Sulfur in peridotites and gabbros at Lost City (30°N, MAR): Implications for hydrothermal alteration and microbial activity during serpentinization

Variations in sulfur mineralogy and chemistry of serpentinized peridotites and gabbros beneath the Lost City Hydrothermal Field at the southern face of the Atlantis Massif (Mid-Atlantic Ridge, 30°N) were examined to better understand serpentinization and alteration processes and to study fluid fluxes, redox conditions, and the influence of microbial activity in this active, peridotite-hosted hydrothermal system. The serpentinized peridotites are characterized by low total sulfur contents and high bulk δ³⁴S values close to seawater composition. Low concentrations of ³⁴S-enriched sulfide phases and the predominance of sulfate with seawater-like δ³⁴S values indicate oxidation, loss of sulfide minerals and incorporation of seawater sulfate into the serpentinites. The predominance of pyrite in both serpentinites and gabbros indicates relatively high fO₂ conditions during progressive serpentinization and alteration, which likely result from high fluid fluxes during hydrothermal circulation and evolution of the Lost City system from temperatures of ∼250 to 150 °C. Sulfate and sulfide minerals in samples from near the base of hydrothermal carbonate towers at Lost City show δ³⁴S values that reflect the influence of microbial activity. Our study highlights the variations in sulfur chemistry of serpentinized peridotites in different marine environments and the influence of long-lived, moderate temperature peridotite-hosted hydrothermal system and high seawater fluxes on the global sulfur cycle.     

Sulfur mineralogy and geochemistry of serpentinites and gabbros of the Atlantis Massif (IODP Site U1309)

In-situ uplifted portions of oceanic crust at the central dome of the Atlantis Massif (Mid-Atlantic Ridge, 30°N) were drilled during Expeditions 304 and 305 of the Integrated Ocean Drilling Program (IODP) and a 1.4 km section of predominantly gabbroic rocks with minor intercalated ultramafic rocks were recovered. Here we characterize variations in sulfur mineralogy and geochemistry of selected samples of serpentinized peridotites, olivine-rich troctolites and diverse gabbroic rocks recovered from Hole 1309D. These data are used to constrain alteration processes and redox conditions and are compared with the basement rocks of the southern wall of the Atlantis Massif, which hosts the Lost City Hydrothermal Field, 5 km to the south. The oceanic crust at the central dome is characterized by Ni-rich sulfides reflecting reducing conditions and limited seawater circulation. During uplift and exhumation, seawater interaction in gabbroic-dominated domains was limited, as indicated by homogeneous mantle-like sulfur contents and isotope compositions of gabbroic rocks and olivine-rich troctolites. Local variations from mantle compositions are related to magmatic variability or to interaction with seawater-derived fluids channeled along fault zones. The concomitant occurrence of mackinawite in olivine-rich troctolites and an anhydrite vein in a gabbro provide temperature constraints of 150-200 °C for late circulating fluids along local brittle faults below 700 m depth. In contrast, the ultramafic lithologies at the central dome represent domains with higher seawater fluxes and higher degrees of alteration and show distinct changes in sulfur geochemistry. The serpentinites in the upper part of the hole are characterized by high total sulfide contents, high δ³⁴S_sulfide values and low δ³⁴S_sulfate values, which reflect a multistage history primarily controlled by seawater-gabbro interaction and subsequent serpentinization. The basement rocks at the central dome record lower oxygen fugacities and more limited fluid fluxes compared with the serpentinites and gabbros of the Lost City hydrothermal system. Our studies are consistent with previous results and indicate that sulfur speciation and sulfur isotope compositions of altered oceanic mantle sequences commonly evolve over time. Heterogeneities in sulfur geochemistry reflect the fact that serpentinites are highly sensitive to local variations in fluid fluxes, temperature, oxygen and sulfur fugacities, and microbial activity.     

