The extinction coefficients in mid- and farinfrared of silicate and iron-oxide minerals of interest for astronomical observations

Extinction measurements were made for some silicate and iron-oxide mineral grains in mid- and far-infrared region. For far-infrared region, high temperature magnesium silicates such as olivine and pyroxenes show the absorption spectra of steep dependence as ^–3 ( being the wavelength) with some peak structure, but the spectrum of magnetite shows ^–1 dependence.     

Mid- and far-infrared extinction coefficients of hydrous silicate minerals

Extinction coefficients were measured for three kind of hydrous silicate minerals, montmorillonite, chlorite and serpentine, from 7 to 140 m. The infrared extinction coefficients of these minerals show (1) a few broad bands in the mid-infrared region and (2) a less steep wavelength-dependence in the far-infrared region, in contrast to those of high-temperature magnesium silicates. In the far-infrared region, montmorillonite shows a ^–0.8±0.1 dependence (, the wavelength) without any band structure, chlorite has a double maxima structure around 80 m, and serpentine shows a rather steep dependence with a small peak at 77 m.The changes of mid-infrared spectra by heating were measured. Change in chlorite spectrum is the most significant. Many fine features appear by heating and then they disappear. Above 900°C one broad feature remains around 10 m. Fine features of the montmorillonite spectrum disappear by heating. For serpentine, many new peaks appear and the spectrum resembles the spectrum of olivin. In near-infrared a band around 2.72 m disappears by heating.Extinction coefficients at very low temperatures were measured in the far-infrared region. For montmorillonite and serpentine, the spectrum is the same as that at room temperature. The double peaks of chlorite around 80 m become higher.     

Mid-infrared extinction coefficients of amorphous silicates

Mid-infrared extinction coefficients of five natural amorphous silicates and seven synthetic glasses were measured. Three bands at about 10, 12, and 20 μm were seen for all the measured samples. The quantities of these bands are found to have good correlations with the SiO₂ content of the samples. The correlations are the most remarkable for the 10 μm band. As the SiO₂ content decreases, the peak wavelengthλ _m shifts to longer side, the peak heightK _m decreases and the full width of half maximumW increases. A quantityλ _m K _m W is constant within 15%. Empirical formula $$\lambda_m (\mu m) = {11.10-2.30 x 10^-2} {[SiO_2 wt.\%]} \pm 0.15$$ and $$W(\mu m) = {5.14-4.68 x 10^- 2} {[SiO_2 wt.\%]} \pm 0.30$$ are obtained for the measured samples. Therefore, the correlation is present between the 10 μm peak wavelengthλ _m and peak widthW for amorphous silicates. The change in peak widthW is remarkable compared the change in peak wavelengthλ _m as the SiO₂ content varies. For the 12 μm band the correlations with the SiO₂ content are not so good. A tendency that theλ _m shifts to the red and theK _m lowers as the decreasing SiO₂ content are found. For the samples with SiO₂ content less than 50% the 12 μm band cannot recognized as the peak. For the 20 μm band, theλ _m is almost independent on SiO₂ content and theK _m lowers with decreasing SiO₂ content. The results are compared with the observed 10 μm band of the astronomical objects. A method to estimate the SiO₂ content of astronomical grain materials is proposed and 48±8% SiO₂ wt.% is found corresponding to the peak wavelength of 9.7 μm and the peak width of 2.5–3.0 μm of typical celestial objects.     

Discovery Of Mg-Rich Pyroxenes In Comet C/1995 O1 (Hale-Bopp): Pristine Grains Revealed At Perihelion

