Water vapor variability in the north polar region of Mars from Viking MAWD and MGS TES datasets

Atmospheric water vapor abundances in Mars’ north polar region (NPR, from 60° to 90°N) are mapped as function of latitude and longitude for spring and summer seasons, and their spatial, seasonal, and interannual variability is discussed. Water vapor data are from Mars Global Surveyor (MGS) Thermal Emission Spectrometer (TES) and the Viking Orbiter (VO) Mars Atmospheric Water Detector (MAWD). The data cover three complete northern spring-summer seasons in 1977-1978, 2000-2001 and 2002-2003, and shorter periods of spring-summer seasons during 1975, 1999 and 2004. Long term interannual variability in the averaged NPR abundances may exist, with Viking MAWD observations showing twice as much water vapor during summer as the MGS TES observations more than 10 martian years (MY) later. While the averaged abundances are very similar in TES observations for the same season in different years, the spatial distributions in the early summer season do vary significantly year over year. Spatial and temporal variabilities increase between L_s ∼ 80-140°, which may be related to vapor sublimation from the North Polar Residual Cap (NPRC), or to changes in circulation. Spatial variability is observed on scales of ∼100 km and temporal variability is observed on scales of <10 sols during summer. During late spring the TES water vapor spatial distribution is seen to correlate with the low topography/low albedo region of northern Acidalia Planitia (270-360°E), and with the dust spatial distribution across the NPR during late spring-early summer. Non-uniform vertical distribution of water vapor, a regolith source or atmospheric circulation ‘pooling’ of water vapor from the NPRC into the topographic depression may be behind the correlation with low topography/low albedo. Sublimation winds carrying water vapor off the NPRC and lifting surface dust in the areas surrounding the NPRC may explain the correlation between the water vapor and dust spatial distributions. Correlation between water vapor and dust in MAWD data are only observed over low topography/low albedo area. Maximum water vapor abundances are observed at L_s = 105-115° and outside of the NPRC at 75-80°N; the TES data, however, do not extend over the NPRC and thus, this conclusion may be biased. Some water vapor appears to be released in plumes or ‘outbursts’ in the MAWD and TES datasets during late spring and early summer. We propose that the sublimation rate of ice varies across the NPRC with varying surface winds, giving rise to the observed ‘outbursts’ at some seasons.     

Water-ice clouds and dust in the north polar region of Mars using MGS TES data

Water-ice and dust optical depths in Mars’ north polar region are mapped as function of season, latitude and longitude, and their characteristics and variability on a geographic, seasonal, and interannual basis are discussed. We use water-ice and dust optical depth data provided by the Mars Global Surveyor (MGS) Thermal Emission Spectrometer (TES), covering nearly three northern spring and summer periods. We find that interannual variability exists in both the water ice and dust behavior, although there are trends that repeat year to year as well. The optical thickness of the north polar hood (NPH) exhibits interannually varying longitudinal structure, both during springtime recession and late-summer onset. We define the characteristics associated with the transition to and from the NPH and find that the disappearance occurs near L_s=75° and the reappearance near L_s=160-165°. We find that the late spring to early summer time frame is characterized by very low water-ice optical depths and enhanced dust activity, with a preference for lower water-ice and higher dust optical depths in the 0-90°W quadrant. We see possible evidence for stationary wavenumber 2 systems in a few of the maps examined.     

Monitoring the perennial martian northern polar cap with MGS MOC

We have used the Mars Global Surveyor Mars Orbiter Camera Wide Angle (MGS MOC WA) dataset to study albedo trends on the martian northern residual cap. Six study regions were selected, the Chasma Boreale source region, three regions near the center of the cap (“fish hook” region, latitude = 87°; “bottle opener” region, latitude = 87°, “steep-shallow” region, latitude = 85°), and two lower latitude regions (crater, latitude = 77°, and polar outlier, latitude = 82°), and the albedos of these six regions were examined. These regions were chosen due to their good temporal coverage in the MOC dataset, as well as having been studied by other researchers (Bass et al., 2000, Icarus 144, 382-396; Calvin and Titus, 2004, Lunar Planet. Sci. XXXV, Abstract 1455). The picture which emerges is complex. Most areas experience a combination of darkening and brightening through the northern summer; only one area consistently brightens (the polar outlier region). A good deal of interannual repeatability in each region's albedo behavior is seen, however. Possible causes for the observed complex behaviors include dust deposition from late summer storms, sintering of frost grains over the course of the summer, and cold trapping of volatiles on bright, cold surfaces.     

