A New Retracking Technique for Brown Peaky Altimetric Waveforms

A new Brown-Peaky (BP) retracker has been developed for peaky waveforms that usually appear within ～10 km to the coastline. The main feature of the BP is that it fits peaky waveforms using the Brown model without introducing a peak function. The retracking strategy first detects the peak location and width of a waveform using an adaptive peak detection method, and then estimates retracking parameters using a weighted least squares (WLS) estimator. The WLS assigns a downsized weight to corrupted waveform gates, but an equal weight to other normal waveform gates. The BP retracker has been applied to 4-year Jason-1 waveform (2002–2006) in two Australian coastal zones. The results retracked by BP, MLE4 and ALES retrackers have been validated against tide-gauge observations located at Burnie, Lorne and Broome. The comparison results show that three retrackers have similar performance over open oceans with the correlation coefficient (～0.7) and RMSE (～13 cm) between altimetric and tide-gauge sea levels for distance >7 km offshore. The main improvement of BP retracker occurs for distance ≤7 km to the coastline, where validation results indicate that data retracked by BP are more accurate (15–21 cm) than those by ALES (16–24 cm) and MLE4 (19–37 cm).     

卫星测高不同波形重构方法的偏差特性分析

利用我国近海4条轨迹、40个周期EnviSat-1的卫星测高波形数据,采用OCOG、Threshold、5-β参数算法以及Ocean法进行波形重构计算。根据不同轨迹和周期的波形数据,由上述四种方法重构海面高并计算相互之间的偏差及其中误差。结果表明,OCOG、Threshold、5-β参数算法与Ocean方法之间的偏差分别为88.46cm、35.90cm和25.83cm,相应的中误差分别为2.11cm、1.96cm和0.41cm,而且该偏差量对于不同的轨迹和周期是不变的。因此,只要对系统偏差进行改正,就能融合不同波形重构方法求得海面高,充分发挥不同波形重构方法在不同海区的优势,为近岸海域海平面变化,大地水准面的研究提供高精度的资料。     

A new preparation process of coal-based magnetically activated carbon

Fe/C-based magnetically activated carbon （MAC） was obtained by carbonizing and activating its precursor, that was prepared by co-precipitation of anthracite coal impregnated in ferric chloride solution. The effect of the concentrations of FeC13 and pH of solution on BET surface area, pore volume and magnetic properties of the MAC was studied by BET N2 adsorption and VSM method. The results indicated that the magnetization of MAC gradually increases with increasing concentration of FeC13 and pH value of solution, and BET surface area was inclined to fluctuation. The largest BET surface area and magnetization of MAC were 1327.5 m2/g and 35.56 emu/g, respec- tively. The form of magnetic matter in the magnetically activated carbon was mainly Fe3C by X-ray powder diffrac- tion （XRD） and magnetic attraction test.     

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森林航空摄影比例尺和森林判读像片放大倍数的研究

为了确定森林航空摄影的最佳比例尺和波段以及判读像片的放大倍数,我们在广东省南昆山林业遥感试验场,测定了地物光谱,拍摄了不同比例尺的多光谱片和彩色红外片,进行了内业判读、野外检测和综合分析。本文讨论了航空摄影机、胶片、地物光谱反射系数和摄影位移等因素对像片分辨力的影响,用经验关系式估算了南昆山像片的影像分辨力,阐述了内业判读和实地检测的情况。试验表明,在所试验的波长附围内绿波段表达森林影像的效果最佳,用于森林判读的影像分辨力宜放大到3.5线/毫米,若用新型航空摄影机和高分辨力胶片,则用于森林资源调查分类判读的像片比例尺可缩小到1:4.8万。     

长江口EnviSat测高数据的波形分类重构分析

采用波形分类重构算法处理EnviSat卫星从2002年10月至2010年5月在长江口近岸海域28°N~32°N、121°E~125°E范围内的波形数据。该区域内海洋波形、波形后缘前端出现峰值的波形、波形后缘后端出现峰值的波形、似镜面波形和复杂波形分别占89.03%、2.95%、0.45%、3.31%和4.26%。根据不同的波形类别采用不同波形算法进行波形重构。同时,分析了不同重构算法之间的系统偏差,并据此确定OCOG算法、Threshold算法和子波形算法的最优阈值水平分别为65%、45%和50%。重构结果表明,波形分类重构算法优于其他波形重构算法,能有效改善原始海面高的精度,改善程度在16.62%~53.86%之间。此外,重构后交叉点差值小于重构前的交叉点差值,与轨迹P089、P411形成的交叉点的海面高差值由1m降低到25cm左右,其余交叉点的差值均在2~6cm。     

Separation of Heavy Lanthanoids by Flash Column Chromatography for Precise Determination of Er and Yb Isotope Compositions in Rock Samples

