Stratiform and vein U,Mo and Cu mineralization in the Novoveská Huta area,CSFR

U-Mo and Cu mineralization occurs in horizons as well as in veins in the Permian formations near Novoveská Huta. Ore mineralization is represented by uraninite, U-Ti oxides, coffinite, molybdenite, chalcopyrite, tennantite and pyrite. The isotopic composition of S and C displays a larger variability in the stratiform ores (³⁴S from –32.7 to +2.7 and ¹³C from –27.1 to — 0.5) These data suggest mixing of meteoric solutions with fluids of volcanic origin and a complex history. There is a narrower range of ³⁴S from –18.8 to –4.6 and ¹³C from –6.3 to –2.5% in quartz-carbonate veins with Cu mineralization suggesting a deep source of ore-bearing solutions. The Permian volcanics were a significant source of ore elements.Their contents of U, Mo, Cu and Y are from two to eight times higher than in sedimentary rocks. Accumulations of ore elements in the horizons were formed by the reduction and adsorption processes 240 ± 30 Ma ago according to U-Pb isotopic dating. Due to Alpine tectonism, these low-grade ores (U<0.1 wt%) were remobilized and higher-grade U-Mo ores (U>0.1 wt%) were formed 130 ± 20 Ma ago at temperatures ranging from 110 to 120° C, according to fluid inclusions. Younger veins with Cu mineralization were formed 115 ± 10 Ma according to the model age of Pb at temperatures ranging from 95 to 190°C.     

Surface effects of triggered fault slip on Reykjanes Peninsula, SW Iceland

Three large earthquakes (M_w>4.5) were triggered within 5 min, 85 km west of a M_w 6.5 earthquake in the South Iceland Seismic Zone (SISZ). We report on surface effects of these triggered earthquakes, which include fresh rupture, widespread rockfall, disrupted rockslides and block slides. Field data confirm that the earthquakes occurred along N-striking right-lateral strike-slip faults. Field data also support the conclusion from modeling of InSAR data that deformation from the second triggered event was more significant than for the other two. A major hydrological effect was the draining of water through an open fissure on a lake bed, lowering the lake level by greater than 4 m. Field relationships suggest that a component of aseismic slip could have been facilitated by water draining into the fault zone.     

Ecophysiology of the saguaro cactus (Carnegiea gigantea) in the Saguaro National Monument: relationship to symptoms of decline

The purpose of this study was to examine physiological correlates to the phenomenon of epidermal browning and saguaro decline in Saguaro National Monument. Gas exchange characteristics, surface temperatures, and the extent of epidermal browning in tissues of both healthy and declining saguaro cacti (Carnegiea gigantea) at different solar orientations were examined in eight long-term monitoring plots in the Rincon Mountain District of the Saguaro National Monument near Tucson, Arizona during both wet and dry seasons and years.Daily maximum surface temperatures were greatest on west-oriented tissues, as predicted by a simple model. However, south- and south-west-oriented tissues showed the highest browning indices, suggesting that browning may be more related to cumulative thermal loading than to extreme late afternoon temperature events. During the wet season, maximum nocturnal CO₂uptake rates and total nocturnal CO₂uptake were negatively correlated with browning index. Uptake rates during dry seasons and dry years was minimal, and not related to browning indices. However, healthy tissues of saguaros that also had tissues with high browning indices had wet-season maximum CO₂uptake rates as high as saguaros without damaged tissues, suggesting that the browning is not systemic but rather is tissue- and angle-specific. Instantaneous measures of water-use efficiency did not vary significantly or predictably by angle, but rather were greatest during night-time and in tissues when CO₂uptake was greatest. We suggest that browning symptoms on cacti are most likely due to natural abiotic stress, and are unrelated to systemic pollution stress or increased UV-B radiation.     

Greenhouse Gas Emissions and Costs over the Life Cycle of Wood and Alternative Flooring Materials

Increased use of wood can substitute more energy demanding products and thus contribute to a long-term solution to the global warming problem. The aim of this article is to provide an empirical study on this substitution impact, its cost-effectiveness, and which methodological assumptions that are of highest importance for the results obtained. We have made a case study where we compare use of various flooring materials. The results show that floor covering in solid oak causes lower greenhouse gas (GHG) emissions than the other materials. The difference can be ranked in the following order, after their potential for reduction in GHG emissions: Carpet in wool, carpet in polyamide, vinyl, and linoleum. At 2% pro anno discount rate, the avoided GHG emission in tons per m³ of oak flooring used is 0.1–1.9 for linoleum, and 11.8–15.5 for wool carpets. Unless the solution in solid oak is on total less expensive over the lifetime of the building, only the price of avoided emissions from a substitution between solid oak and carpet in wool is reasonable, compared to present carbon fees. The assumptions that influence the result most are choice of discount rate, carbon fixation on forest area, and waste handling. Empirical case studies like this indicate GHG emission reduction potentials caused by substitution, but should be complemented by dynamic input/output analyses and econometric studies. To analyse the flow of CO₂ over time, they should also be linked to forest management models.     

