北京密云放马峪基性岩墙群LA-MC-ICP-MS锆石U-Pb年龄及其意义

太古宙基性岩墙群在北京密云地区广泛分布,其年代学研究一直备受关注,多年来取得了一些数据,但对太古宙变质片麻岩控制作用未做论述。利用LA-MC-ICP-MS U-Pb同位素测定技术,测得放马峪石榴辉石岩中锆石的年龄为2497±15Ma,此年龄被解释为区内变质片麻岩成岩年龄应早于基性岩墙群成岩年龄,其为研究区内太古宙片麻岩成岩年龄提供了重要的参考数据。     

超临界态甲烷密度研究

超临界甲烷密度不仅是非常规天然气资源量计算与吸附能力测定的重要参数,同时也是衡量超临界甲烷扩散效率与溶解有机物能力的主要指标。通过对比分析各种气体状态方程的适用性,认为基于亥姆霍兹能量基本状态方程可以准确计算0~30 MPa、270~360 K条件下甲烷的密度。利用Microsoft Office Excel编写了甲烷密度的计算程序,与NIST （美国国家标准与技术研究院）商业软件计算结果相比,误差小于0.05%。分析了0~100 MPa、270~360 K范围内甲烷密度的变化规律。结果表明,甲烷密度随压力增大而增大,在低于30 MPa时增速较大且对温度的敏感性较强,高于30 MPa时增速逐渐变缓,且敏感性减弱。在煤层原位条件下随着埋深的增大,甲烷密度随温度升高而减小,随压力增大而增大;在温度与压力共同作用下,甲烷密度呈先增速不变、近似线性增加,后增速逐渐减小、凸曲线形增加的变化规律。游离态甲烷密度受温度的影响比吸附态甲烷小,是深部煤层气资源增量的主要贡献者。研究结果为深部煤层气赋存及其潜力预测提供了基础参数。      

Application of the stable-isotope system to the study of sources and fate of Hg in the environment: A review

With the improvement of analytical methods and the development of multiple-collector inductively coupled plasma-mass spectrometry (MC-ICP/MS), research on non-traditional stable isotope (Cu, Zn, Fe, Se, Mo, Cr, Hg) in geochemistry has made tremendous progress in the past decade. Recent studies have demonstrated that both organic and inorganic reactions may cause Hg isotope fractionation, and variations of Hg isotopic composition in the environment have been successfully employed to explain Hg pollution history, Hg sources and tracking Hg pathways in nature. Furthermore, Hg isotopic fractionation studies can be a powerful tool in the calibration of global Hg cycling models. Stable isotope geochemistry of Hg is therefore becoming a new frontier subject in earth sciences. Based on summarizing previous research, this paper outlines the main advances in the study of Hg stable isotopes with particular emphasis placed on a brief explanation of Hg isotope analytical techniques, possible Hg isotope fractionation mechanisms observed in both natural and experimental processes, Hg isotope composition variations in different environmental matrices, and the application prospects of the Hg stable isotopes in environmental geosciences.     

The impact of over 100 years of wildfires on mercury levels and accumulation rates in two lakes in southern California,USA

In southern California, USA, wildfires may be an important source of mercury (Hg) to local watersheds. Hg levels and Hg accumulation rates were investigated in dated sediment cores from two southern California lakes, Big Bear Lake and Crystal Lake, located approximately 40-km apart. Between 1895 and 2006, fires were routinely minimized or suppressed around Big Bear Lake, while fires regularly subsumed the forest surrounding Crystal Lake. Mean Hg concentrations and mean Hg accumulation rates were significantly higher in Crystal Lake sediments compared to Big Bear Lake sediments (Hg levels: Crystal Lake 220 ± 93 ng g⁻¹, Big Bear Lake 92 ± 26 ng g⁻¹; Hg accumulation: Crystal Lake 790 ± 1,200 μg m⁻² year⁻¹, Big Bear 240 ± 54 μg m⁻² year⁻¹). In Crystal Lake, the ratio between post-1965 and pre-1865 Hg concentrations was 1.1, and several spikes in Hg levels occurred between 1910 and 1985. Given the remote location of the lake, the proximity of fires, and the lack of point sources within the region, these results suggested wildfires (rather than industrial sources) were a continuous source of Hg to Crystal Lake over the last 150 years.     

贵州百花湖表层水中不同形态汞的分布规律

均匀布点采集百花湖表层水样44个,对水样不同形态汞含量进行了分析,并现场测定水质参数。采用经典统计学与半变异函数拟合相结合的方法,研究了百花湖表层水中不同形态汞含量的空间变异性。根据半变异函数拟合的结果,在ArcGIS软件的支持下进行克立格插值,以此来揭示百花湖表层水中不同形态汞含量的空间分布规律。研究表明:百花湖表层水中的汞污染主要来自上游,随水体流动汞污染减少;但也有一些区域可能因富营养化而使颗粒态汞和总汞含量增加。     

北京区域成矿规律综述

2013～2019年开展的"中国矿产地质志·北京卷"项目是全面总结北京地区现代地质矿产工作,特别是新中国成立以来北京地区矿产勘查与研究成果,旨在全面反映北京市矿产全貌及重要成矿规律。本文是对该项工作部分成果的概括总结。系统收集了北京市铁、金、煤、石灰岩等各类矿产资料,划分了矿种矿床类型,重点对铁、金、煤、石灰岩等矿种成矿地质特征进行了阐述。在全国Ⅰ-Ⅲ级成矿区带划分基础上,结合北京市地质构造演化和成矿特点,提出北京市区域成矿区带划分方案,划分了怀柔北金萤石成矿区、八达岭金铜钼铅锌成矿区、京西煤石灰岩成矿区、密云-怀柔铁金成矿区、密云-平谷金石灰岩成矿区5个Ⅴ级成矿区,总结了不同区带各矿种规律特征。从矿产时空演化、岩浆岩控矿、构造控矿角度进行了区域成矿规律总结,提升了北京地区矿产地质研究水平,填补了北京区域成矿规律多矿种综合性研究的空白。     

