The geochemistry of Ca,Sr, Ba and Ra sulfates in some deep brines from the Palo Duro Basin,Texas

The geochemistry of Ca, Sr, Ba and Ra sulfates in some deep brines from the Palo Duro Basin of north Texas, was studied to define geochemical controls on radionuclides such as ⁹⁰Sr and ²²⁶Ra. Published solubility data for gypsum, anhydrite, celestite, barite and RaSO₄ were first reevaluated, in most cases using the ion interaction approach of Pitzer, to determine solubility products of the sulfates as a function of temperature and pressure. Ionic strengths of the brines were from 2.9 to 4.8 m, their temperatures and pressures up to 40°C and 130 bars. Saturation indices of the sulfates were computed with the ion-interaction approach in one brine from the arkosic granite wash fades and four from the carbonate Wolfcamp Formation. All five brines are saturated with respect to gypsum, anhydrite and celestite, and three of the five with respect to barite. All are undersaturated by from 5 to 6 orders of magnitude with respect to pure RaSO₄. ²²⁶Ra concentrations in the brines, which ranged from 10^?11.3 to 10^?12.7 m, are not controlled by RaSO₄ solubility or adsorption, but possibly by the solubility of trace Ra solid solutions in sulfates including celestite and barite.     

Petrology of basalts from Loihi Seamount,Hawaii

Loihi Seamount is the southeasternmost active volcano of the Emperor-Hawaii linear volcanic chain. It comprises a spectrum of basalt compositional varieties including basanite, alkali basalt, transitional basalt and tholeiite. Samples from four dredge collections made on Scripps Institution of Oceanography Benthic Expedition in October 1982 are tholeiite. The samples include highly vesicular, olivine-rich basalt and dense glass-rich pillow fragments containing olivine and augite phenocrysts. Both quartz-normative and olivine-normative tholeiites are present. Minor and trace element data indicate relatively high abundances of low partition coefficient elements (e.g., Ti, K, P. Rb, Ba, Zr) and suggest that the samples were derived by relatively small to moderate extent of partial melting, of an undepleted mantle source. Olivine composition, MgO, Cr and Ni abundances, and Mg/(Mg+Fe), are typical of moderately fractionated to relatively unfractionated “primary” magmas. The variations in chemistry between samples cannot be adequately explained by low-pressure fractional crystallization but can be satisfied by minor variations in extent of melting if a homogeneous source is postulated. Alternatively, a heterogeneous source with variable abundances of certain trace elements, or mixing of liquids, may have been involved. Data for ³He/⁴He, presented in a separate paper, implies a mantle plume origin for the helium composition of the Loihi samples. There is little variation in the helium isotope ratio for samples having different compositions and textures. The helium data are not distinctive enough to unequivocally separate the magma sources for the tholeiitic rocks from the other rock types such as Loihi alkalic basalts and the whole source region for Loihi may have a nearly uniform helium compositions even though other element abundances may be variable. Complex petrologic processes including variable melting, fractional crystallization and magma mixing may have blurred original helium isotopic signatures.     

The age of carbonatites,kimberlites and lamprophyres from southern West Greenland: recurrent alkaline magmatism during 2500 million years

Alkaline rocks were intruded into the Precambrian basement in southern West Greenland during at least five separate episodes. The Tupertalik carbonatite intrusion was emplaced around or before 2650 m.y.; it is now metamorphosed in granulite facies but is recognisable by its trace element content. Lamprophyre dykes were intruded at ca. 1800 m.y. and again at ca. 1200 m.y. At ca. 600 m.y. the Sarfartôq carbonatite intrusion and extensive kimberlite dykes were emplaced in the Holsteiborg-Strømfjord region. At 225-115 m.y. the Qaqarssuk carbonatite complex was emplaced in the Sukkertoppen region, and numerous lamprophyre and kimberlite dykes were emplaced between Fishenasset and Ivigtut. All these episodes are correlatable with contemporaneous alkaline activity in Canada and Scandinavia and substantiate the periodicity of carbonatite emplacement. The Mesozoic suite of intrusions is related to rifting prior to continental break-up and the formation of the North Atlantic Ocean. The Eocambrian suite of 600 m.y. is thought to have formed under similar conditions during continental break-up and the formation of the Iapetus ocean.     

大地测量在近代发展的内部地球物理学中的作用

我们的目的是说明大地测量学的近代发展如何为解决地球动力学的基本问题提供新的工具。例如:1.全球规模的重力场的知识将给出关于地幔中过渡带位置的信息,或关于地核-地幔交界面的地形的资料;2.在地球表面上的高精度定位将允许测量构造板块的位移,同时将对地震预报作出贡献;3.用新技术所确定的极移的分析,将能阐明其阻尼问题,维持这一运动的能源问题以及地核-地幔耦合等问题。     

Geology and mineralogy of the Sarfartôq carbonatite complex,southern West Greenland

The Sarfartôq carbonatite complex was emplaced in lower Palaeozoic time in a weakness zone within the Precambrian shield. Dolomitic magma intruded in two major stages of activity. In the first stage a steeply dipping conical body of concentric sheets of rauhaugite was formed, while in the second stage several batches of magma were emplaced into the surrounding marginal shock-zone as concentric and radial beforsite dykes and agglomerates. Hydrothermal activity gave rise to several phases of mineralisation in veins and shear zones. The accompanying fenitisation was of the Na-type. The whole complex covers about 90 km². The main rock-forming minerals are dolomite-ankerite, apatite, orange reversely pleochroic phlogopite, richterite-arfvedsonite and magnetite. Important accessories are pyrochlore, zircon and niobian rutile. A complete mineral list is given, together with microprobe data on mineral chemistry. The dolomitic magmas were poor in SiO₂, Al₂O₃ and K₂O in relation to other carbonatites. Nb, U and LREEs are strongly enriched in pyrochloremineralised zones where the Nb content may be up to 40%. Some shear zones are strongly enriched in Th and HREEs (specifically Eu) and lesser Pb and Zn. Niobium, uranium, rare earth elements and phosphorus occur in economically interesting concentrations.     

