Late Quaternary submarine bedforms and ice‐sheet flow in Gerlache Strait and on the adjacent continental shelf,Antarctic Peninsula

Geophysical data from Gerlache Strait, Croker Passage, Bismarck Strait and the adjacent continental shelf reveal streamlined subglacial bedforms that were produced at the bed of the Antarctic Peninsula Ice Sheet (APIS) during the last glaciation. The spatial arrangement and orientation of these bedforms record the former drainage pattern and flow dynamics of an APIS outlet up‐flow, and feeding into, a palaeo‐ice stream in the Western Bransfield Basin. Evidence suggests that together, they represent a single ice‐flow system that drained the APIS during the last glaciation. The ice‐sheet outlet flowed north/northeastwards through Gerlache Strait and Croker Passage and converged with a second, more easterly ice‐flow tributary on the middle shelf to form the main palaeo‐ice stream. The dominance of drumlins with low elongation ratios suggests that ice‐sheet outlet draining through Gerlache Strait was comparatively slower than the main palaeo‐ice stream in the Western Bransfield Basin, although the low elongation ratios may also partly reflect the lack of sediment. Progressive elongation of drumlins further down‐flow indicates that the ice sheet accelerated through Croker Passage and the western tributary trough, and fed into the main zone of streaming flow in the Western Bransfield Basin. Topography would have exerted a strong control on the development of the palaeo‐ice stream system but subglacial geology may also have been significant given the transition from crystalline bedrock to sedimentary strata on the inner–mid‐shelf. In the broader context, the APIS was drained by a number of major fast‐flowing outlets through cross‐shelf troughs to the outer continental shelf during the last glaciation. Copyright © 2004 John Wiley & Sons, Ltd.     

Micromorphological characteristics of glacimarine sediments: implications for distinguishing genetic processes of massive diamicts

Glacimarine diamicts are produced by diverse processes, and genetic differentiation is often problematic using macro-sedimentological criteria alone. Micromorphology offers a potentially helpful tool in such investigations. Macroscopically massive diamict samples of known glacimarine origin, from the Polar North Atlantic, Antarctica and north Irish Sea, were prepared for micromorphological analysis to (1) identify microstructures unique to different modes of sedimentation and (2) interpret genetic processes from those structures. The samples comprised examples of debris-flow, iceberg-turbate and suspension settling deposits from late Quaternary glacier-influenced marine environments: tidewater glacier, sub- or pro-ice shelf and continental slopes in front of ice stream termini. Results show two significant features of debris-flow sediments: a bimodal grain fabric of near-horizontal and -vertical grains, and laminated clay and silt coatings on sand and pebble grains. Coatings are best developed in sediments with finer grain-size distributions and in debris-flow sediments which have had relatively long run-out distances on trough-mouth fans, suggesting continuous rotation of grains in a buoyant, turbulent aqueous environment. This is significant because it precludes debris-flow delivery by plug flow. The micromorphology of iceberg turbate has not been described previously. It contains structures similar to those described in tills, so that unambiguous identification of these sediments seems unlikely based on micromorphological criteria alone. Suspension sediments range from fine-grained massive diamicts containing microfossils to more heterogeneous coarser sediments characterised by abrupt textural variations, from ice-distal and ice-proximal glacimarine environments respectively. The ice-proximal sediments contain fine vertical lineations marking the trajectories of dropstones through wet matrix. These dropstone tracks have not been reported in previous studies.     

Solute provenance,transport and denudation in a high arctic glacierized catchment

Recent understanding of chemical weathering in glacierized catchments has been focused on mid-latitude, Alpine catchments; comparable studies from the high latitudes are currently lacking. This paper attempts to address this deficiency by examining solute provenance, transport and denudation in a glacierized catchment at 78°N in the Svalbard High Arctic archipelago. Representative samples of snow, glacier ice, winter proglacial icing and glacier meltwater were obtained from the catchment during spring and summer 1993 and analysed for major ion chemistry. Seasonal variations in the composition of glacier meltwater occur and are influenced by proglacial solute acquisition from the icing at the very start of the melt season, and subsequently by a period of discharge of concentrated snowmelt caused by snowpack elution; weathering within the ice-marginal channels that drain the glacier, particularly carbonation reactions, continues to furnish solute to meltwater when suspended sediment concentrations increase later in the melt season. Partitioning the solute flux into its various components (sea-salt, crustal, aerosol and atmospheric sources) shows that c. 25% of the total flux is sea salt derived, consistent with the maritime location of the glacier, and c. 71% is crustally derived. Estimated chemical denudation, 160 meq m⁻² a⁻¹ sea salt-corrected cation equivalent weathering rate, is somewhat low compared with other studied glacierized catchments (estimates in the range 450–1000 meq m⁻² a⁻¹), which is probably attributable to the relatively short melt season and low specific runoff in the High Arctic. A positive relationship was identified between discharge and CO₂ drawdown owing to carbonation reactions in turbid meltwater. © 1997 John Wiley & Sons, Ltd.     