三峡库区汉丰湖鱼类群落结构的季节变化

为了解汉丰湖鱼类群落结构的季节变化特征,以便为汉丰湖鱼类资源的合理利用及保护提供理论依据,于2014年12月、2015年4、7和10月按季度共4次对汉丰湖鱼类群落结构进行调查与分析.结果表明:共采集到鱼类8538尾,38种,隶属于5目9科32属;其中,鲤形目鱼类有28种,占总物种数的73.68%.鱼类组成以湖泊定居性种类为主,瓦氏黄颡鱼(Pelteobagrus vachelli)、蛇鮈(Saurogobio dabryi)、银鮈(Squalidus argentatus)、鲫(Carassius auratus)、光泽黄颡鱼(Pelteobagrus nitidus)、鲤(Cyprinus carpio)和贝氏(Hemiculter bleekeri)为汉丰湖的重要优势种,占总尾数的67.45%.汉丰湖鱼类群落Shannon-Wiener多样性指数、Pielous均匀度指数和Margalef丰富度指数在冬季最高,而Pielous均匀度指数在不同季节相对稳定.Jaccard群落相似性指数较高,季节间种类相似度较高.鱼类群落稳定性分析表明,冬季稳定性最高,其次为春季,夏季稳定性最低.湖泊生境尤其是水位的变化对汉丰湖鱼类群落结构影响明显.     

全风化花岗岩化学及矿物成份在全土和粘粒中的不同表征

对全风化花岗岩化学和矿物成份的测试常用全土和粘粒部分(粒径<2μm)分别进行。业已发现两者由于物质组成和结构特征的差异,对土工程地质性质所起作用不同。本文给出了6个全风化花岗岩样品的全土和粘粒部分筛分法和移液管法测定粒度成份,用X荧光光谱仪做全量化学分析,及XRD矿物学分析的结果。对比这两部分数据发现,属于含砾土的这些样品化学成份的变化同矿物一致,尤其是同粘土矿物成份含量变化很一致。同全岩相比,粘粒化学成份中的SiO₂减少了近50%,K₂O含量也降低,而Al₂O₃、Fe₂O₃和H₂O⁺都明显升高。粘粒中氧化物相对含量升高者居多;全岩矿物成份以石英、粘土矿物和长石为主,粘粒中埃洛石和高岭石占大多数,其次为伊利石;粒度成份、化学成份和矿物含量相关性比较明显的是:石英和角砾正相关,和砂粒负相关,长石和砂粒正相关,粘土矿物含量和Al₂O₃、烧失量(LOI)和埃洛石含量正相关。     

青藏高原发现大型冻胀丘群

在青藏高原黄河源地区多格茸盆地内发现大型冻胀丘群,这些冻胀丘外观多呈穹窿状,有些呈脊状、新月状.盆地内的冻胀丘隆起高度多在3~6 m,最高不超过10 m,水平扩展范围数十米到上百米,最大超过300 m.冻胀丘在盆地内密集分布,众多小型湖塘嵌于其中,分布密度估计5~8个·km^-2,局部区域内可达10个·km^-2以上.从外观看,多数冻胀丘形态较完整,但有的已经部分塌陷,有的几乎完全塌陷,不同塌陷阶段的冻胀丘在盆地内均有发现.冻胀丘顶部钻孔岩芯揭示高含冰地层从丘顶以下5 m左右一直延续到20多米,局部发育厚层地下纯冰层,厚度可达2 m以上.根据外观形态、地下冰类型判断,这些多年生的冻胀丘属冰土丘(lithalsa),和常见的冰核丘(pingo)有所区别.初步判断,这些冻胀丘形成于全新世大暖期以后的新冰期时期.多格茸盆地冻胀丘群的发现对现行的工程建设及工程建筑物的运营安全、区域古环境、流域水文等方面的研究都具有重要意义.     

Mercury pollution from artisanal mercury mining in Tongren, Guizhou, China

Concentrations of total Hg (T-Hg) were measured in mine waste, stream water, soil and moss samples collected from the Tongren area, Guizhou, China to identify potential Hg contamination to local environments, which has resulted from artisanal Hg mining. Mine waste contained high T-Hg concentrations, ranging from 1.8 to 900 mg/kg. High concentrations of Hg were also found in the leachates of mine waste, confirming that mine waste contains significant water-soluble Hg compounds. Total Hg distribution patterns in soil profiles showed that top soil is contaminated with Hg, which has been derived from atmospheric deposition. Data suggest that organic matter plays an important role in the binding and transport of Hg in soil. Elevated T-Hg concentrations (5.9–44 mg/kg) in moss samples suggest that atmospheric deposition is the dominant source of Hg to local terrestrial ecosystems. Concentrations of T-Hg were highly elevated in stream water samples, varying from 92 to 2300 ng/L. Particulate Hg in water constituted a large proportion of the T-Hg and played a major role in Hg transport. Methyl–Hg (Me–Hg) concentrations in the water samples was as high as 7.9 ng/L. Data indicate that Hg contamination is dominantly from artisanal Hg mining in the study area, but the extent of Hg contamination is dependent on the mining history and the scale of artisanal Hg mining.