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1.
Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff
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We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AICC] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component. 相似文献
2.
叶澜涛 《广东海洋大学学报》2006,26(2):92-96
池莉小说作为当代新写实小说的重要代表性文本引起了许多研究和评论。这些评论试图从以下四个方面来阐释池莉小说的各种意义:1、女性意识的觉醒;2、凡俗与无奈的生活图景;3、主题与结构的内外比较,4、综述及反思。通过对池莉小说近十年研究状况的梳理来加深对池莉小说的了解。 相似文献
3.
采用PCR技术对2种亚洲龙鱼的mtDNAD_Loop全序列进行扩增和测序,序列结构分析和序列同源性比对结果表明,2种亚洲龙鱼的mtDNAD_Loop在靠近5’端有3个终止相关序列TAS(Ⅰ、Ⅱ、Ⅲ),靠近D_Loop的3’端有4个保守区域CSB1、CSB2、CSB3、CSB-D。在终止相关序列和保守区域之间是连续重复区域。经DNASP4.0软件分析,全序列中检测出多态位点数(S)为26,其中有17个转换,核苷酸多样性(Pi)为0.013,平均核苷酸差异数(K)为17.333。 相似文献
4.
基于可靠度理论的黄土高边坡优化设计 总被引:11,自引:2,他引:9
对黄土高边坡进行可靠性分析,应用数学原理和优化原理,建立了黄土高边坡的优化模型,对铜黄一级公路黄土高边坡进行分析验证。结果表明,该方法计算的结果与实际较接近.应用中易操作。 相似文献
5.
Three continuous marine fish cell lines of FG (i. e., Hounder Gill) from flounder (Paralichthys olivaceus) gill, SPH (i. e. , Sea Perch Heart) from sea perch (Lateolabrax japonicus) heart and RSBF (i.e., Red Sea Bream Fin) from red sea bream (Pagrosomus major) fin, were characterized by lactate dehydrogenase (LDH) isozyme and morphological analysis. The LDH isozyme patterns of these three cell lines and their corresponding tissues of origin were investigated and compared. The results showed: (1) No difference was found in the LDH isozyme patterns of FG and flounder gill tissue. However, the LDH isozyme patterns of SPH and RSBF were significantly different from their corresponding tissues of origin; (2) LDH isozyme patterns of FG, SPH and RSBF were markedly different from each other and could serve as genetic markers for species identification and detection of cross contamination. Morphological change analysis of these three cell lines in comparison to their original tissues indicated that FG cells still appeared epithelioid without morphological transformation. However, morphological changes were found in SPH and RSBF compared to their original tissues. Therefore, the cellular morphology was still plastic in the relatively stable culture conditions, and it was possible that change of LDH patterns wasrelated to morphological changes of fish cells in vitro. 相似文献
6.
本文叙述南天区 5GHzVLBI普查中新发现的视超光速射电源 ,0 4 2 0— 0 1 4,1 334—1 2 7和 2 345— 1 67,这些结果尚待进一步的观测加以证实 相似文献
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8.
EM技术在我国水环境保护中的应用研究进展 总被引:4,自引:0,他引:4
对EM技术在我国水环境保护中的应用情况进行了综述,重点介绍了EM技术应用于废水处理领域的研究进展,同时还展望了将来的应用及研究前景. 相似文献
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10.
提出了Winkler地基参数的Kalman滤波识别方法。引入Mindlin理论后,推导了Winkler地基上板的控制微分方程。利用Fourier变换,推求了Winkler地基上简支板的Fourier闭式解。推导了Winkler地基参数的Kalman滤波方程,研究了Winkler地基参数的Kalman滤波识别的具体计算步骤。研究表明,运用Kalman滤波理论进行Winkler地基参数的识别,能有效地估计Winkler地基参数;Winkler地基参数的滤波收敛速度和精度受地基参数初始值选取和位移实测资料的影响,且Kalman滤波理论也可用于其他地基模型地基参数的识别。 相似文献