Geochemistry and shock petrography of the Crow Creek Member,South Dakota,USA: Ejecta from the 74‐Ma Manson impact structure

Abstract— The Crow Creek Member is one of several marl units recognized within the Upper Cretaceous Pierre Shale Formation of eastern South Dakota and northeastern Nebraska, but it is the only unit that contains shock‐metamorphosed minerals. The shocked minerals represent impact ejecta from the 74‐Ma Manson impact structure (MIS). This study was aimed at determining the bulk chemical compositions and analysis of planar deformation features (PDFs) of shocked quartz; for the basal and marly units of the Crow Creek Member. We studied samples from the Gregory 84‐21 core, Iroquois core and Wakonda lime quarry. Contents of siderophile elements are generally high, but due to uncertainties in the determination of Ir and uncertainties in compositional sources for Cr, Co, and Ni, we could not confirm an extraterrestrial component in the Crow Creek Member. We recovered several shocked quartz grains from basal‐unit samples, mainly from the Gregory 84‐21 core, and results of PDF measurements indicate shock pressures of at least 15 GPa. All the samples are composed chiefly of SiO₂ (29–58 wt%), Al₂O₃ (6–14 wt%), and CaO (7–30 wt%). When compared to the composition of North American Shale Composite, the samples are significantly enriched in CaO, P₂O₅, Mn, Sr, Y, U, Cr, and Ni. The contents of rare earth elements (REE), high field strength elements (HFSE), Cr, Co, Sc, and their ratios and chemical weathering trends, reflect both felsic and basic sources for the Crow Creek Member, an inference, which is consistent with the lithological compositions in the environs of the MIS. The high chemical indices of alteration and weathering (CIA' and CIW': 75–99), coupled with the Al₂O₃‐(CaO*+Na₂O)‐K₂O (A‐CN'‐K) ratios, indicate that the Crow Creek Member and source rocks had undergone high degrees of chemical weathering. The expected ejecta thicknesses at the sampled locations (409 to 219 km from Manson) were calculated to range from about 1.9 to 12.2 cm (for the present‐day crater radius of Manson), or 0.4 to 2.4 cm (for the estimated transient cavity radius). The trend agrees with the observed thicknesses of the basal unit of the Crow Creek Member, but the actually observed thicknesses are larger than the calculated ones, indicating that not all of the basal unit comprises impact ejecta.     

Absolute and relative amplitudes of variations in radius of classical cepheids

On the basis of observational data for the absolute R and relative R/R amplitudes of variations in radius of galactic classical cepheids (55 stars from Balona and Stobie (1979) and 30 stars from Sollazzoet al. (1981)), four kinds of empirical linear relations are obtained: log(P V)–logR, logP–logR, log(P V)–log(R/R), and logP–log(R/R);P, R, and V are the pulsation periods, the mean stellar radii, and the amplitudes of light variations, respectively. Three groups of stars are considered: short-period cepheids (SPC)-with logP1.1; long-period cepheids (LPC)-with logP>1.1; and s-cepheids (sC). Both the R values and the R/R values increase withP andP V, for a given group of variables. A comparison is performed with our results obtained from data in other sources (Kurochkin, 1966; Gieren, 1982; etc.). The investigated relations can be applied for determining R and R/R of galactic classical cepheids, by using their observedP and V. All studied galactic classical cepheids have R/R<0.35, R<10R for SPC and 10R <R60R for LPC. The sC have smaller R and R/R values than other classical cepheids, at the same periods (the difference is about 2 times for R and 1.4–2.8 times for R/R); the studied sC have R/R in the range 0.025–0.075 and R in the range 1–3R (only Y Oph has R8R ).     