南海南部SA09-040孔孢粉记录及古气候

依据南海低纬地区SA09-040孔高分辨率的孢粉记录,自下至上划分了4个孢粉组合带。从孢粉成分的变化,重建了22.25ka B P以来的植被与气候变化历史。结果表明:孢粉主要来源于婆罗洲和周围岛屿,孢粉1带(22.25～16.6ka B P),低山雨林植被发育,为暖热气候,从测年时间看,当时为末次冰期晚期。孢粉2带(16.6～10.82ka B P,为末次冰消期),植被以热带低山雨林和低地雨林为主,针叶的松数量较多,当时的气温比现在低。孢粉3带(全新世早期,10.82～6.43ka B P),植被以热带低山雨林和低地雨林为主,针叶松属数量减少,气温比前期升高,海平面也上升。孢粉4带(全新世中晚期,6.43ka B P至今),全新世中期为炎热、湿润的气候环境,全新世晚期可能与婆罗洲现今的植被景观相近,为热、湿的气候环境。     

An origin for laminated glacimarine sediments through sea-ice build-up and suppressed iceberg rafting

Laminated glacimarine sediments are observed in visual core logs and x-radiographs from Scoresby Sund and Nansen Fjord, east Greenland. They are mostly underlain and overlain by massive or stratified glacimarine diamicton (Dmm or Dms), which is a product of iceberg delivery of heterogeneous debris and, in Scoresby Sund, reworking by deep-drafted iceberg keels. The laminated sediments are AMS radiocarbon dated to two cold periods since the last, Late Weichselian deglaciation: the Younger Dryas stadial (Milne Land Stadial in east Greenland) and the Little Ice Age. During cold climatic events, multiyear shorefast sea ice ('sikussak') formed in these fjords and trapped the icebergs. Fine-grained, laminated muds (Fl) were deposited in Scoresby Sund when the flux of icebergs was suppressed, but turbid meltwater continued to provide some sediment flux to the fjord systems, varying through time to produce laminations. In Nansen Fjord, thinner and often massive mud layers (Fm) resulted from shorter intervals of sea-ice cover with no ice rafting. Stratified diamicton layers (Dms), which alternate with mud deposition to produce a laminated unit, probably represent intervening times of more open conditions with iceberg rafting. In Scoresby Sund, foraminifera are either absent from the laminated unit or begin to appear towards the end of its deposition. The absence of both benthic and planktonic foraminifera also suggests that multiyear sea ice was covering the core sites. There is no evidence of macrofaunal activity, and bioturbation is absent from the laminated sediments. Satellite data show that multiyear shorefast sea ice is present in several areas of the high Arctic today, and this traps icebergs calved from interior ice-cap drainage basins. Thus, the process of laminated glacimarine sediment formation is likely to be applicable to a number of areas of the modern and Quaternary Arctic.     

大兴安岭中南段中生代成矿物质的深部来源与背景

大兴安岭是我国北方一个重要的多金属成矿带。本文从成矿的物质来源和构造作用两方面讨论大兴安岭的成矿系统。Sr、Nd、O、Pb同位素的研究显示大兴安岭成矿物质的深部来源,大兴安岭晚中生代壳幔混熔花岗质岩石组成及其构造环境的研究,表明它们是在板内非造山的伸展环境下形成的A型花岗岩。与南岭花岗岩及其成矿作用的对比研究,将加深对大兴安岭中生代成矿特征的认识。深部构造特征也进一步印证了大兴安岭的成岩-成矿的背景。     

Do predatory fish of benthic crustaceans vary between kelp and barren reef habitats in northeastern New Zealand?

Fish assemblages that included known predators of benthic crustaceans were compared between kelp and barren habitats in northeastern New Zealand using baited underwater video census methods. The benthic-feeding fish were observed in winter, spring/summer and autumn, as well as during night-time in spring/summer. Overall, the fish assemblages varied between barren and kelp habitat, being most marked in winter. Individual benthic-feeding species, such as grey mao mao (Scorpis lineolatus) and leatherjacket (Meuschenia scaber) were associated with barren habitat, while the spotted wrasse (Notolabrus celidotus) was more strongly associated with kelp habitat. The results suggest that changes in habitats on coastal reefs affect populations of species that are benthic predators, which may in turn influence the distribution and abundance of their prey species, such as juvenile spiny lobsters.     