MGS TES observations of the water vapor above the seasonal and perennial ice caps during northern spring and summer

We report on new retrievals of water vapor column abundances from the Mars Global Surveyor (MGS) Thermal Emission Spectrometer (TES) data. The new retrievals are from the TES nadir data taken above the ‘cold’ surface areas in the North polar region (T_surf < 220 K, including seasonal frost and permanent ice cap) during spring and summer seasons, where retrievals were not performed initially. Retrievals are possible (with some modifications to the original algorithm) over cold surfaces overlaid by sufficiently warm atmosphere. The retrieved water vapor column abundances are compared to the column abundances observed by other spacecrafts in the Northern polar region during spring and summer and good agreement is found. We detect an annulus of water vapor growing above the edge of the retreating seasonal cap during spring. The formation of the vapor annulus is consistent with the previously proposed mechanism for water cycling in the polar region, according to which vapor released by frost sublimation during spring re-condenses on the retreating seasonal CO₂ cap. The source of the vapor in the vapor annulus, according to this model, is the water frost on the surface of the CO₂ at the retreating edge of the cap and the frost on the ground that is exposed by the retreating cap. Small contribution from regolith sources is possible too, but cannot be quantified based on the TES vapor data alone. Water vapor annulus exhibits interannual variability, which we attribute to variations in the atmospheric temperature. We propose that during spring and summer the water ice sublimation is retarded by high relative humidity of the local atmosphere, and that higher atmospheric temperatures lead to higher vapor column abundances by increasing the water holding capacity of the atmosphere. Since the atmospheric temperatures are strongly influenced by the atmospheric dust content, local dust storms may be controlling the release of vapor into the polar atmosphere. Water vapor abundances above the residual polar cap also exhibit noticeable interannual variability. In some years abundances above the cap are lower than the abundances outside of the cap, consistent with previous observations, while in the other years the abundances above the cap are higher or similar to abundances outside of the cap. We speculate that the differences may be due to weaker off-cap transport in the latter case, keeping more vapor closer to the source at the surface of the residual cap. Despite the large observed variability in water vapor column abundances in the Northern polar region during spring and summer, the latitudinal distribution of the vapor mass in the atmosphere is very similar during the summer season. If the variability in vapor abundances is caused by the variability of vapor sources across the residual cap then this would mean that they annually contribute relatively little vapor mass to significantly affect the vapor mass budget. Alternatively this may suggest that the vapor variability is caused by the variability of the polar atmospheric circulation. The new water vapor retrievals should be useful in tuning the Global Circulation Models of the martian water cycle.     

Ghost crab burrow density at Watamu Marine National Park: An indicator of the impact of urbanisation and associated disturbance?

Ghost crab (Ocypode species) burrow densities have previously been used as an indicator of anthropogenic impact. This study aimed to assess the burrow density of Ocypode species (O. ryderi and O. cordimanus) at four sites across Watamu Marine National Park, Kenya. Two sites were in front of hotel complexes (denoting a high degree of urbanisation), and two were in front of residential housing among coastal scrub (denoting a low degree of urbanisation). The findings reveal significantly higher burrow densities at sites in front of residential housing, which was the less developed area. This provides further evidence that Ocypode burrow densities can be used, where other methods would be impractical, to estimate the impact of some human activities along beach fronts, such as at Watamu Marine National Park.     

应用高分辨率质谱分析苏丹高酸值原油成因

苏丹Muglad和Melut盆地是苏丹乃至整个中、西非剪切带最富含油气的盆地,所发现的原油主要为中质油(重度为20°～34°API),其次为重质油(重度小于20°API),普遍高含沥青质、高含蜡、高酸值、低含硫。为了探讨高酸值原油的成因,选择了苏丹地区18个不同酸值的原油样品,尝试高分辨率质谱分析上述原油有机酸的组成。结果表明,高酸值原油的有机酸主要由环烷酸组成;环烷酸的平均相对分子质量随降解作用程度增加而增大,分子碳原子数分布范围变宽;环烷酸以一环、二环、三环环烷酸为主。生物降解作用是形成高酸值原油的主要原因。