We present a new column chemistry technique for the quantitative separation of heavy lanthanoids by an ultra‐fine‐grained LN resin (20–50 µm) with a specific emphasis on the purification of Er and Yb for their isotopic analysis. To achieve the quantitative separation of Er and Yb within a reasonable timescale, flash column chromatography was applied, where the column was attached to a newly designed vacuum box system, thus accelerating the elution speed by ten times compared with that of the normal column procedure operated by gravity flow. The recovery yields of Er and Yb were confirmed to be approximately 100%, which is important to suppress the effect of the mass‐independent fractionation of the Er and Yb isotopes during chromatography. Additionally, we have developed precise Er and Yb isotope measurements by thermal ionisation mass spectrometry (TIMS) using multistatic and/or dynamic methods. Moreover, in most cases, the Er and Yb isotope compositions of the measured four terrestrial rock samples were indistinguishable from those of the commercially available Er and Yb Alfa Aesar solutions. The new method presented in this work will be useful for future studies on heavy lanthanoids in various geological materials.     

Chemical forms of zinc in sea water

Recent experimental evidence concerning the chemical forms of zinc occurring in sea water is reviewed in order to aid in the systematic understanding of zinc geochemistry in the marine environment. The review indicates the necessity of systematizing the results obtained by different methods for the determination of zinc in sea water with respect to the chemical nature of the zinc fractions measured. Analytical procedures for the zinc determinations in sea water by spectrophotometry with dithizone extraction and anodic stripping voltammetry with composite mercury graphite electrodes are described. By using these methods, various pre-treatment tests were carried out to relate the results of different modes of measurements to the chemical forms of zinc involved. The comparisons of the results of these tests lead to an estimation of the occurrence of the following categories of chemical forms of zinc in sea water: (1) ionic plus labile form, (2) inorganic complexes and colloids as well as weak organic complexes and (3) occuled fraction in large organic molecules and/or organic colloids. Capabilities of different analytical procedures for differentiating one category from another are discussed.     

The Positive Indian Ocean Dipole–like Response in the Tropical Indian Ocean to Global Warming

Climate models project a positive Indian Ocean Dipole(p IOD)–like SST response in the tropical Indian Ocean to global warming. By employing the Community Earth System Model and applying an overriding technique to its ocean component(version 2 of the Parallel Ocean Program), this study investigates the similarities and differences of the formation mechanisms for the changes in the tropical Indian Ocean during the p IOD versus global warming. Results show that their formation processes and related seasonality are quite similar; in particular, wind–thermocline–SST feedback is the leading mechanism in producing the anomalous cooling over the eastern tropics in both cases. Some differences are also found, including the fact that the cooling effect of the vertical advection over the eastern tropical Indian Ocean is dominated by the anomalous vertical velocity during the p IOD but by the anomalous upper-ocean stratification under global warming. These findings are further examined through an analysis of the mixed layer heat budget.     

Delivery of transuranic elements by rain to the Mediterranean Sea

The concentrations of ²³⁸Pu, ^{239 + 240}Pu, ²⁴¹Am and ¹³⁷Cs were determined in rain samples collected at Monaco in the course of 1978–1979. Based on these data, the annual deliveries of these radionuclides to the Mediterranean by rain are computed to be 0.18 ± 0.01 pCim^?2 for ²³⁸Pu, 8.1 ± 0.1 pCim^?2 for ^{239 + 240}Pu, 0.58 ± 0.02 pCim^?2 for ²⁴¹Am and 351 ± 4 pCim^?2 for ¹³⁷Cs.Comparing the delivery data with the mixed layer inventories of ^{239 + 240}Pu and ²⁴¹Am in the Mediterranean, the upper limits of the mean residence time of these radionuclides in the mixed layer were estimated to be 12.3 yr for ^{239 + 240}pu and 2.9 yr for ²⁴¹Am. These values are consistent with the conclusion deduced from the vertical distribution pattern of these transuranic elements in the Mediterranean.Based on delivery values, the annual activity ratios for ${}^{238}\text{pu}{}^{\mathrm{239\; +\; 240}}\text{Pu}$, ${}^{241}\text{Am}{}^{\mathrm{239\; +\; 240}}\text{Pu}$ and ${}^{\mathrm{239\; +\; 240}}\text{pu}{}^{137}\text{Cs}$ are found to be 0,022, 0.072 and 0.023 respectively. The ${}^{238}\text{pu}{}^{\mathrm{239\; +\; 240}}\text{pu}$ and ${}^{\mathrm{239\; +\; 240}}\text{Pu}{}^{137}\text{Cs}$ activity ratios vary within relatively narrow ranges with time, while a much wider variation was observed for the ${}^{241}\text{Am}{}^{\mathrm{239\; +\; 240}}\text{Pu}$ activity ratio. The cause of the wider variation of the ${}^{241}\text{Am}{}^{\mathrm{239\; +\; 240}}\text{Pu}$ ratio may be related to the difference in the mean age of fallout brought down in different seasons.