Fog and rain water chemistry at Mt. Fuji: A case study during the September 2002 campaign

Measurements of fog and rain water chemistry at the summit of Mt. Fuji, the highest peak in Japan, as well as at Tarobo, the ESE slope of Mt. Fuji in September 2002. The pH of fog and rain water sampled at Mt. Fuji varied over a range of 4.0–6.8. Acidic fogs (pH < 5.0) were observed at the summit when the air mass came from the industrial regions on the Asian continent. The ratio of [SO₄²⁻]/[NO₃⁻] in the fog water was lower at Tarobo than at the summit. High concentrations of Na⁺ and Cl⁻ were determined in the rain water sampled at the summit, possibly because of the long-range transport of sea-salt particles raised by a typhoon through the middle troposphere. The vertical transport of sea-salt particles would influence the cloud microphysical properties in the middle troposphere. Significant loss of Mg²⁺ was seen in the rain water at the summit. The concentrations of peroxides in the fog and rain water were relatively large (10–105 μM). The potential capacity for SO₂ oxidation seems to be strong from summer to early autumn at Mt. Fuji. The fog water peroxide concentrations displayed diurnal variability. The peroxide concentrations in the nighttime were significantly higher than those in the daytime.     

Sound velocity and density of liquid Ni68S32 under pressure using ultrasonic and X-ray absorption with tomography methods

A new experimental setup for simultaneous P-wave velocity (V_P) and density (ρ) measurements for liquid alloys is developed using ultrasonic and X-ray absorption methods combined with X-ray tomography at high pressures and high temperatures. The new setup allows us to directly determine adiabatic bulk moduli (K_S) and to discuss the correlation between the V_P and ρ of the liquid sample. We measured V_P and ρ of liquid Ni₆₈S₃₂ up to 5.6 GPa and 1045 K using this technique. The effect of pressure on the V_P and ρ values of liquid Ni₆₈S₃₂ is similar to that of liquid Fe₅₇S₄₃. (Both compositions correspond to near-eutectic ones.) The obtained K_S values are well fitted to the finite strain equation with a $K_{{\text{S}}_0}$ value (K_S at ambient pressure) of 31.1 GPa and a dK_S/dP value of 8.44. The measured V_P was found to increase linearly with increasing ρ, as approximated by the relationship: V_P [m/s] = 1.29 ρ [kg/m³] – 5726, suggesting that liquid Ni–S follows an empirical linear relationship, Birch's law. The dV_P/dρ slope is similar between Ni₆₈S₃₂ and Fe₅₇S₄₃ liquids, while the V_P–ρ plot of liquid Ni–S is markedly different from that of liquid Fe–S, which indicates that the effect of Ni on Birch's law is important for understanding the V_P–ρ relation of planetary and Moon's molten cores.     

Seasonal variation of volatile organic iodine compounds in the water column of Funka Bay,Hokkaido, Japan

Volatile organic iodine compounds (VOIs) emitted from the ocean surface to the air play an important role in atmospheric chemistry. Shipboard observations were conducted in Funka Bay, Hokkaido, Japan, bimonthly or monthly from March 2012 to December 2014, to elucidate the seasonal variations of VOI concentrations in seawater and their sea-to-air iodine fluxes. The bay water exchanges with the open ocean water of the North Pacific twice a year (early spring and autumn). Vertical profiles of CH₂I₂, CH₂ClI, CH₃I, and C₂H₅I concentrations in the bay water were measured bimonthly or monthly within an identified water mass. The VOI concentrations began to increase after early April at the end of the diatom spring bloom, and represented substantial peaks in June or July. The temporal variation of the C₂H₅I profile, which showed a distinct peak in the bottom layer from April to July, was similar to the PO₄ ^3? variation profile. Correlation between C₂H₅I and PO₄ ^3? concentrations (r = 0.93) suggests that C₂H₅I production was associated with degradation of organic matter deposited on the bottom after the spring bloom. CH₂I₂ and CH₂ClI concentrations increased substantially in the surface and subsurface layers (0–60 m) in June or July resulted in a clear seasonal variation of the sea-to-air iodine flux of the VOIs (high in summer or autumn and low in spring).     

