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The behaviour of quartz during metamorphism is studied based on two case studies from the Barrovian terrains of Sulitjelma in arctic Scandinavia and Loch Tay in the Central Highlands Dalradian of Scotland. Both terrains preserve evidence for metamorphism in pelites involving nucleation and growth of garnet at different times in the deformation history. Data are presented on the size, shape and crystallographic orientation of quartz preserved as inclusions in garnet and as grains in the surrounding matrix. While quartz-grains remain small and dispersed between mica grains, deformation appears to be dominated by grain-boundary sliding accommodated by dissolution–precipitation. At amphibolite facies, textural coarsening occurs by dissolution of small quartz grains and growth of larger quartz grains, coupled with segregation of quartz from mica. As a result, quartz deforms by dislocation creep, developing crystallographic preferred orientations (CPO) consistent with both coaxial and non-coaxial strain. Quartz CPOs with <0001> axes lying parallel to foliation and stretching direction are commonly developed, and best explained by mechanical rotation of inequant (detrital?) quartz grains. There is no evidence for selective entrapment of quartz inclusions in garnet on the basis of quartz crystallographic orientation. 相似文献
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Offsets from isotopic equilibrium in biogenic carbonates have complicated paleoclimate reconstructions for decades. A new archive of climate, deep-sea corals, is used to evaluate the calcification processes, independent of photosynthesis, that contribute to these offsets. Carbon and oxygen stable isotope data from six modern deep-sea corals show strong linear trends between δ13C and δ18O. Slopes of these trends between samples are similar and range between 1.9 to 2.6 for Δδ13C/Δδ18O. Linear trends intersect isotopic equilibrium for δ18O and are slightly depleted for δ13C. Variations in the isotopic ratios are strongly correlated with the density banding structure. Isotopically depleted aragonite is associated with light, quickly precipitating bands, whereas isotopically enriched points correspond to slowly accumulating, less dense aragonite. The densest white band at the trabecular center is furthest from isotopic equilibrium for both carbon and oxygen. Data from this region fall off the linear trend between δ18O and δ13C. This deviation, where δ13C remains constant while the δ18O continues to decrease, does not support “vital effect” mechanisms that call upon kinetic fractionation to explain offsets from isotopic equilibrium. We propose a new mechanism for vital effects in these deep-sea corals that is based on a thermodynamic response to a biologically induced pH gradient in the calcifying region. 相似文献
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Edward A. Boyle 《Geochimica et cosmochimica acta》2005,69(21):5165-5166
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Peter J. J. Kamp Fraka J. Harmsen Campbell S. Nelson Susan F. Boyle 《Sedimentary Geology》1988,60(1-4):173-195
Pliocene, non-tropical, widespread and locally thick (up to 100 m) limestones occur in Hawke's Bay, eastern North Island, where they are intimately associated with very thick ( > 5 km), terrigenous-dominated, Neogene sequences that formed in a tectonically active convergent margin setting. The non-tropical character of the limestones is shown unequivocally by (1) the complete dominance of skeletal calcarenites and calcirudites, (2) the occurrence of oyster banks as the only in situ organic structures, (3) the dominance of barnacles, epifaunal molluscs, bryozoans, echinoderms, foraminifers, brachiopods and calcareous red algae as skeletal components, and (4) the preponderance of calcite over aragonite in the mineralogy of the skeletal grains and cements. The abundance of barnacle fragments in the limestones, and the related exclusive occurrence of only one major organic association, a barnacle-(epifaunal) bivalve-bryozoan assemblage, is striking and unusual given the extent of the limestones. Pecten and oyster valves acted as substrates for barnacle attachment, and their growth was promoted by strong tidal paleocurrents that swept the depositional setting: a long (450 km), narrow (30–50 km) forearc basin seaway, which formed between an actively deforming subduction complex to the east and an uplifting structural ridge to the west. Synsedimentary deformation promoted limestone formation on the margins of the seaway by creating current-swept, clastic-free submarine ridges that acted as the sites of carbonate production. Tidal flows dispersed the carbonate constituents and organised them into a wide spectrum of tide-influenced, cross-bedded and horizontal structures. Most spectacular are occurrences of giant tabular cross-beds, with sets 10–40 m thick and foreset dips of 7–36°, some interpreted as the deposits of major sand bars on carbonate deltas marginal to the mouths of saddles traversing the rising antiforms, and others analogous to modern linear sand ridges. The small- to large-scale planar and trough cross-beds, and the horizontal and lenticular beds that are invariably associated with the giant cross-beds and dominate most sections, represent mainly the deposits of sand waves and sand sheets at inner- to mid-shelf depths in the seaway. 相似文献