Arsenic mobility in alteration products of sulfide-rich, arsenopyrite-bearing mine wastes, Snow Lake, Manitoba, Canada

The Arsenopyrite Residue Stockpile (ARS) in Snow Lake, Manitoba contains approximately 250,000 tons of cyanide treated, refractory arsenopyrite ore concentrate. The residue was deposited between 1950 and 1959 in an open waste rock impoundment, and remained exposed until 2000, when the pile was capped with layers of waste rock and clay. During the time when the ARS was exposed to the atmosphere, arsenopyrite, pyrrhotite, pyrite and chalcopyrite were oxidized producing scorodite, jarosite and two generations of amorphous Fe sulfo-arsenates (AISA). These secondary phases attenuated some of the As released to pore water during oxidation in the upper layers of the ARS. The imposition of the cap prevented further oxidation. The secondary As minerals are not stable in the reduced environment that currently dominates the pile. Therefore, As currently is being released into the groundwater. Water in an adjacent monitoring well has concentrations of >20 mg/L total As with relative predominance of As(III).     

An adjoint-based optimization method for gas production in shale reservoirs

In this work, we consider a new model for flow in a multiporosity shale gas reservoir constructed within the framework of an upscaling procedure where hydraulic fractures are treated as (\(n-1\)) interfaces (\(n=2,3\)). Within this framework, the hydrodynamics is governed by a new pressure equation in the shale matrix which is treated as a homogenized porous medium composed of organic matter (kerogen aggregates with nanopores) and inorganic impermeable solid (clay, calcite, quartz) separated from each other by a network of interparticle pores of micrometer size. The solution of the pressure equation is strongly influenced by the constitutive response of the retardation parameter and effective hydraulic conductivity where the former incorporates gas adsorption/desorption in the nanopores of the kerogen. By focusing our analyses on this nonlinear diffusion equation in the domain occupied by the shale matrix, an optimization strategy seated on the adjoint sensitivity method is developed to minimize a cost functional related to gas production and net present value in a single hydraulic fracture. The gradient of the objective functional computed with the adjoint formulation is explored to update the controlled pressure drop aiming to optimize production in a given window of time. The combination of the direct approach and gradient-based optimization using the adjoint formulation leads to the construction of optimal production scenarios under controlled pressure decline in the well. Numerical simulations illustrate the potential of the methodology proposed herein in optimizing gas production.     

A numerical simulation of residual circulation in Tampa Bay. Part I: Low-frequency temporal variations

The residual (time-average) salinity and circulation in a numerical ocean model of the Tampa Bay estuary are shown to experience significant temporal variation under realistic forcing conditions. A version of the Estuarine Coastal Ocean Model developed for Tampa Bay with 70 by 100 horizontal grid points and 11 sigma levels is examined for the years 2001–2003. Model output variables are averaged over the entire time of the simulation to generate long-term residual fields. The residual axial current is found to be dominated by the buoyancy-driven baroclinic circulation with an outflow (southwestward) at the surface and to the sides of the shipping channel, and an inflow (northeastward) usually occurring subsurface within or above the shipping channel. Averages over 30 d are used to examine variations in the residual fields. During the simulation the average surface salinity near the head of Tampa Bay varies with the freshwater inflow, from 12‰ to 33%. At the bay mouth salinity varies from 30%. to 36%.. A localized measure of the baroclinic circulation in the shipping channel indicates the residual circulation can vary strongly, attaining a magnitude triple the long-term mean value. The baroclinic circulation can be disrupted, going to near zero or even reversing, when the buoyancy-driven flow is weak and the surface winds are to the northeast. Three time periods, representing different environmental conditions, are chosen to examine these results in detail. A scaling argument indicates the relative strength of buoyancy versus wind as ΔρgH²(LC _Dω²)⁻¹, where δρ is head-to-mouth density difference across the bay,g is gravitational acceleration,H is depth,L is bay length,C _D is the surface wind drag coefficient, andw is wind speed. Tampa Bay is usually in the buoyancy dominated regime. The importance of winds in the weak-buoyancy case is demonstrated in an additional simulation without wind stress.     

Small D-Spacing WC/SiC Multilayers for Future Hard X-Ray Telescope Designs

Multilayer coatings for reflecting hard X-rays up to 80 keV, like W/Si and Pt/C, have been studied for several years. To go to higher energies, in the range of 100 keV to 250 keV, one needs coatings with smaller d-spacings than can currently be made with these material combinations, and a lower interfacial roughness. With the new material combinations of WC/SiC the interface roughness can be reduced down to between 0.23 nm and 0.25 nm enabling bi-layer thicknesses down to 1.0 nm to reflect efficiently. The production of thinner period coatings thus enables the possibility for focusing optic designs with reasonable focal lengths and throughput up to 250 keV.     

Spatiotemporal evolution of the completeness magnitude of the Icelandic earthquake catalogue from 1991 to 2013

In 1991, a digital seismic monitoring network was installed in Iceland with a digital seismic system and automatic operation. After 20 years of operation, we explore for the first time its nationwide performance by analysing the spatiotemporal variations of the completeness magnitude. We use the Bayesian magnitude of completeness (BMC) method that combines local completeness magnitude observations with prior information based on the density of seismic stations. Additionally, we test the impact of earthquake location uncertainties on the BMC results, by filtering the catalogue using a multivariate analysis that identifies outliers in the hypocentre error distribution. We find that the entire North-to-South active rift zone shows a relatively low magnitude of completeness M_c in the range 0.5–1.0, highlighting the ability of the Icelandic network to detect small earthquakes. This work also demonstrates the influence of earthquake location uncertainties on the spatiotemporal magnitude of completeness analysis.