Sound velocity and elastic properties of Fe–Ni and Fe–Ni–C liquids at high pressure

The sound velocity (V _P) of liquid Fe–10 wt% Ni and Fe–10 wt% Ni–4 wt% C up to 6.6 GPa was studied using the ultrasonic pulse-echo method combined with synchrotron X-ray techniques. The obtained V _P of liquid Fe–Ni is insensitive to temperature, whereas that of liquid Fe–Ni–C tends to decrease with increasing temperature. The V _P values of both liquid Fe–Ni and Fe–Ni–C increase with pressure. Alloying with 10 wt% of Ni slightly reduces the V _P of liquid Fe, whereas alloying with C is likely to increase the V _P. However, a difference in V _P between liquid Fe–Ni and Fe–Ni–C becomes to be smaller at higher temperature. By fitting the measured V _P data with the Murnaghan equation of state, the adiabatic bulk modulus (K _S0) and its pressure derivative (K _S ^′ ) were obtained to be K _S0 = 103 GPa and K _S ^′  = 5.7 for liquid Fe–Ni and K _S0 = 110 GPa and K _S ^′  = 7.6 for liquid Fe–Ni–C. The calculated density of liquid Fe–Ni–C using the obtained elastic parameters was consistent with the density values measured directly using the X-ray computed tomography technique. In the relation between the density (ρ) and sound velocity (V _P) at 5 GPa (the lunar core condition), it was found that the effect of alloying Fe with Ni was that ρ increased mildly and V _P decreased, whereas the effect of C dissolution was to decrease ρ but increase V _P. In contrast, alloying with S significantly reduces both ρ and V _P. Therefore, the effects of light elements (C and S) and Ni on the ρ and V _P of liquid Fe are quite different under the lunar core conditions, providing a clue to constrain the light element in the lunar core by comparing with lunar seismic data.     

On wave-free floating-body forms in heaving oscillation

Some wave-free heaving forms are obtained in a manner similar to Bessho's earlier work by using a source and vertical dipole combination to generate bulbous-shaped two and three-dimensional bodies which have zero radiation damping. Then the combinations of higher singularities, such as triple-pole and quadra-pole, are considered. Using the thin-ship approximation, where the boundary condition is satisfied on the centreline, a simple procedure for generating any arbitrary shape that has the same property is established. The existence of wave-free frequencies of such bodies are verified numerically, in two dimensions by a standard singularity-distribution method based on the actual body-contour and in three-dimensions by using vortex-ring distribution for an axisymmetric body. Experiments are carried out for the models obtained theoretically and the results support the theoretical predictions fairly well. Finally, some suggestions are made to apply such a wave-free body to a moored buoy to suppress its heaving oscillation.     

日本Kojima湖的富营养化

日本Kojima湖现在每年的COD平均浓度大约是10mg/L，这是日本环境标准的两倍。COD颗粒的浓度被确定是与叶绿素a的浓度成比例的。另一方面，溶解COD的浓度与叶绿素a的浓度无关。因此，COD颗粒显然是被水藻增长引起的。此外，估计与Kojima湖富营养化相关的内部产物导致的COD的百分比是总COD的20％－30％。     

Low-Frequency Temperature Variability at Fukue Island Located Southwest of the Tsushima Straits

Sea surface temperature (SST) and sea surface salinity variations at Fukue Island (located southwest of the Tsushima Straits) were investigated. In spring, low-frequency SST fluctuations with periods of 10–20 days predominate. Synthetic analysis of in situ observation and satellite infrared image reveals that these SST fluctuations are caused by movement of mixed warm water masses which have a temperature intermediate between those of the Kuroshio and the East China Sea (ECS) shelf waters. Since these fluctuations do not correspond with those in the Tsushima Straits, it is indicated that these water masses can hardly pass the Tsushima Straits while retaining their original water properties. In July, SST fluctuations with a period of several days are also found at Fukue Island. Since these SST fluctuations show an opposite correspondence with its salinity fluctuations and a good correspondence with the SST fluctuations at Okinoshima in the Tsushima Straits, it is inferred that warm and low-salinity water originated from the ECS shelf water causes these fluctuations and intrudes into the Tsushima Straits.     

