Impact of mercury emissions from incineration of automobile shredder residue in Japan

Mercury emissions from the incineration of automobile shredder residues (ASRs) were investigated. Continuous monitoring of elemental and reactive gaseous Hg in flue gas was performed in lab-scale and plant-scale ASR incineration. Results of continuous monitoring agreed with those obtained using the JIS K0222 method and Ontario-Hydro method. Before cleaning by air pollutant control devices (APCDs), reactive Hg was the dominant form of that element in both lab-scale and plant-scale results. Emission factors of reactive Hg before APCDs estimated from monitoring results showed large differences between plant-scale and lab-scale emissions. The emission factor in the plant scale was more than 10 times larger than that in the lab-scale, which is explainable by the different Hg contents of ASR. Based on plant-scale monitoring at the stack, emission factors after APCDs were estimated as 0.79 mg-Hg/Mg-ASR for elemental Hg and 6.8 mg-Hg/Mg-ASR for reactive Hg. Using these emission factors, total Hg emissions from ASR incineration were estimated as 2.2 kg/a. An ASR incineration plant investigated in this study used highly effective APCDs. Consequently, these emission factors might result in underestimation of national Hg emissions from ASR incineration. Emission factors estimated from lab-scale monitoring at a fabric filter outlet side might be more appropriate. However, even if emission factors calculated from plant-scale or the lab-scale monitoring are used, estimated emissions are still less than 1.0% of total Hg emissions in Japan. Therefore, Hg emissions from ASR incineration can be evaluated as insignificant. Unless Hg contents of ASR increase extremely, ASR incineration would be a minor source of Hg atmospheric emission in Japan, even if all ASRs were incinerated.     

Strain field measurements of rubber by image analysis and design criteria for laminated rubber bearings (LRB)

Although seismic isolation rubber bearings in bridges and buildings have proven to be a very effective passive method for reducing earthquake‐induced forces, a detailed mechanical modeling of the rubber that is used in bearings under large strains has not been established. Therefore, a 3D model of failure behavior and the design criteria for the safety evaluation of seismic isolation bearings have not yet been developed. This paper presents: (1) correlation‐based template‐matching algorithms to measure large strain fields of continua; (2) a failure criterion for rubber; and (3) the design criteria for the safety evaluation of laminated algorithms, data‐validation algorithms were developed and implemented to eliminate possible unrealistic displacement vectors present in the measured displacement field. The algorithms were successfully employed in the strain field measurement of LRB and rubber materials that are subjected to failure. The measured local strains for rubber material at failure were used to develop a failure criterion for rubber. The validity of the proposed criterion was evaluated by applying it to the LRB; the criterion was introduced into a 3D finite element model of LRB, compared with the experimental results of bearings failure, and verified. Finally, design criteria are proposed for LRB for the safety evaluation. Copyright © 2003 John Wiley & Sons, Ltd.     

Changes in Earth’s Energy Flows and Clouds in 228-Year Simulation with a High-Resolution AGCM

We have examined long-term changes in Earth’s energy flows at top of the atmosphere (TOA) and at Earth’s surface (land and ocean) by using 228-year simulation of a high-resolution global atmosphere model, MRI-AGCM3.2. It is found that the net downward short wave (SW) radiation (absorbed solar radiation, ASR) at TOA significantly increases during twenty-first century in agreement with a previous study. However, in the present study, the reason for the change is an increase in clear sky SW absorption by increased water vapor in the atmosphere, while it is a decrease in cloud amount in the previous study. It is also found that the long wave (LW) cloud radiative forcing for atmosphere is positive and increasing during twenty-first century in agreement with a previous study. The reason for the change in the present study is an increase in absorption by water vapor of the downward LW radiation emitted from clouds, while it is reductions of cloud amount in the middle troposphere in the previous study.     

