Triassic Nb-enriched basalts, magnesian andesites, and adakites of the Qiangtang terrane (Central Tibet): evidence for metasomatism by slab-derived melts in the mantle wedge

New chronological, geochemical, and isotopic data are reported for Triassic (219–236 Ma) adakite-magnesian andesite-Nb-enriched basaltic rock associations from the Tuotuohe area, central Qiangtang terrane. The adakites and magnesian andesites are characterized by high Sr/Y (25–45), La/Yb (14–42) and Na₂O/K₂O (12–49) ratios, high Al₂O₃ (15.34–18.28 wt%) and moderate to high Sr concentrations (220–498 ppm) and ε_ND (t) (+0.86 to +1.21) values. Low enrichments of Th, Rb relative to Nb, and subequal normalized Nb and La contents, and enrichments of light rare earth elements combine to distinguish a group of Nb-enriched basaltic rocks (NEBs). They have positive ε_ND (t) (+2.57 to +5.16) values. Positive correlations between Th, La and Nb and an absence of negative Nb anomalies on mantle normalized plots indicate the NEBs are products of a mantle source metasomatized by a slab melt rather than by hydrous fluids. A continuous compositional variation between adakites and magnesian andesites confirms slab melt interaction with mantle peridotite. The spatial association of the NEBs with adakites and magnesian andesites define an “adakitic metasomatic volcanic series” recognized in many demonstrably subduction-related environments (e.g., Mindanao arc, Philippines; Kamchatka arc, Russia; and southern Baja California arc, Mexico). The age of the Touhuohe suite, and its correlation with Triassic NEB to the north indicates that volcanism derived from subduction-modified mantle was abundant prior to 220 Ma in the central Qiangtang terrane.     

舟山国家石油储备基地堆载预压加固效果分析

介绍了舟山国家石油储备基地试验区软基堆载预压大型现场试验结果,根据现场试验测得的数据,分析了软土地基堆载预压下沉降变化规律、分层沉降变化规律、深层土体位移变化规律、超静孔隙水压力变化规律,进一步探讨了根据应力和应变分析得到的地基固结性状,其中通过应变分析得到适用于储备基地的沉降经验系数m。结果表明,打设塑料排水板结合堆载预压处理软弱地基具有良好的效果。     

翅碱蓬(Suaeda heteroptera)根际与非根际沉积物常见重金属总量及化学形态变化

原子吸收光谱法和等离子光谱法分别研究了潮滩盐沼植物翅碱蓬(Suaedaheterop-tera)根际与非根际(根上部和根下部)沉积物中Cu、Zn、Pb和Cd的总量和化学形态。结果表明,从总量来看,不同潮滩沉积物中4种重金属次序均为Zn>Pb>Cu>Cd,但同一元素随潮滩位置变化明显,尤以中潮滩差异最显著,重金属总量明显大于其他两个潮滩(低潮滩和高潮滩),特别是根际沉积物中的重金属总量远高于非根际沉积物总量,其比值分别为Cu3·4—4·2倍,Zn2·2—2·7倍,Pb3·2—3·3倍。同一潮滩均表现为根际沉积物>根上部>根下部。Cd含量相对较低,其变化不明显。从化学形态看,沉积物重金属表现为环境直接影响态(交换态和有机结合态)、环境间接影响态(碳酸盐态和铁锰氧化物态)和稳定态(残渣态)。与非根际沉积物相比,根际沉积物中重金属的化学形态发生了显著的变化,Cu和Pb以稳定态为主,其次为环境间接影响态,环境直接影响态最低;Zn与上述2种金属不同,以环境直接影响态含量最高(可交换态是有机结合态的7倍),其次分别为环境间接影响态(主要是碳酸盐结合态)和稳定态。实验结果表明,由于特异根圈效应,一方面该植物使可迁移形态的Cu和Pb在根际逐步得到矿化,使其生物可利用性降低;另一方面使Zn的生物可利用性提高,促进了植物对Zn的吸收利用。     

冲绳海槽西北侧表层沉积物中微型腹足类的分布及其研究意义

冲绳海槽西北侧大陆架向大陆坡转折处表层沉积物中微型腹足类动物群具有混合的生态特征,这与现代海洋沉积环境并不一致。腹足类动物群中除少数种类为陆坡深海分子,多数种类属内陆架区或近岸浅水分子。因此,动物群主要反映了晚更新世末次冰期低海平面的海洋环境,而少数深海种类的混入应与黑潮暖流在冲绳北端所形成的上升流有关。根据本区腹足类在其他海区的时空分布规律,本文认为在更新世末次冰期,黑潮暖流仍对本区有重要影响，并控制着腹足类的分布。本区腹足类这种混合的生态特征是晚更新世末次冰期以来各种海洋动力环境叠加影响的结果。     