Structure and dynamics of demersal fish assemblages over three decades (1985–2012) of increasing fishing pressure in Guinea

In a context of growing fishing pressures and recommendations for an ecosystem approach to fisheries, there is a need to monitor changes in fish communities over time. In this study, we analysed data from scientific trawl surveys carried out on the continental shelf off Guinea between 1985 and 2012. We performed factorial analyses and calculated biodiversity indices to characterise the changes in the structure and composition of fish communities that occurred over the 28-year period in this area, particularly given intensive fishing activities. We show that, over the study period, fish communities on the Guinean shelf were structured primarily according to spatial factors, with temporal changes being less pronounced than expected. However, a temporal analysis of biodiversity indices and species dominance showed that the intensification of fishing had significant effects on the general ecological features of the fish assemblages under study. There was a decrease in fish density and in mean trophic level. In addition, there were changes in species dominance, whereby large, slow-growing species with high commercial value were gradually replaced by smaller, fast-growing species of lesser commercial interest. These results from field observations are in line with some conclusions from previous modelling studies in the same geographical area, and provide further support for the hypothesis of a progressive ‘ecosystem effect of fishing’ occurring in Guinean waters.     

Summer and winter differences in zooplankton biomass,distribution and size composition in the KwaZulu-Natal Bight,South Africa

Zooplankton biomass and distribution in the KwaZulu-Natal Bight were investigated in relation to environmental parameters during summer (January–February 2010) and winter (July–August 2010). Mean zooplankton biomass was significantly higher in winter (17.1 mg dry weight [DW] m^–3) than in summer (9.5 mg DW m^?3). In summer, total biomass was evenly distributed within the central bight, low off the Thukela River mouth and peaked near Durban. In winter, highest biomass was found offshore between Richards Bay and Cape St Lucia. Zooplankton biomass in each size class was significantly, negatively related to sea surface temperature and integrated nitrate, but positively related to surface chlorophyll a and dissolved oxygen. Zooplankton biomass was significantly related to bottom depth, with greatest total biomass located inshore (<50 m). Distribution across the shelf varied with zooplankton size. Seasonal differences in copepod size composition suggest that a smaller, younger community occupied the cool, chlorophyll-rich waters offshore from the St Lucia upwelling cell in winter, and a larger, older community occurred within the relatively warm and chlorophyll-poor central bight in summer. Nutrient enrichment from quasi-permanent upwelling off Durban and Richards Bay appears to have a greater influence on zooplankton biomass and distribution in the bight than the strongly seasonal nutrient input from the Thukela River.     

Calculation of the visible-UV absorption spectra of hydrogen sulfide,bisulfide, polysulfides,and As and Sb sulfides,in aqueous solution

Recently we showed that visible-UV spectra in aqueous solution can be accurately calculated for arsenic (III) bisulfides, such as As(SH)₃, As(SH)₂S^- and their oligomers. The calculated lowest energy transitions for these species were diagnostic of their protonation and oligomerization state. We here extend these studies to As and Sb oxidation state III and v sulfides and to polysulfides S _n ^2- , n = 2–6, the bisulfide anion, SH^-, hydrogen sulfide, H₂S and the sulfanes, S _n H₂, n = 2–5. Many of these calculations are more difficult than those performed for the As(iii) bisulfides, since the As and Sb(v) species are more acidic and therefore exist as highly charged anions in neutral and basic solutions. In general, small and/or highly charged anions are more difficult to describe computationally than larger, monovalent anions or neutral molecules. We have used both Hartree-Fock based (CI Singles and Time-Dependent HF) and density functional based (TD B3LYP) techniques for the calculations of absorption energy and intensity and have used both explicit water molecules and a polarizable continuum to describe the effects of hydration. We correctly reproduce the general trends observed experimentally, with absorption energies increasing from polysulfides to As, Sb sulfides to SH^- to H₂S. As and Sb(v) species, both monomers and dimers, also absorb at characteristically higher energies than do the analogous As and Sb(III)species. There is also a small reduction in absorption energy from monomeric to dimeric species, for both As and Sb III and v. The polysufides, on the other hand, show no simple systematic changes in UV spectra with chain length, n, or with protonation state. Our results indicate that for the As and Sb sulfides, the oxidation state, degree of protonation and degree of oligomerization can all be determined from the visible-UV absorption spectrum. We have also calculated the aqueous phase energetics for the reaction of S₈ with SH^- to produce the polysulfides, S _n H^-, n = 2–6. Our results are in excellent agreement with available experimental data, and support the existence of a S₆ species.