Dynamics of pelagic variables in two contrasting coastal systems in the western Hokkaido coast off Otaru port,Japan

Human impact on adjacent coastal waters, leading to alteration in nutritional environment and hence affecting phytoplankton biomass (Chlorophyll a), will probably be enhanced by the nearby presence of ports. The main goal of this study is to assess the influence of nearby presence of port on phytoplankton biomass build-up and the physical–chemical environmental characteristics in two contrasting coastal systems (Otaru port, S-IN and an exposed coastal area, S-OUT) in the western Hokkaido coast off Otaru port, Japan. Sampling was conducted on “bi-weekly and monthly” basis during the period of September 2006–December 2007 and data comprising 11 pelagic variables were obtained. In most instance, phytoplankton biomass, nutrients' (NH₄, NO₃, PO₄, and Si(OH)₄) concentrations and nutrients' molar ratios were higher at the Otaru port location. Physical parameters (temperature, salinity, hydrogen ion concentration (pH), photosynthetically active radiation (PAR) and dissolved oxygen, (DO)) were not significantly different (P > 0.05) between the two locations. With the exception of salinity, pH and DIC, all variables measured showed significant variation (P < 0.05) with season. While the coefficient of variation (CV) of physical parameters and phytoplankton biomass were relatively higher in Otaru port location (S-IN), the exposed coastal location (S-OUT) showed a higher variation in chemical parameters. Other variables showed different patterns between the two locations. We conclude that ports, due to its activities and restricted circulation favour high nutrient loading and phytoplankton biomass build-up in adjacent coastal systems, thus, suggesting the need for continuous field observation data in order to advance our knowledge on possible future human impact on coastal environment and the need to monitor and control port activities.     

Two strong radio bursts at high and medium Galactic latitude

The Nasu Observatory, which is composed of eight 20 m elements, was constructed for observing radio transients over a wide field at 1400 MHz. We report on two radio transients detected in consecutive drift scanning observations at declination 32° over a period of about two months. One of the two transients, WJN J1039+3200, appeared at =10^h39^m40^s±10^s, δ=32°±0.4° on March 4, 2005, and the other one, WJN J0645+3200, appeared at =06^h45^m25^s±10^s, δ=32°±0.4° on March 24, 2005. Both exhibited flux densities in excess of 1 Jy, and the burst durations were up to two days. Since there are few examples of radio transients outside the Galactic plane, these are very important observations. We have previously reported on four radio transients with features that look like the two transients detected this time. Of these six WJN transients in total, five had a duration of up to two days, and one up to three days. Four of the transients were detected at high Galactic latitude of b > 30°. Counterparts of the six WJN transients included X-ray sources in four events and had a consistency of 66%. The consistency of γ-ray, PGC Galaxy, NVSS, and FIRST sources was concentrated at about 50%. We were not able to find any special features in the counterparts. The distribution was verified by making a log N–log S plot using data for the four previously detected transients and the new ones. As a result, the distribution of the radio transients that we observed might have an isotropic distribution not dependent on Galactic longitude and Galactic latitude. The detection probability was calculated based on the assumption of an isotropic distribution. The 2σ upper probability limit for detection of transients of 1000 mJy or more is 0.0049 [deg⁻² yr⁻¹]. We cannot yet identify these two radio transients, because their features are different from any radio bursts observed in the past.     

Thermal anomalies associated with shallow gas hydrates in the K-2 mud volcano, Lake Baikal

Thermal measurements and hydrate mapping in the vicinity of the K-2 mud volcano in Lake Baikal have revealed a particular type of association of thermal anomalies (29–121?mW?m^–2) near hydrate-forming layers. Detailed coring within K-2 showed that hydrates are restricted to two distinct zones at sub-bottom depths exceeding 70–300?cm. Temperature data from stations with hydrate recovery and degassing features all display low thermal gradients. Otherwise, the thermal gradients within the mud volcano are generally increased. These findings imply a more complicated thermal regime than often assumed for mud volcanoes, with important roles for both fluids and hydrates. The coexistence of neighbouring low and high thermal anomalies is interpreted to result from discharging and recharging fluid activity, rather than hydrate thermodynamics. It is suggested that hydrates play a key role in controlling the fluid circulation pattern at an early stage. At a later stage, the inflow of undersaturated lake water would favour the dissolution of structure I hydrates and the formation of structure II hydrates, the latter having been observed on top of structure I hydrates in the K-2 mud volcano.     

Are numerical weather model outputs helpful to reduce tropospheric delay signals in InSAR data?

