影像与激光雷达数据的城市地物信息提取

针对城市地物信息提取中地物边界难以确定、分类精度不高的问题,该文提出一套综合利用影像及激光雷达点云高程信息的面向对象分类方法。在分割中,各类地物的最佳分割尺度由监督法分割精度评价确定,最终分割结果利用粒度理论下的分割尺度综合方法进行合成,能兼顾不同地物最优分割尺度,获得准确地物边界;在分类中,采用ReliefF特征选择算法度量从影像及点云数据提取的对象特征重要度,选择最佳特征组合,并采用多分类器组合方法进行分类,以消除Hughes现象,提高分类精度。选择德国斯图加特市两块实验区进行分类实验,结果表明:该方法有利于提高大范围城市地物精细信息提取的精度和效率,具有较高的应用价值。     

Characterization,dissolution and solubility of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb<Subscript>x</Subscript>Ca<Subscript>1−x</Subscript>)<Subscript>5</Subscript>(PO<Subscript>4</Subscript>)<Subscript>3</Subscript>OH] at 25 °C and pH 2–9

Background

The interaction between Ca-HAP and Pb²⁺ solution can result in the formation of a hydroxyapatite–hydroxypyromorphite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)], which can greatly affect the transport and distribution of toxic Pb in water, rock and soil. Therefore, it’s necessary to know the physicochemical properties of (Pb_xCa_1?x)₅(PO₄)₃(OH), predominantly its thermodynamic solubility and stability in aqueous solution. Nevertheless, no experiment on the dissolution and related thermodynamic data has been reported.

Results

Dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)] in aqueous solution at 25 °C was experimentally studied. The aqueous concentrations were greatly affected by the Pb/(Pb + Ca) molar ratios (X_Pb) of the solids. For the solids with high X_Pb [(Pb_0.89Ca_0.11)₅(PO₄)₃OH], the aqueous Pb²⁺ concentrations increased rapidly with time and reached a peak value after 240–720 h dissolution, and then decreased gradually and reached a stable state after 5040 h dissolution. For the solids with low X_Pb (0.00–0.80), the aqueous Pb²⁺ concentrations increased quickly with time and reached a peak value after 1–12 h dissolution, and then decreased gradually and attained a stable state after 720–2160 h dissolution.

Conclusions

The dissolution process of the solids with high X_Pb (0.89–1.00) was different from that of the solids with low X_Pb (0.00–0.80). The average K _sp values were estimated to be 10^?80.77±0.20 (10^?80.57–10^?80.96) for hydroxypyromorphite [Pb₅(PO₄)₃OH] and 10^?58.38±0.07 (10^?58.31–10^?58.46) for calcium hydroxyapatite [Ca₅(PO₄)₃OH]. The Gibbs free energies of formation (ΔG _f ^o ) were determined to be ?3796.71 and ?6314.63 kJ/mol, respectively. The solubility decreased with the increasing Pb/(Pb + Ca) molar ratios (X_Pb) of (Pb_xCa_1?x)₅(PO₄)₃(OH). For the dissolution at 25 °C with an initial pH of 2.00, the experimental data plotted on the Lippmann diagram showed that the solid solution (Pb_xCa_1?x)₅(PO₄)₃(OH) dissolved stoichiometrically at the early stage of dissolution and moved gradually up to the Lippmann solutus curve and the saturation curve for Pb₅(PO₄)₃OH, and then the data points moved along the Lippmann solutus curve from right to left. The Pb-rich (Pb_xCa_1?x)₅(PO₄)₃(OH) was in equilibrium with the Ca-rich aqueous solution.

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Graphical abstractLippmann diagrams for dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃OH] at 25??C and an initial pH of 2.00.

     

TLS技术在环境地质灾害监测中的应用进展

针对地面三维激光扫描技术在环境地质灾害监测中的应用问题,该文在系统介绍此技术关键指标和数据处理的基础上,从滑坡监测、土壤侵蚀监测、敏感地貌微变形监测和水灾害边界追踪4个方面,详细介绍了该技术在环境地质灾害监测领域的应用历史和现状,其研究热点包括该技术在应用中的适宜性评价、监测精度评价、滤波算法的开发及灾害发生趋势预判等方面。另外,应用中高植被覆盖度和降雨天气的干扰问题可通过继续优化软硬件并加强与其他技术联合应用予以弥补。     

论乡村聚落优化与乡村相对贫困治理

2020年后,中国反贫困将转入相对贫困治理的新阶段。乡村聚落居住、就业、教育、医疗、环卫、文化、防灾减灾等功能的发展不充分和多维剥夺,是乡村相对贫困的重要表现和重要原因,乡村相对贫困治理必须从乡村聚落的整体优化出发。论文在梳理相对贫困概念内涵的基础上,着眼于乡村聚落与相对贫困治理的内在关联,分析乡村聚落与乡村相对贫困发生、乡村聚落优化与相对贫困治理长效机制建立之间的关系,提出基于相对贫困治理的乡村聚落优化策略,以期为2020年后的乡村相对贫困治理和乡村振兴提供理论依据。研究认为：① 乡村相对贫困的形成与聚落要素、功能密切相关,并因区位、布局、规模、形态的差异而有所不同;② 乡村聚落是缓解乡村相对贫困长效机制建立的空间基础,乡村相对贫困治理长效机制的建立要充分发挥乡村聚落的要素支撑与空间载体功能;③ 基于相对贫困治理的乡村聚落优化策略包括振兴村落产业、优化村落空间组织、强化村落文化认同、建立绿色生态村落、促进村落多功能协同转型、坚持分类施策等6个方面。     