Temporal constraints on basin inversion provided by 3D seismic and well data: a case study from the South Viking Graben, offshore Norway

Three-dimensional (3D) seismic, well and biostratigraphic data are integrated to determine the timing of inversion on the hangingwall of the South Viking Graben, offshore Norway. Within the study area two, NW–SE to NE–SW trending normal faults are developed which were active during a Late Jurassic rift event. In the hangingwall of these faults asymmetric, 2–5 km wide anticlines are developed which trend parallel to the adjacent faults and are interpreted as growth folds formed in response to compressional shortening (inversion) of the syn-rift basin-fill. Marked thickness variations are observed in Late Jurassic and Early Cretaceous growth strata with respect to the inversion-related folds, with seismic data indicating onlap and thinning of these units across the folds. In addition, well data suggests that not only are erosional surfaces only locally developed towards the crests of the folds, but these surfaces may also truncate underlying flooding surfaces towards the fold crests. Taken together, these observations indicate that inversion and growth of inversion-related structures initiated in the late Early Volgian and continued until the Late Albian. Furthermore, it is demonstrated that individual folds amplified and propagated laterally through time, and that fold growth was not synchronous across the study area. This study demonstrates that the temporal evolution of structures associated with the inversion of sedimentary basins can be accurately determined through the integration of 3D seismic, well and biostratigraphic data. Furthermore, this study has local implications for constraining the timing of inversion within the South Viking Graben during the Late Mesozoic.     

Sur l'influence de la loi de répartition des densités à l'intérieur de la Terre dans les variations luni-solaires de la gravité en un point

Résumé Les observations des variations luni-solaires de la gravité en divers points du globe ne donnent pas des valuers très concordantes pour le facteur lié au module de rigidité de la Terre. On démontre ici que la répartition croissante des densités vers le centre de la Terre a pour conséquence d'amplifier encore les effets dus à l'élasticité. En adoptant la répartition deBullen, on aurait =1+0.244h>1, (h étant le premier nombre deLove). En outre une relation simple lie les facteurs et (déviations de la verticale). La valuer deh déduite de telles observations ne peut conduire directement à une valeur significative du module de rigidité du globe car il faut encore tenir compte des variations de la période et de l'amplitude du mouvement chandlérien du pôle.

---

Summary Observations of luni-solar variations of gravity at various points of the Earth do not give values in agreement for the factor bound to the Earth's modulus of rigidity. It is shown here that the law of increasing of density toward the center of the Earth emphasizes the effect of elasticity: following the law ofBullen, we should have =1+0.244h>1, (h is the firstLove's number). Further, there is a simple relation between the factors and (deviations of the vertical). The value ofh deduced from such observations could not give directly a significative value of the modulus of rigidity because we must take into account the variations of period and amplitude of the chandlerian motion of the pole.

---

Riassunto Le osservazioni delle variazioni luni-solari della gravità in diversi punti della Terra non dànno valori concordanti per il fattore legato al modulo di rigidità del Globo. Si dimostra che la ripartizione crescente della densità verso il centro della Terra ha per conseguenza di amplificare ancora gli effetti dell'elasticità; adottando la legge diBullen, abbiamo =1+0.244h>1, (h essendo il primo numero diLove). Inoltre, una semplice relazione lega i fattori e (deviazioni della verticale). Il valore dih dedotto da tali osservazioni non può condurre ad un valore significativo del modulo di rigidità del Globo poiché bisogna considerare anche le variazioni del periodo e dell'ampiezza del moto polare diChandler.

     

Petrology of mugearite-hawaiite: Early extrusives in the 1973 Heimaey eruption,Iceland

Rocks which erupted during the first few weeks are described and chemical analyses of rocks and microprobe analyses of minerals are presented. An outline of the eruption history and of the geology of the area is given. A gradational change in chemistry from mugearitic to hawaiitic composition is recorded. Xenoliths of hypersthene gabbro not cognate with magma were discovered in the mugearite. One xenolith has reacted with the mugearite magma at depth to form pargasitic hornblende and kaersutite. It is argued that the magma reacted with the xenoliths at a total pressure well below 8–9 kbar and at a gas pressure higher 1 kbar.     

A trans-world tidal gravity profile

Tidal recordings have been made with high-precision equipment at twenty-eight stations in the South East Asia and the South Pacific areas. Each station was occupied for five months or more. Amplitude factors (δ) and phase differences (α) of the principal tidal constituents exhibit a regional behaviour which results from the oceanic-tide interaction. At Alice Springs, Northern Territory, the middle point of Australia, the results based upon nine month's observations fit fairly well the Molodensky theory on the dynamical effects of the liquid core of the earth.