Interferometric synthetic aperture radar phase data include not only signals due to crustal movements, but also those associated with microwave propagation delay through the atmosphere. In particular, the effect of water vapor can generate apparent signals in the order of a few centimeters or more, and prevent us from detecting such geophysical signals as those due to secular crustal deformation. To examine if and to what extent numerical weather model (NWM) outputs are helpful to reduce the tropospheric delay signals at spatial scales of 5–50 km wavelengths, we compared three approaches of tropospheric signal reduction, using 54 interferograms in central Hokkaido, Japan. The first approach is the conventional topography-correlated delay correction that is based on the regional digital elevation model (DEM). The second approach is based on the Japan Meteorological Agency’s operational meso-scale analysis model (MSM) data, where we compute tropospheric delays and subtract them from the interferogram. However, the MSM data are available at predefined epochs and their spatial resolution is about 10 km; therefore, we need to interpolate both temporally and spatially to match with interferograms. Expecting to obtain a more physically plausible reduction of the tropospheric effects, we ran a 1-km mesh high-resolution numerical weather model WRF (Weather Research and Forecasting model) by ourselves, using the MSM data as the initial and boundary conditions. The third approach is similar to the second approach, except that we make use of the WRF-based tropospheric data. Results show that if the topography-correlated phases are significant, both the conventional DEM-based approach and the MSM-based approach reveal comparable performances. However, when the topography-correlated phases are insignificant, none of the approaches can efficiently reduce the tropospheric phases. Although it could reduce the tropospheric signals in a local area, in none of the case studies did the WRF model produce the “best” performance. Whereas the global atmospheric model outputs are shown to be effective in reducing long-wavelength tropospheric signals, we consider that further improvements are needed for the initial and boundary condition data for high-resolution NWM, so that the NWM-based approach will become more reliable even in the case of a non-stratified troposphere.     

Crystallization of authigenic carbonates in mud volcanoes at Lake Baikal

This paper presents data on authigenic siderite first found in surface sediments from mud volcanoes in the Central (K-2) and Southern (Malen’kii) basins of Lake Baikal. Ca is the predominant cation, which substitutes Fe in the crystalline lattice of siderite. The enrichment of the carbonates in the ¹³C isotope (from +3.3 to +6.8‰ for the Malen’kii volcano and from +17.7 to +21.9‰ for K-2) results from the crystallization of the carbonates during methane generation via the bacterial destruction of organic matter (acetate). The overall depletion of the carbonates in ¹⁸O is mainly inherited from the isotopic composition of Baikal water.     

Estimation of surface soil water content from surface temperatures in dust source regions of Mongolia and China

Surface conditions, such as surface roughness and soil moisture, control wind erosion and dust emission in northeast Asia. Data on spatial and temporal changes of surface soil water content are needed for dust-modeling systems used to predict dust events with the aim of preventing damage from them. A modified temperature-vegetation dryness index (MTVDI) was tested to see if it could reproduce surface soil water contents measured during the dust event season in Bayan Unjuul, Mongolia, and Shenmu, China. MTVDI was calculated from land surface temperature and aerodynamic minimum and maximum surface temperatures estimated from meteorological data. The standard deviation of the error of estimations of soil water content from MTVDI was ±1.5% in Bayan Unjuul when soil water content was lower than 4%. This compares favorably with the observational error of ±1% of the soil moisture sensors used.     

Raman spectroscopic and calorimetric observations on natural gas hydrates with cubic structures I and II obtained from Lake Baikal

This study reports measurements of the Raman spectra of Lake Baikal gas hydrates and estimations of the hydration number of methane-rich samples. The hydration number of gas hydrates retrieved from the southern Baikal Basin (crystallographic structure I) was approx. 6.1. Consistent with previous results, the Raman spectra of gas hydrates retrieved from the Kukuy K-2 mud volcano in the central Baikal Basin indicated the existence of crystallographic structures I and II. Measurements of the dissociation heat of Lake Baikal gas hydrates by calorimetry (from the decomposition of gas hydrates to gas and water), employing the hydration number, revealed values of 53.7–55.5?kJ?mol^–1 for the southern basin samples (structure I), and of 54.3–55.5?kJ?mol^–1 for the structure I hydrates and 62.8–64.2?kJ?mol^–1 for the structure II hydrates from the Kukuy K-2 mud volcano.