红树植物白骨壤叶片衰老过程中叶肉细胞Ca2+水平的变化

用焦锑酸钙沉淀的电镜细胞化学方法，研究了白骨壤叶片衰老过程中叶肉细胞Ca^2 水平的变化．结果表明，在白骨壤幼叶和成熟叶叶肉细胞中，焦锑酸钙沉淀颗粒大量出现在液池和细胞间隙中，细胞壁中也可见少量沉淀，而细胞基质中则看不到焦锑酸钙沉淀．在衰老叶中，细胞基质和细胞膜上焦锑酸钙沉淀增加，而液泡和细胞间隙中的锑酸钙沉淀则显著减少，并且叶绿体外膜部分破损，结构破坏，核膜与液泡膜内部结构模糊，叶绿素含量、净光合速率、气扎手率和蒸腾速率显著下降．Ca^2 的区域性分布的变化与植物叶片衰老密切相关。     

Review: Theory-guided machine learning applied to hydrogeology—state of the art,opportunities and future challenges

Hydrogeology Journal - Thanks to recent technological advances, hydrogeologists now have access to large amounts of data acquired in real time. Processing these data using traditional modelling...     

Geometry and kinematics of brittle deformation in the Central Cameroon Shear Zone (Kékem area): Implication for gold exploration within the Central Africa Fold Belt in Cameroon

The Central Africa Fold Belt (CAFB) is a collision belt endowed with gold deposits in Eastern Cameroon area mined for about 50 years. However, favorable areas for gold exploration are poorly known. This paper presents (1) the kinematics of the brittle deformation in the Kékem area in the SW portion of the Central Cameroon Shear Zone and (2) constraints gold mineralization events with respect to the collisional evolution of the CAFB. The authors interpret that the conjugate ENE to E and NNW to NW trending lineament corresponds to the synthetic (R) and the antithetic (R’) shears, which accompanied the dextral slip along the NE to ENE striking shear. The latter coincides with the last 570–552 Ma D₃ dextral simple shear-dominated transpression, which is parallel to the Bétaré Oya shear zone hosting gold deposits. Gold mineralizations, which mainly occurred during the last dextral shearing, are disseminated within quartz veins associated to Riedel’s previous structures reactivated due to late collisional activities of the CAFB as brittle deformation. Gold mineralizations occurred mainly during the 570–552 Ma D₃ event. The reactivation, which might be due to dextral simple shear during mylonitzation, plausibly remobilized the early gold deposits hosted in syn-compressional rocks and/or possibly focused deep-sourced fluid mixed with those released by dehydration. Therefore, the Central Cameroon Shear Zone where Kékem is located, and which shows similar petrographical and structural features to those controling Batouri gold district, is a target area for gold exploration in Cameroon.     

Insights on the events surrounding the final drainage of Lake Ojibway based on James Bay stratigraphic sequences

Deglaciation of the James Bay region was highly dynamic, with the occurrence of ice (Cochrane) readvances into glacial Lake Ojibway around final deglaciation time, which culminated with the drainage of Ojibway waters into Hudson Bay and subsequent incursion of the Tyrrell Sea at ～8 ka. Renewed interest on these events comes from the possible link between the drainage of the ice-dammed Lake Agassiz-Ojibway and a major climate deterioration known as the 8.2-ka cooling event. Recent glaciological modeling suggests that this drainage may have occurred subglacially, a mechanism that can accommodate more than one lake discharge, as suggested by marine records. The exact number and timing of drainage events, as well as location of the lake discharge pathway(s) remain, however, largely unconstrained. Here we focus on the events that led to the drainage of Lake Ojibway by documenting late-glacial sedimentary sequences located east of James Bay. Our investigations indicate that the deglacial sequence consists of a readvance till, extensive Ojibway rhythmites, and thick marine sediments. The glaciolacustrine and marine units are separated by a 60 cm-thick horizon composed of laminated silt beds containing rounded clay balls and disseminated clasts resulting from the abrupt drainage of the lake. Radiocarbon dating of marine fossils lying above the drainage horizon indicates that the glaciolacustrine episode ended around 8128–8282 cal yr BP. Micropaleontological analyses reveal that freshwater ostracods (Candona sp.) and marine microfossils (foraminifers, dinocysts) occur together in the upper part of the Ojibway sediments. Analysis of oxygen isotopes (δ¹⁸O) of ostracods and foraminifers originating from the same stratigraphic position show highly contrasting values that suggest possible subglacial exchanges between Lake Ojibway and Tyrrell Sea waters prior to the final drainage event. The complexity of the deglacial events is further indicated by radiocarbon dating of marine shells retrieved from a Cochrane till that suggests that the last ice readvance occurred almost simultaneously with the final lake discharge. These results bring additional constraints on the drainage mechanism of the coalesced Lake Agassiz-Ojibway and indicate that the James Bay region formed an important drainage pathway for meltwaters at the end of the last deglaciation.     

