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1.
Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff
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We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AICC] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component. 相似文献
2.
青藏高原隆升的非线性动态有限元仿真研究 总被引:7,自引:4,他引:3
根据青藏高原的地质特征建立分析模型,采用3维动态有限元方法,在计算仿真板块速度场的基础上,计算在青藏高原的隆升过程中该地区地壳岩石的等效应力和位移随时间的变化,计算仿真得到的速度场与1998年GPS观测的速度场吻合良好;与过去一贯的假设相反,计算结果反映出地壳应力场不是静态的,而是此起彼伏,不断变化的,应力值最大且变化最剧烈的地区在克什米尔地区、鄂尔多斯地区和鲜水河-小江断裂带,与地震多发区域吻合。 相似文献
3.
利用“地震预报计算机专家系统”的思想对大同 -阳高 Ms6 .1地震前每一前兆异常事件进行综合评估 ,以每一异常的最可能发震时间来计算发震概率 ,利用地震前兆综合加权信息熵研究了系统熵值与地震的关系。对华北地区的地震前兆综合加权信息熵研究表明 ,在大同 -阳高 Ms6 .1地震前 ,信息熵出现了明显的减熵有序变化 相似文献
4.
Xue-Fei Chen Zhan-Wen HanNational Astronomical Observatories Yunnan Observatory Chinese Academy of Sciences. Kunming Graduate School of the Chinese Academy of Sciences Beijing 《中国天文和天体物理学报》2005,5(1):65-76
We have studied the influence of different choices of core-envelope transition point on the final merger of contact binaries with two main-sequence components. A binary of 1.00 + 0.90M⊙ with an initial orbital period of 0.35d is examined. The mass fraction of the primary mixed with the matter of the secondary, qmix, determined by the chosen core-envelope transition point, ranges from 0.04 to 1.00 in our analysis. If as qmix< 0.8, none of the 相似文献
5.
Vertical drains are usually installed in subsoil consisting of several layers. Due to the complex nature of the problem, over the past decades, the consolidation properties of multi‐layered ground with vertical drains have been analysed mainly by numerical methods. An analytical solution for consolidation of double‐layered ground with vertical drains under quasi‐equal strain condition is presented in this paper. The main steps for the computation procedure are listed. The convergence of the series solution is discussed. The comparisons between the results obtained by the present analytical method and the existing numerical solutions are described by figures. The orthogonal relation for the system of double‐layered ground with vertical drains is proven. Finally, some consolidation properties of double‐layered ground with vertical drains are analysed. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献
6.
Zhan-Le Du Hua-Ning Wang Xiang-Tao He National Astronomical Observatories Chinese Academy of Sciences Beijing Department of Astronomy Beijing Normal University Beijing 《中国天文和天体物理学报》2006,6(4):489-494
The maximum amplitudes of solar activity cycles are found to be well anti-correlated (r = -0.72) with the newly defined solar cycle lengths three cycles before (at lag -3) in 13-month running mean sunspot numbers during the past 190 years. This result could be used for predicting the maximum sunspot numbers. The amplitudes of Cycles 24 and 25 are estimated to be 149.5±27.6 and 144.3±27.6, respectively. 相似文献
7.
芮国强 《广东海洋大学学报》2003,23(2):72-78
可持续发展作为现代化建设的两大战略之一 ,对我国政府的能力提出了挑战。可持续发展战略的实施 ,要求加强政府的作用 ,将政府建设成为强有力而又廉价的政府。为此 ,我国政府应从加强政府的财政汲取能力建设、强化中央政府协调地区发展的能力 ,加强政府调控能力建设、强化中央政府协调当前利益和长远利益、经济利益与生态效益的能力 ,并从根本上转变政府职能、精兵简政、建设廉价高效的政府等方面着手来提高我国政府推进和实施可持续发展战略的能力 相似文献
8.
海岩的长篇小说《河流如血》再创出版高记录,但作家仍局限于特有的小说叙述模式,这部作品设能做到相应的创新。概言之,模式第一面是“刑侦+恋爱”;模式第二面是“财子+佳人”;模式第三面是“道德+法制”。文学创作需要不断创新,创新的过程也是对创作模式的不断突破过程。作家应该警惕的是,不要让模式成为创作的桎梏。 相似文献
9.
DEVELOPMENTSTRATEGIESOFWATERANDLANDRESOURCESINTHEHEXIREGION,CHINA肖洪浪,高前兆,李福兴DEVELOPMENTSTRATEGIESOFWATERANDLANDRESOURCESINTHE... 相似文献
10.
Tidal effects on temperature front in the Yellow Sea 总被引:5,自引:0,他引:5
Temperature front (TF) is one of the important features in the Yellow Sea, which forms in spring, thrives in summer, and fades
in autumn as thermocline declines. TF intensity ⋎S
T
⋎ is defined to describe the distribution of TF. Based on the MASNUM wave-tide-circulation coupled model, temperature distribution
in the Yellow Sea was simulated with and without tidal effects. Along 36°N, distribution of TF from the simulated results
are compared with the observations, and a quantitative analysis is introduced to evaluate the tidal effects on the forming
and maintaining processes of the TF. Tidal mixing and the circulation structure adapting to it are the main causes of the
TF.
Supported by the National Basic Research Program of China (No. G1999043809) and the National Science Foundation of China (No.
49736190). 相似文献