Population I pulsating stars

The radiiR and surface gravitiesg of Population I pulsating stars (89 Delta Scuti-variables and 155 classical cepheids) have been investigated. Semi-empirical period-radius (P-R) and period-gravity (P-g) relations are obtained for Delta Scuti-stars (for the four lowest modes of radial pulsations) and for classical cepheids. For Delta Scuti-stars, the uncertainties of radius and gravity estimations calculated from theP-R andP-g relations for different modes, are evaluated. There is a good agreement both between theP-R relations and between theP-g relations for Delta Scuti-stars and for classical cepheids, but a gap exists between the two types of variables. From models of Delta Scuti-stars, theoreticalP-R andP-g relations for the four lowest modes of radial pulsations are obtained, in a good agreement with the corresponding semi-empirical relations. There is an excellent agreement between the theoretical and semi-empirical period ratios of radial pulsations as derived from theP-R andP-g relations for Delta Scuti-stars. It is not necessary to take into account the colours (in addition to the periods), in order to estimate the radii and gravities of the variables under study.     

The buckling of a corrugated carbon fibre cylinder under external hydrostatic pressure

A theoretical and an experimental investigation was carried out, where a carbon fibre corrugated circular cylinder was tested to destuction under external hydrostatic pressure. The theoretical investigation was via the finite element method, where the structure was modelled with several orthotropic axisymmetric thin-walled shell elements. The experimental observations were aided with strategically placed strain gauges. Comparison between theory and experiment showed that the experimentally observed buckling pressure was a little lower than the theoretical prediction. This may have been due to the fact that the model had slight initial geometrical imperfections in the circumferenential direction.     

Plastic buckling of ring-stiffened conical shells under external hydrostatic pressure

The paper describes experimental tests carried out on three ring-stiffened cones that were tested to destruction under external hydrostatic pressure. The cones were carefully machined from EN1A Steel. All three cones failed by plastic non-symmetric bifurcation buckling in a mode commonly known as general instability. In this mode the entire ring-shell combination buckles bodily.The paper also provides a design chart using the results obtained from these three vessels, together with the results of six other vessels obtained from other tests. The design chart allows the possibility of obtaining a plastic knock down factor, so that the theoretical buckling pressures, based on elastic theory, can be divided by the plastic knockdown factor, to give the predicted buckling pressure. This method can also be used for the design of full-scale vessels.     

Class distribution and locality in rural areas: an example from Gloucestershire

The analysis of rural social change has reached a point of somewhat saturated orthodoxy. Numerous studies over the last 20 years have served to reinforce a standard view that it is the ‘newcomer vs local’ conflict which lies at the heart of social and cultural changes in rural communities. Moreover, these broad categorisations have often been translated into class terms without due regard for the detailed circumstances of locality or intra-class fractions. This paper presents some evidence from an intensive study of 10 parishes in rural Gloucestershire, and seeks to provide a detailed background to the distribution of selected indicators of social change in that area. It focuses on the diversions and needs experienced by different social groups and suggests additional complexities to those recognised in traditional treatments of rural conflict.     

Microbial reduction of chromium from the hexavalent to divalent state

We demonstrate that Shewanella oneidensis, a metal-reducing bacteria species with cytoplasmic-membrane-bound reductases and remarkably diverse respiratory capabilities, reduced Cr(VI) to Cr(II) in anaerobic cultures where chromate was the sole terminal electron acceptor. Individual cell microanalysis by transmission electron microscopy (TEM) using electron energy-loss spectroscopy (EELS) and energy dispersive X-ray spectroscopy (EDXS) demonstrates Cr(II) concentrated near the cytoplasmic membrane, suggesting the terminal reduction pathway is intracellularly localized. Further, estimated cellular Cr(II) concentrations are relatively high at upwards of 0.03-0.09 g Cr/g bacterium. Accumulation of Cr(II) is observed in S. oneidensis cells prior to the formation of submicron-sized precipitates of insoluble Cr(III) on their surfaces. Furthermore, under anaerobic conditions, Cr(III) precipitates that encrust cells are shown to contain Cr(II) that is likely bound in the net negatively charged extracellular biopolymers which can permeate the surfaces of the precipitates. In otherwise nearly identical incubations, Cr(III) precipitate formation was observed in cultures maintained anaerobic with bubbled nitrogen but not in three replicate cultures in an anaerobic chamber.