The NASA Ames HIFOGS spectrometer observed comet C/1995 O1 (Hale-Bopp) at epochs including 96 Oct 7–14 UT (2.8 AU), 97 Feb 14–15 UT (1.2 AU), 97 Apr 11 UT (0.93 AU), and 97 Jun 22, 25 UT (1.7 AU). The HIFOGS 7.5–13.5 μm spectrophotometry (R = 360 - 180) of the silicate feature at 2.8 AU is identical in shape to the ISO SWS spectra of comet Hale-Bopp (Crovisier et al., 1997); the strong 11.2 μm peak in the structured silicate feature is identified as olivine. Upon close passage to the sun, the HIFOGS spectra at 1.2 AU and 0.93 AU reveals strong peaks at 9.3 μm and 10.0 μm. The post-perihelion 10 μm silicate feature at 1.7 AU is weaker but has nearly the same shape as the pre-perihelion spectra at 1.2 AU, reverting to its pre-perihelion shape: there is no change in the dust chemistry by close passage to the sun. The appearance of the strong peaks at 9.3 μm and 10.0 μm at r_h ≲ 1.7 AU is attributed to the rise in the contribution of pryoxenes (clino-pyroxene and orthopyroxene crystals) to the shape of the feature, and leads to the hypothesis that the pyroxenes are significantly cooler than the olivines. The pyroxenes are radiating on the Wien side of the blackbody at 2.8 AU and transition to the Rayleigh-Jeans tail of the blackbody upon closer approach to the Sun. Composite fits to the observed 10 μm silicate features using IDPs and laboratory minerals shows that a good empirical fit to the spectra is obtained when the pryoxenes are about 150 K cooler than the olivines. The pyroxenes, because they are cooler and contribute signficantly at perihelion, are more abundant than the olivines. The perihelion temperature of the pyroxenes implies that the pyroxenes are more Mg-rich than the other minerals including the olivines, amorphous olivines, and amorphous pyroxenes. The PUMA-1 flyby measurements of comet P/Halley also indicated an overabundance of Mg-rich pryoxenes compared to olivines. Comet Hale-Bopp's pyroxenes are similar to pyroxere IDPs from the ’Spray‘ class, known for their D-richness and their unaltered morphologies: Hale-Bopp's Mg-rich pyroxenes may be pristine relic ISM grains. This revised version was published online in July 2006 with corrections to the Cover Date.     

Mid-infrared spectra of differentiated meteorites (achondrites): Comparison with astronomical observations of dust in protoplanetary and debris disks

Mid-infrared (5–25 μm) transmission/absorption spectra of differentiated meteorites (achondrites) were measured to permit comparison with astronomical observations of dust in different stages of evolution of young stellar objects. In contrast to primitive chondrites, achondrites underwent heavy metamorphism and/or extensive melting and represent more advanced stages of planetesimal evolution. Spectra were obtained from primitive achondrites (acapulcoite, winonaite, ureilite, and brachinite) and differentiated achondrites (eucrite, diogenite, aubrite, and mesosiderite silicates). The ureilite and brachinite show spectra dominated by olivine features, and the diogenite and aubrite by pyroxene features. The acapulcoite, winonaite, eucrite, and mesosiderite silicates exhibit more complex spectra, reflecting their multi-phase bulk mineralogy.Mixtures of spectra of the primitive achondrites and differentiated achondrites in various proportions show good similarities to the spectra of the few Myr old protoplanetary disks HD104237A and V410 Anon 13. A spectrum of the differentiated mesosiderite silicates is similar to the spectra of the mature debris disks HD172555 and HD165014. A mixture of spectra of the primitive ureilite and brachinite is similar to the spectrum of the debris disk HD113766. The results raise the possibility that materials produced in the early stage of planetesimal differentiation occur in the protoplanetary and debris disks.     

Study of the structure of silica film by infrared spectroscopy and electron diffraction analyses

Amorphous silicon oxide films have been studied on the basis of electron diffraction (ED) analyses and infrared (IR) spectroscopy in order to elucidate the relationship between the structures. After the heat treatment of the film in air at 300 and 500°C, the ED pattern showed halo rings, and the IR spectra clearly changed. Intensity analysis of the ED pattern provided evidence for the structural change of the amorphous film. It was concluded that the spectral changes in the ranges of 9.2–10.2, 12.5–13.5 and 19.5–22.5 μm were the result of phase transitions of the microcrystallites of α-cristobalite to β-cristobalite, and α- or β-quartz. Astrophysical implications have been discussed.     

Grain size dependence of far-infrared extinction spectra of amorphous fine grains

The far-infrared extinction spectra of fused silica grains with the size range from 1.8 m to 60 Å were measured. The spectra depend clearly on the grain size. For large grain sizes (from 1.8 m to 400 Å) the spectra show almost the ^–2 dependence ( is the wavelength), which resembles that of the bulk material. For fine grains (70 and 60 Å) the spectra are less steep, the wavelength dependence being ^–1. This grain size dependence of extinction spectra agrees essentially with the prediction of Seki and Yamamoto.