The sediment load and deposition by river discharge and their relation to organochlorine pesticides pollutants in the sediment bottom of Nha Trang Bay,Vietnam

Ocean Science Journal - Based on previous results from the “River reef impact studies project that was carried out as a co-operation programme between ZMT (Germany) and NIO (Vietnam) from...     

Electrical resistivity and 57Fe Mössbauer spectra of Fe-bearing calcic amphiboles

Electrical resistivity and ⁵⁷Fe Mössbauer spectra are reported for three calcic amphiboles with different Fe concentrations. AC measurements (20?Hz–1?MHz) were performed, applying impedance spectroscopy between 100 and 785?°C in an N₂ gas atmosphere. It was found that up to three semiconducting charge transport processes can be distinguished, which in part changed slightly when several runs were carried out to higher temperatures. The extrapolated DC resistivity is much smaller for an amphibole with high Fe content than for the two with lower Fe concentrations. The derived activation energies are between ～0.48 and ～1.06?eV. For temperatures ≤600?°C the results are compatible with a charge transport mechanism due to electron hopping between Fe²⁺ and Fe³⁺. Above 600?°C, dehydrogenation and/or beginning amphibole decomposition obviously alter the conduction mechanism. From Mössbauer spectra it was established that in all amphibole samples Fe²⁺ and Fe³⁺ are simultaneously present. Mössbauer parameters were derived by fitting the observed spectra to models taking the occupation of various M sites into account.     

Electrical conductivity,thermopower and <Superscript>57</Superscript>Fe Mössbauer spectroscopy of aegirine (NaFeSi<Subscript>2</Subscript>O<Subscript>6</Subscript>)

DC and AC electrical conductivities were measured on samples of two different crystals of the mineral aegirine (NaFeSi₂O₆) parallel () and perpendicular () to the [001] direction of the clinopyroxene structure between 200 and 600 K. Impedance spectroscopy was applied (20 Hz–1 MHz) and the bulk DC conductivity _DC was determined by extrapolating AC data to zero frequency. In both directions, the log _DC – 1/T curves bend slightly. In the high- and low-temperature limits, differential activation energies were derived for measurements [001] of E_A 0.45 and 0.35 eV, respectively, and the numbers [001] are very similar. The value of _DC [001] with _DC(300 K) 2.0 × 10^{–6 –1}cm^–1 is by a factor of 2–10 above that measured [001], depending on temperature, which means anisotropic charge transport. Below 350 K, the AC conductivity () (/2=frequency) is enhanced relative to _DC for both directions with an increasing difference for rising frequencies on lowering the temperature. An approximate power law for () is noted at higher frequencies and low temperatures with () ^s, which is frequently observed on amorphous and disordered semiconductors. Scaling of () data is possible with reference to _DC, which results in a quasi-universal curve for different temperatures. An attempt was made to discuss DC and AC results in the light of theoretical models of hopping charge transport and of a possible Fe²⁺ Fe³⁺ electron hopping mechanism. The thermopower (Seebeck effect) in the temperature range 360 K < T <770 K is negative in both directions. There is a linear – 1/T relationship above 400 K with activation energy E 0.030 eV [001] and 0.070 eV [001]. ⁵⁷Fe Mössbauer spectroscopy was applied to detect Fe²⁺ in addition to the dominating concentration of Fe³⁺.     

Electrical conductivity, thermopower and 57Fe Mössbauer spectroscopy of an Fe-rich amphibole, arfvedsonite

The electrical charge transport was examined in an Fe-rich amphibole, arfvedsonite, using frequency dependent AC resistivity (impedance spectroscopy) and thermopower Θ measurements in the temperature range 30–800°C. Two different semiconducting charge transfer mechanisms were observed which are due to volume conduction for measurements parallel and perpendicular to the [001] direction; they arise probably from a conduction mechanism related to lattice defects, both with activation energies E_A ≈ 0.4 eV. The extrapolated DC conductivity, for a fixed temperature, along [001] is about 5–6 times higher than that perpendicular to [001]. From the temperature independent positive Θ values it follows that hole conduction occurs, and a hopping-type charge transport is acting, probably effected by electron hopping Fe²⁺ → Fe³⁺. Possible charge transfer paths are discussed. ⁵⁷Fe Mössbauer spectra enabled to determine the relative concentrations of Fe²⁺ and Fe³⁺. From a comparison of these data and from Θ results it is concluded that the main fraction of Fe²⁺ and Fe³⁺ take part in long range charge transport.     

Korallen,Fischer und Touristen

Ocean Dynamics - Als Folge von natürlichen und anthropogenen Störungen sind Korallenriffe weltweit gefährdet. Im vorliegenden Vortrag wird von zwei sehr wesentlichen menschlichen...     

A 1642 Ma age for the Fraynes Formation,Birrindudu Basin,confirms correlation with the economically significant Barney Creek Formation,McArthur Basin,Northern Territory

Abstract

An interpreted CA–IDTIMS age of 1642.2?±?3.9?Ma for a volcanogenic tuffaceous siltstone from the previously undated Fraynes Formation of the Birrindudu Basin in the northwestern Northern Territory enables a rigorous chronostratigraphic correlation to be made with the economically important Barney Creek Formation of the southern McArthur Basin. This result supports previous interpretations that these geographically widely separated formations are probably linked in the subsurface. It also establishes the stratigraphic interval encompassing the Fraynes and Barney Creek formations as a potential target for greenfields base metals and petroleum exploration programs across the greater McArthur Basin.

• KEY POINTS

• A new interpreted CA–IDTIMS age provides a chronostratigraphic link between the Fraynes Formation of the Birrindudu Basin and the economically important Barney Creek Formation of the southern McArthur Basin.

• The Fraynes and Barney Creek formations are probably linked in the subsurface.

• This stratigraphic level is a potential target for greenfields base metals and petroleum exploration across the greater McArthur Basin.