Present state and historical changes of trace metal pollution in Kaoping coastal sediments, southwestern Taiwan

Surface and gravity-cored sediments were collected from the Kaoping coastal area off southwestern Taiwan to determine particle size, organic carbon, trace metal concentration and enrichment factor (EF), 210Pb dating, and 206Pb/207Pb ratio for determining present and historical metal pollution. Surface distributions of trace metals ranged from 0.02 to 0.13 mg/kg for Cd (EF: 0.16-1.65), from 35 to 189 mg/kg for Cr (EF: 0.85-2.92), from 25 to 64 mg/kg for Ni (EF: 0.53-2.38), from 10 to 32 mg/kg for Pb (EF: 1.20-4.94), and from 29 to 129 mg/kg for Zn (EF: 1.18-3.50). Trace metal concentrations correlate closely with distributions of mud (<63 microm) and organic carbon which accumulate largely around river mouths and within the Kaoping Canyon. With the exception of Cd, Cr and Ni in certain areas with rather coarse sediments, metals were generally elevated above the baseline levels over the studied area. Metals were also relatively enriched in areas with high contents of mud and organic carbon. Sedimentation rates derived from the excess 210Pb data in core sediments sampled from the canyon illustrate metal pollution beginning around 1970 that is corresponding to the booming time of economic growth in Taiwan. Meanwhile, the status of Pb pollution in core sediments is verified by an inversed correlation between 206Pb/207Pb ratios and Pb concentrations. Anthropogenic Pb and other metals in the studied area were apparently derived primarily from the Kaoping River and accumulated around the river mouth and within the Kaoping Canyon. The Kaoping Canyon appears to act as a major sink for river borne trace metals.     

Structural Setting of the Neoarchean Terrains in the Commonwealth Bay Area (143-145°E), Terre Adélie Craton, East Antarctica

Geological maps of East Commonwealth Bay Unit (ECB), (Terre Adélie and Georges V Land, Antarctica) are presented with a summary of the main structural and metamorphic data for the region. The ECB unit was developed during Neoarchean_Paleoproterozoic event (at 2.5-2.42 Ga), with (i) granulite metamorphism at 9±1.5 kbar and 800±50°C in the lower crust section and amphibolite metamorphism (P=5 kbar, T=750°C) at the upper crustal levels; (ii) the lower crustal granulites were uplifted, and suffered local partial melting and retrogression to the amphibolite facies at 550±50°C_5 kbar. Granulites were extruded in the core of a crustal-scale anticlinal fold, but retrogressed only on the rims of the anticline. Crustal-scale folding, along with other structural features resulted from intense NE-SW shortening that prevailed during the Neoarchean orogenic cycle. Strike-slip and extensional motions were only minor components in that process; (iii) top-to-the-East thrusting and nappe piling had (at least locally) occurred under lower amphibolite to greenschist facies conditions. Finally, it seems that (iv) the Paleoproterozoic 1.7 Ga structural imprint may have only affected the rims of the Archean units. The tectonic context observed in the 1.7 Ga Cape Hunter phyllites features mainly an E-W shortening component and vertical extrusion. The eastern (Mertz) and western (Port Martin) parts of the Archean block were reactivated by localized dextral shearing.     

Ultrahigh-pressure garnet peridotites from the devolatilization of sea-floor hydrated ultramafic rocks

Garnet peridotites occur in quartzofeldspathic gneisses in the Northern Qaidam Mountains, western China. They are rich in Mg and Cr, with mineral compositions similar to those in mantle peridotites found in other orogenic belts and as xenoliths in kimberlite. Garnet‐bearing lherzolites interlayered with dunite display oriented ilmenite and chromite lamellae in olivine and pyroxene lamellae in garnet that have been interpreted to indicate pressures in excess of 6 GPa. However, some garnet porphyroblasts include hornblende, chlorite and spinel + orthopyroxene symplectite after garnet; some clinopyroxene porphyroblasts include abundant actinolite/edenite, calcite and lizardite in the lherzolite; some olivine porphyroblasts (Fo₉₂) include an earlier generation Mg‐rich olivine (Fo_95–99), F‐rich clinohumite, pyroxene, chromite, anthophyllite/cummingtonite, Cl‐rich lizardite, carbonates and a new type of brittle mica, here termed ‘Ca‐phlogopite’, in the associated dunite. The pyrope content of garnet increases from core to rim, reaching the pyrope content (72 mol.%) of garnet typically found in the xenoliths in kimberlite. The simplest interpretation of these observations is that the rock association was formerly mantle peridotite emplaced into the oceanic crust that was subjected to serpentinization by seawater‐derived fluids near the sea floor. Dehydration during subduction to 3.0–3.5 GPa and 700 °C transformed these serpentinites into garnet lherzolite and dunite, depending on their Al and Ca contents. Pseudosection modelling using thermocalc shows that dehydration of the serpentinites is progressive, and involved three stages for Al‐rich and two stages for Al‐poor serpentinites, corresponding to the breakdown of the key hydrous minerals. Static burial and exhumation make olivine a pressure vessel for the pre‐subduction mineral inclusions during ultrahigh‐pressure (UHP) metamorphism. The time span of the UHP event is constrained by the clear interface between the two generations of olivine to be very short, implying rapid subduction and exhumation.     

Palaeoproterozoic high-pressure granulite overprint of the Archean continental crust: evidence for homogeneous crustal thickening (Man Rise, Ivory Coast)

The character of mountain building processes in Palaeoproterozoic times is subject to much debate. Based on the discovery of high-pressure granulites in the Man Rise (Côte d'Ivoire), several authors have argued that Eburnean (Palaeoproterozoic) reworking of the Archean basement was achieved by modern-style thrust-dominated tectonics.
A mafic granulite of the Kouibli area (Archean part of the Man Rise, western Ivory Coast) displays a primary assemblage (M1) containing garnet, diopsidic clinopyroxene, red-brown pargasitic amphibole, plagioclase (andesine), rutile, ilmenite and quartz. This assemblage is associated with a subvertical regional foliation. Symplectites that developed at the expense of the M1 assemblage contain orthopyroxene, clinopyroxene, plagioclase (bytownite), green pargasitic amphibole, ilmenite and magnetite (M2). Multiequilibrium thermobarometric calculations and P–T pseudosections calculated with thermocalc suggest granulite facies conditions of ∼ 13 kbar, 850 °C and <7 kbar, 700–800 °C for M1 and M2, respectively. In agreement with the qualitative information obtained from reaction textures and chemical zoning of minerals, this suggests an evolution dominated by decompression accompanied by moderate cooling. A Sm–Nd garnet – whole-rock age of 2.03 Ga determined on this sample indicates that this evolution occurred during the Palaeoproterozoic. It is argued that from the geodynamic point of view the observed features are best explained by homogeneous thickening of the margin of the Archean craton, re-heated and softened due to the accretion of hot, juvenile Palaeoproterozoic crust, as well as coeval intrusion of juvenile magmas. Crustal shortening was mainly accommodated by transpressive shear zones and by lateral crustal spreading rather than large-scale thrust systems.