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Here we report iron (Fe) isotopic data of three pure Fe solution standards (IRMM-014, GSB Fe, and NIST 3126a) and five widely used geological reference materials (RMs) from the United States Geological Survey and Geological Survey of Japan obtained on a Neptune Plus multi-collector–inductively coupled plasma–mass spectrometer (MC-ICP-MS) in our laboratory over the past 3 years. The instrumental mass bias was corrected by three independent methods: sample-standard bracketing (SSB), Ni doping?+?SSB, and 57Fe–58Fe double spike?+?SSB. Measurements reveal that both the Ni doping and double spike methods helped calibrate short-term fluctuations in mass bias. Collectively, almost all measurements of RMs yielded δ56Fe within?±?0.05 of recommended values, provided that each sample was measured four times on MC-ICP-MS. For the first time, new recommended values for NIST SRM3126a are reported (δ56Fe?=?0.363?±?0.006, 2SE, 95% CI; and δ57Fe?=?0.534?±?0.010, 2SE). 相似文献
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Steven L. Huntley Richard J. Wenning Steave H. Su Nancy L. Bonnevie Dennis J. Paustenbach 《Estuaries and Coasts》1995,18(2):351-361
In an attempt to characterize localized rates of sediment accretion, 10 sediment cores were collected from the lower reach of the Passaic River, a major tributary of Newark Bay, New Jersey. Sediments were assayed for 210Pb activity at predetermined depths and the rate of sediment accretion (cm yr?1) was estimated from the least squares regression of the log of unsupported activity versus depth. Sediment accretion rates, derived from 210Pb measurements (RPb) were used to predict the depth interval within the core containing sediments deposited around 1954; subsequent 137Cs analyses were focused on this depth interval. Sediment accretion rates derived from 137Cs measurements (RCs) were extrapolated from the depth of the 1954 horizon. Lead-210 derived sediment accretion rates in cores collected from a sediment bench extending along the inside bend on the southern shore of a meander in the river, ranged from 4.1 cm yr?1 to 10.2 cm yr?1 and averaged 6.8 cm yr?1. The RCs estimates for cores from this area ranged from 3.8 cm yr?1 to 8.9 cm yr?1 and averaged 6.6 cm yr?1. The RCs for cores collected in a more hydrologically dynamic reach of the river upstream of the sediment bench, were only 0.41 cm yr?1 and 0.66 cm yr?1. The results of this investigation indicate that this reach of the lower Passaic River is an area of high sediment accumulation, retaining much of the sediment load deposited from upstream and downstream sources. The rates of sediment accretion in the lower Passaic River are among the highest reported anywhere in the Newark Bay estuary. 相似文献
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The hepatopancreae of the ribbed mussel, Geukensia demissa, and the wedge clam, Rangia cuneata, were examined for their ability to catalyze the reduction/oxidation cycling of the bipyridyl herbicide paraquat. In vitro studies indicated a dose-dependent increase in the rate of superoxide anion (O2−) generation in microsomal fractions supplemented with NADPH; the highest concentration of paraquat employed (4 mm) elicited an 81 % increase in cytochrome c reduction in G. demissa and a 135% increase in R. cuneata. In both .species, cytochrome c reduction was inhibited by the addition of exogenous superoxide dismutase (SOD). For in vivo studies, a single application of paraquat (0·5, 1·0 or 2·0 mm) was added to aerated salt-water aquaria containing G. demissa. Biochemical analyses of antioxidant enzymes, reduced glutathione (GSH) and lipid peroxidation were performed in hepatopancreatic tissue after exposures of 6, 12, 24 and 36 h. Results support the hypotheses that these bivalves can activate redox cycling compounds and demonstrate in vivo responses typical of oxidative stress as observed in other organisms. 相似文献
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针对移动容迟网络中的数据共享服务,提出基于社团的源路由算法(Social-based Source Routing,SSR)。将移动容迟网络中的数据共享过程分为摘要消息广播、兴趣消息回传与内容数据转发。利用分布式社团检测算法区别各节点的多社团结构,通过摘要消息广播构建节点间的社团路径(Community Path),并将共享数据沿社团路径进行基于单消息副本的转发。仿真结果表明算法在一定条件下能够达到与多副本转发算法类似的消息传输成功率,同时显著降低消息传输代价。 相似文献
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Mary Wenning 《The Professional geographer》2013,65(3):426-428
Since the launch of the U.S. Department of Homeland Security in 2002, research needs have been established in the areas of disaster preparedness and critical infrastructure protection. Disaster preparedness seeks to lessen the adverse effects of catastrophes by planning in advance and instituting a proper response. Critical infrastructures are those entities deemed necessary for society to function correctly and thus require protection. Recent studies have used location models to aid in the management of many of these crucial establishments, but few efforts have modeled where to geographically site a future critical supply facility. Furthermore, no research has explored a multihazards approach for siting critical supply facilities and the explicitly spatial factors that make a potential target vulnerable to attack. In this article, we propose a strategic multiobjective modeling framework for siting critical supply facilities that incorporates explicitly spatial disaster preparedness directives and critical infrastructure protection demands. We detail the spatial data requirements and modeling assumptions and present results from an application involving the placement of critical vaccine stores in Orlando, Florida. 相似文献
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