大气污染物排放量与颗粒物环境空气质量的空间非协同耦合研究——以武汉市为例

针对区域大气污染物排放量与空气质量在时空分布上存在不完全协同、匹配的现象,论文选择SO₂、NO_X、PM_2.5、CO和VOCs作为大气污染物指标,选择气溶胶光学厚度(Aerosol Optical Depth, AOD)表征颗粒物环境空气质量,以武汉市为例,综合应用耦合模型和空间错位指数模型研究2类指标之间的空间非协同耦合规律。主要结论如下：① 武汉市大气污染物排放量与颗粒物空气质量具有不同空间分布特征,大气污染物排放量呈现由城市中心城区向远城区递减的趋势,其中SO₂、PM_2.5和VOCs的排放具有明显的中心聚集现象,而NO_X和CO聚集现象不显著,且与道路分布明显相关;AOD分布具有明显的空间差异性,总体上呈由西北向东南依次递减的趋势。② 武汉市大气污染物排放与颗粒物空气质量的空间非协同耦合规律：越靠近城市中心城区,空间协同耦合现象越显著,空间错位现象越弱;越远离主城区,空间非协同耦合现象越显著,空间错位现象越显著;SO₂排放量与AOD在武汉市远城区的空间错位指数均大于0.7,且耦合度指数小于0.3,呈现较强的非协同耦合特征,NO_X、VOCs、PM_2.5的排放量与AOD在武汉中心城区的空间错位指数均小于0.5,且耦合度指数大于0.5,协同耦合现象较为显著。③ 基于时空非协同耦合分析城市大气环境污染治理建议：针对污染物与AOD空间错位不显著的城市中心城区,以本地减排治理为主;针对污染物与AOD空间错位显著的远城区,应在污染溯源分析的基础上进行区域协调综合治理。     

The Belt and Road: Geographical pattern and regional risks

Journal of Geographical Sciences - Building the Belt and Road is initiatives of China to promote win-win international cooperation in the new era, aiming at green, health, intellect and peace and...     

基于DEM地形因子的水土流失分析

研究地形因子对水土流失造成的影响,可为区域水土保持工作提供参考.本文以广西百色市、河池市、贺州市、防城港市为研究区域,以ArcGIS平台为技术支持,基于数字高程模型数据,选取坡度、剖面曲率、地表粗糙度、沟壑密度4个指标,进行空间叠加分析,得到研究区基于所选地形因子的水土流失强度分级图及水土流失面积,得出如下结论:1)基...     

汇聚板块边缘岩浆中金属和氯的地球化学性质研究

总结了铜(Cu)、金(Au)、铼(Re)和氯(Cl)在汇聚板块边缘岩浆中的性质。在岛弧型的火山岩岩浆演化的早期,Cu、Au和Re均表现为中度不相容元素,含量随SiO2含量的增加而增加。在SiO2质量分数为58%时,多数岛弧型火山岩中Au、Cu的含量会突然大幅度下降。这一变化与铁和钛的变化是耦合的,铁和钛均由不相容元素变为相容元素,显示钛磁铁矿开始结晶了。进一步的研究表明,钛磁铁矿的结晶使硫酸根被还原为氢硫酸根,后者与Au、Cu形成氢硫酸根络合物,被萃取到流体相中,从而形成成矿流体。这一过程可以很好地解释Au、Cu矿床广泛分布于汇聚板块边缘的现象。与Au、Cu相反,Re的含量在SiO2质量分数为60%时才开始下降,而且是缓慢下降。这是因为Re通常比Au、Cu更亲石。此外,Re还具有强烈的挥发性。氯在东Manus岩浆中表现为高度不相容的特点。氯的性质主要受压力、初始水含量和岩浆演化分异程度的控制。计算结果显示,由于MORB和OIB含水量低,分异演化程度低,氯在上述岩浆中表现为高度不相容的特点。相比之下,氯在岛弧岩浆中的性质就复杂得多。随着水含量和岩浆房深度的不同,氯的性质可以从相容变到高度不相容。     

A New Gigantic Sauropod Dinosaur with the Deepest Known Body Cavity from the Cretaceous of Asia

A new species of sauropod dinosaur Huanghetitan ruyangensis is erected based on the following characters： deepest body cavity with a dorsal rib reaching at least 2.93 m long, anterior caudal vertebrae with mushroom-shaped neural spines. Based on this new specimen of Huanghetitan found in the early Late Cretaceous Mangchuan Formation of Ruyang, Henan Province, the family Huanghetitanidae faro. nov. is proposed as a new rank to include only the genus Huanghetitan You et al. 2006. At present, Huanghetitan includes two species： H. liujiaxiaensis You et al., 2006 and H. ruyangensis sp. nov. The systematic relationships of Huanghetitan among sauropod dinosaurs are briefly discussed.     

吉林延边地区屯田营组时代商榷

本文主要论述吉林省延边地区屯田营组时代。通过对屯田营组研究历史的回顾,从火山岩喷发—沉积序列和生物地层资料指出屯田营组时代为晚侏罗世,屯田营组与金沟岭组同是晚侏罗世两个火山旋回。