁵N/¹⁴N) than that in other chondrite groups. The primitive characteristics of the CB chondrites suggest that they contain one of the best records of early nebular processes. Another chondrite, Grosvenor Mountains 95551, is petrographically similar to the CB chondrites, but its mineral and oxygen and nitrogen isotope compositions indicate that it formed from a different nebular reservoir.     

Neutron capture effects on samarium,europium, and gadolinium in Apollo 15 deep drill‐core samples

Abstract— The isotopic compositions of Sm and Gd in seven lunar samples from the Apollo 15 deep drill core were determined to discuss the effects of neutron capture near the lunar surface. Large isotopic deviations of ¹⁵⁰Sm/¹⁴⁹Sm, ¹⁵⁶Gd/¹⁵⁵Gd, and ¹⁵⁸Gd/¹⁵⁷Gd derived from neutron capture effects were observed in all samples. Although neutron capture products in lunar samples were investigated extensively in the 1970s, our precise isotopic measurements resulted in several new findings. The neutron fluence in the Apollo 15 drill core is a function of depth with a symmetric peak at 190 g/cm² depth from the surface, confirming the results of earlier investigations. Neutron fluence values calculated from the isotopic shifts by comparison to artificially irradiated standard reagents were (5.16–7.49) × 10¹⁶ n/cm². These values are 1.3 to 1.4x larger than those previously reported. Variations of ε_Sm/ε_Gd with depth are interpreted as being due to variations in the neutron energy spectrum. Here ε_Sm and ε_Gd are defined as in previous studies of lunar neutron stratigraphy. Our data suggest that the neutron is more thermalized at the lower layers than it is at the upper layers. In addition to large isotopic shifts for ¹⁴⁹Sm, ¹⁵⁰Sm, ¹⁵⁵Gd, ¹⁵⁶Gd, ¹⁵⁷Gd, and ¹⁵⁸Gd, isotopic enrichments of ¹⁵²Gd and ¹⁵⁴Gd derived from neutron capture for ¹⁵¹Eu and ¹⁵³Eu, respectively, were also observed in all samples.