Envisat and SARAL/AltiKa Observations of the Antarctic Ice Sheet: A Comparison Between the Ku-band and Ka-band

The AltiKa altimeter onboard SARAL is a joint CNES/ISRO mission launched in February 2013 that has the same 35 days repeat orbit of the previous European altimeters, Envisat, and ERS-1/2. SARAL/AltiKa is thus a unique opportunity to extend the repeat observations of this orbit that have been surveyed since 1991. However, the altimeter operates in Ka-band, which is higher than the previous frequencies, and offers new paths of investigation. The penetration depth is theoretically reduced from around 10 m in Ku-band to less than 1 m in Ka-band, such that the volume echo originates from the near subsurface. Second, the sharper antenna aperture leads to a narrower leading edge that reduces the impact of the ratio between surface and volume echoes of the height retrieval. Indeed, the spatial and temporal observations of AltiKa at cross-over points and along-track indicate that the impact of backscatter changes on the height decreasesfrom 0.3 m/dB for the Ku-band to only 0.05 m/dB for the Ka-band. Therefore, the height measurement is stable over time. Moreover, the volume echo in the Ka-band results from the near subsurface layer and is mostly controlled by ice grain size, unlike the Ku-band.     

Fracture roughness and thermal exchange: A case study at Soultz-sous-Forêts

Heat exchange during laminar flow in an open fracture is studied numerically on the basis of the Stokes equation in the limit of hydrothermal lubrication. We examine the influence of fracture roughness on hydraulic permeability and heat flux through the fracture sides when a cold fluid is injected into a homogeneous hot host rock. Spatial temperature fluctuations inside the fluid are studied assuming the temperature of the rock to be constant and the fracture aperture to be self-affine. An application to the case study at the deep geothermal reservoir of Soultz-sous-Forêts, France, is presented. Finally, a thermal model based on sparse spatial information of the geometrical aperture is successfully proposed to reproduce the response of the fracture.     

Geophysical exploration of an active pockmark field in the Bay of Concarneau,southern Brittany,and implications for resident suspension feeders

About a decade ago, a large field of pockmarks (individual features up to 30 m in diameter and <2 m deep) was discovered in water depths of 15–40 m in the Bay of Concarneau in southern Brittany along the French Atlantic coast, covering an overall area of 36 km² and characterised by unusually high pockmark densities in places reaching 2,500 per square kilometre. As revealed by geophysical swath and subbottom profile data ground-truthed by sediment cores collected during two campaigns in 2005 and 2009, the confines of the pockmark field show a spectacular spatial association with those of a vast expanse of tube mats formed by a benthic community of the suspension-feeding amphipod Haploops nirae. The present study complements those findings with subbottom chirp profiles, seabed sonar imagery and ultrasonic backscatter data from the water column acquired in April 2011. Results show that pockmark distribution is influenced by the thickness of Holocene deposits covering an Oligocene palaeo-valley system. Two groups of pockmarks were identified: (1) a group of large (>10 m diameter), more widely scattered pockmarks deeply rooted (up to 8 ms two-way travel time, TWTT) in the Holocene palaeo-valley infills, and (2) a group of smaller, more densely spaced pockmarks shallowly rooted (up to 2 ms TWTT) in interfluve deposits. Pockmark pore water analyses revealed high methane concentrations peaking at ca. 400 μl/l at 22 and 30 cm core depth in silty sediments immediately above Haploops-bearing layers. Water column data indicate acoustic plumes above pockmarks, implying ongoing pockmark activity. Pockmark gas and/or fluid expulsion resulting in increased turbidity (resuspension of, amongst others, freshly settled phytoplankton) could at least partly account for the strong spatial association with the phytoplankton-feeding H. nirae in the Bay of Concarneau, exacerbating impacts of anthropogenically induced eutrophication and growing offshore trawling activities. Tidally driven hydraulic pumping in gas-charged pockmarks represents a good candidate as large-scale short-term triggering mechanism of pockmark activation, in addition to episodic regional seismic activity.