New buoy observation system for tsunami and crustal deformation

We have developed a new system for real-time observation of tsunamis and crustal deformation using a seafloor pressure sensor, an array of seafloor transponders and a Precise Point Positioning (PPP ) system on a buoy. The seafloor pressure sensor and the PPP system detect tsunamis, and the pressure sensor and the transponder array measure crustal deformation. The system is designed to be capable of detecting tsunami and vertical crustal deformation of ±8 m with a resolution of less than 5 mm. A noteworthy innovation in our system is its resistance to disturbance by strong ocean currents. Seismogenic zones near Japan lie in areas of strong currents like the Kuroshio, which reaches speeds of approximately 5.5 kt (2.8 m/s) around the Nankai Trough. Our techniques include slack mooring and new acoustic transmission methods using double pulses for sending tsunami data. The slack ratio can be specified for the environment of the deployment location. We can adjust slack ratios, rope lengths, anchor weights and buoy sizes to control the ability of the buoy system to maintain freeboard. The measured pressure data is converted to time difference of a double pulse and this simple method is effective to save battery to transmit data. The time difference of the double pulse has error due to move of the buoy and fluctuation of the seawater environment. We set a wire-end station 1,000 m beneath the buoy to minimize the error. The crustal deformation data is measured by acoustic ranging between the buoy and six transponders on the seafloor. All pressure and crustal deformation data are sent to land station in real-time using iridium communication.     

The nationwide investigation of endocrine disruptors in sediment of harbours

Various types of endocrine disruptors or environmental hormones flow from their sources down into harbours through rivers and other watercourses, and are accumulated in sediment on the sea bottom. Tributyltin, which has been used as paint for ship bottoms, is considered one of the endocrine disruptors.In close cooperation with the other ministries and agencies, the Ports and Harbours Bureau of the Ministry of Land, Infrastructure and Transport carried out an investigation in 1999 to determine the actual condition of 12 endocrine disruptors in the sediment of 39 harbours, in order to gather fundamental data to be used in future examinations of policy. Furthermore, in 2000 the bureau chose seven harbours out of the above 39 harbours as subjects of an additional investigation regarding the surface distribution of endocrine disruptors in the harbour areas and the synchronistic change of accumulation of dioxin and other substances. As the result of the investigation regarding the surface distribution of endocrine disruptors accumulated in seven harbours, relatively high concentrations were measured in the innermost parts of harbours and the mouths of rivers. Synchronistic changes in the amount of dioxin and other substances accumulated in sediments of five harbours were determined. Small amounts of dioxin and other substances, including an especially small amount of coplanar-PCBs, were found in the layers formed before or around 1950. Relatively large amounts of these substances were measured in the upper layers formed during roughly 1960-1990, though no significant yearly differences in concentration could be identified. This result coincides with the facts that, during roughly 1960-1980, PCP and CNP were used as agricultural chemicals and full-scale production of PCBs started in 1960.     

Estimation of methane emission from whole waste landfill site using correlation between flux and ground temperature

A methodology to estimate a methane emission in a waste landfill site was developed. The methane flux at a waste landfill site in summer, autumn, and winter was within the following ranges: from −1.3×10⁻² to 16, from −6.4×10⁻² to 7.5, and from −1.6×10⁻³ to 1.5×10⁻² g-CH₄ m⁻² h⁻¹, respectively. In those seasons, the mean methane emission rate and coefficient of variation were 1.1 g-CH₄ m⁻² h⁻¹ ±290%, 0.57 g-CH₄ m⁻² h⁻¹ ±347%, and 5.4×10⁻² g-CH₄ m⁻² h⁻¹ ±370%, respectively. These results simultaneously showed that fluctuations of methane emission from the landfill surface were both of spatial and temporal variability. In each season, an exponential relationship was observed between the methane flux density and the ground temperature. Total methane emissions were estimated to be 5.7×10⁻², 7.1×10⁻³, and 1.7×10⁻³ g-CH₄ m⁻² h⁻¹ in the summer, autumn, and winter surveys, respectively, using a temperature surrogated-kriging method. The results of this study would improve upon the labor-intensive closed-chamber method, and could be a more practical way to estimate methane emissions from waste landfills.