草酰胺合铜(Ⅱ)单核配合物的热分解动力学研究

应用TG-DTG-DTA热分析技术研究了N，N’-双(2-氨丙基)草酰胺合铜(Ⅱ)单核配合物在空气气氛中的热行为；分别用微分法(Achar法)和积分法(Coats-Redfen法)对其非等温TG数据进行了解析。通过对热分解动力学参数的对比分析，提出了该配合物热分解反应机理；根据TG曲线计算出了E，lnA和S^*，并由动力学补偿效应获得了E与lnA的数学表达式。     

频率域电磁法中视电阻率全区定义

视电阻率定义在电法勘探中得到广泛的应用。目前在频率域电磁法中常常采用远区视电阻率定义。由于在频率域中收发距并非足够大,以致在低频段远区定义视电阻率往往不能反映地下电阻率值。我们定义全区电阻率及引入校正系数K,经二层三层模型及野外实测资料的计算,证明了方法的有效性。     

水平井含水率上升影响因素

利用塔里木油田塔中4油田(TZ4)底水油藏相关的地质、流体数据建立数值模型。在所建模型的基础上,应用数值模拟计算的累积产油、产水和产液量回归俞启泰水驱特征曲线,以反映水平井见水特征的参数b。以参数b为研究对象,采用正交试验的方法研究不同因素对b值的影响,筛选影响水平井见水特征的主要因素,认为原油粘度、油层厚度、非均质性及水平井水平段在油藏中的位置是影响水平井含水上升趋势的主要指标。最后建立主要因素与b值的关系式,结合俞启泰曲线b值图版,提出预测水平井见水规律的公式——图版法(F-b法)。应用F-b法对塔里木水平井含水率进行预测,并与其他相关方法及实际生产数据对比,认为F-b法可作为预测塔里木油田水平井含水率、估算可采储量的一种有效方法。     

井中激电地-井方式井旁球体正反演

以激发极化法中的地-井方式中的体极化球形体作为研究对象,采用解析法对地下半空间的电位场进行求解,利用提取出的井中二次场异常电位差进行反演,得出极化球体的球心离井的距离和球心的埋深。通过计算机进行正反演模拟,验证了进行正反演计算的解析式的正确性,并从物理意义上对正反演过程中出现的现象进行分析。最后给出该方法的适用条件以及注意事项。研究对激发极化法地下勘探目标的定量分析具有明确意义。     

基于ArcGIS的1:5万DLG数据库生成地形图的设计与实现

探讨在ArcGIS环境下利用1:5万DLG数据库直接生成地形图的若干关键技术,如定制1:5万DLG符号库、符号配置,并给出地形图生产的完整的工艺流程,这样能够缩短1:5万地形图的成图周期,提高工作效率。     

GNSS three carrier ambiguity resolution using ionosphere-reduced virtual signals

This paper presents a general modeling strategy for ambiguity resolution (AR) and position estimation (PE) using three or more phase-based ranging signals from a global navigation satellite system (GNSS). The proposed strategy will identify three best “virtual” signals to allow for more reliable AR under certain observational conditions characterized by ionospheric and tropospheric delay variability, level of phase noise and orbit accuracy. The selected virtual signals suffer from minimal or relatively low ionospheric effects, and thus are known as ionosphere-reduced virtual signals. As a result, the ionospheric parameters in the geometry-based observational models can be eliminated for long baselines, typically those of length tens to hundreds of kilometres. The proposed modeling comprises three major steps. Step 1 is the geometry-free determination of the extra-widelane (EWL) formed between the two closest L-band carrier measurements, directly from the two corresponding code measurements. Step 2 forms the second EWL signal and resolves the integer ambiguity with a geometry-based estimator alone or together with the first EWL. This is followed by a procedure to correct for the first-order ionospheric delay using the two ambiguity-fixed widelane (WL) signals derived from the integer-fixed EWL signals. Step 3 finds an independent narrow-lane (NL) signal, which is used together with a refined WL to resolve NL ambiguity with geometry-based integer estimation and search algorithms. As a result, the above two AR processes performed with WL/NL and EWL/WL signals respectively, either in sequence or in parallel, can support real time kinematic (RTK) positioning over baselines of tens to hundreds of kilometres, thus enabling centimetre-to-decimentre positioning at the local, regional and even global scales in the future.