Dissolution of Corundum and Andalusite in H2O-Saturated Haplogranitic Melts at 800{degrees}C and 200 MPa: Constraints on Diffusivities and the Generation of Peraluminous Melts

The mechanisms and kinetics of equilibration between peraluminousminerals and granitic melt were investigated experimentallyby the dissolution of corundum and andalusite into H₂O-saturatedmetaluminous haplogranitic melt at 800°C and 200 MPa. Mineraland haplogranitic glass rods were juxtaposed inside platinumcapsules, and then subjected to experimental conditions fortimes ranging from 12 to 2900 h. Upon melting, the mineral –meltinterface retreats with the square root of time. The compositionof the melt at the interface changes with time, but its ASI[aluminum saturation index = molar Al₂O₃/(CaO + Na₂O + K₂O)]remains constant at     

Application of pattern recognition algorithm in the seismic belts of Indian convergent plate margin — CN algorithm

The earthquake catalogue from 1964 to August 1991 is used to identify the times of increased probabilities (TIPs) of the earthquake mainshocks of magnitudes greater than or equal to 6·4 and are associated with the Indian convergent plate margins, in retrospect. In Pakistan and Indo-Burma regions, the analysis was repeated for magnitude threshold 6·2 and 7·0 respectively. All the earthquakes (except one in the Hindukush region and one in Indo-Burmese region) in Pakistan, Hindukush-Pamir, Himalaya and Indo-Burmese regions were preceded by the special activation and hence were predicted. Approximately 23 ± 10% of the total time (1970 to August 1991) is occupied by the TIPs in all the regions. The reasons for failure to predict the two earthquakes in these regions are discussed. Our analysis gives a better picture of the regionalization and the size of the space-time volume for the preparation of an earthquake. The high success ratio of the algorithm proves that it can be applied in this territory for further prediction in the real time, without any significant changes in its parameters.     

Contrasting interactions of sodium and potassium with H<Subscript>2</Subscript>O in haplogranitic liquids and glasses at 200 MPa from hydration–diffusion experiments

This study examines hydration–diffusion in the metaluminous haplogranite system at 200 MPa H₂O and 800–300°C. At 800°C hydration is accompanied by melting and uphill diffusion of sodium from anhydrous glass toward the region of hydration and melting, whereas potassium diffuses away from the hydration front and into anhydrous glass. Silicon and aluminum are simply diluted upon hydration. There is no change in molecular Al/(Na + K) throughout the entire hydration-diffusion aureole and, therefore, (1) there is no loss of alkalis to the vapor, and (2) K migrates to replace Na in order to maintain local charge balance required by ^IVAl. Alkali diffusion occurs over a viscosity contrast from 10^4.1 Pa s in hydrous liquid to 10^11.8–10^13.5 Pa s in anhydrous glass. From these results, we interpret that: (1) Na is structurally or energetically favored over K as a charge-balancing cation for ^IVAl in hydrous granitic liquids, whereas the opposite behavior has been observed for anhydrous melts, and (2) the diffusion of alkalis through silicate melts is largely independent of viscosity. Results from 600°C are similar to those at 800°C, but hydration at 300°C involves a loss of Na and concomitant increase in molar Al/(Na + K) in the hydration zone due to hydrogen-alkali exchange between fluid and glass. Hydration behavior at 400°C is transitional between those at 300°C and 600°C, suggesting that the change in hydration mechanism occurs near the glass transition.     

Behavior and effects of phosphorus in the system Na2O−K2O−Al2O3−SiO2−P2O5−H2O at 200 MPa(H2O)

The addition of phosphorus to H₂O-saturated and initially subaluminous haplogranitic (Qz–Ab–Or) compositions at 200 MPa(H₂O) promotes expansion of the liquidus field of quartz, a marked decrease of the solidus temperature, increased solubility limits of H₂O in melt at low phosphorus concentrations, and fractionation of melt out of the haplogranite plane (projected along an Or₂₈ isopleth) toward a peralkaline, silica-poor but quartz-saturated minimum composition. The partition coefficient for P₂O₅ between aqueous vapor and melt with an ASI (aluminum saturation index, mol Al/[mol Na+K])=1 is negligible (0.06), and consequently so are the effects of phosphorus on other melt-vapor relations involving major components. Phosphorus becomes more soluble in vapor, however, as the concentration of a NaPO₃ component increases via the fractionation of melt by crystallization of quartz and feldspar. The experimental results here corroborate existing concepts regarding the interaction of phosphorus with alkali aluminosilicate melt: phosphorus has an affinity for alkalis and Al, but not Si. Phosphorus is incorporated into alkali feldspars by the exchange component AlPSi_-2. For subaluminous compositions (ASI=1), the distribution coefficient of phosphorus between alkali feldspar and melt, D[P]Af/m, is 0.3. This value increases to D[P]Af/m=1.0 at a melt ASI value of 1.3. The increase in D[P]Af/m with ASI is expected from the fact that excess Al promotes the AlPSi_-2 exchange. With this experimental data, the P₂O₅ content of feldspars and whole rocks can reveal important facets of crystallization and phosphorus geochemistry in subaluminous to peraluminous granitic systems.     

Pattern recognition applied to earthquake epicenters in California

A pattern recognition procedure is explained which uses geological data and the earthquake history of a region, in this case California, and learns how to separate earthquake epicenters from other places. Sites of future earthquake epicenters are predicted as well as places where epicenters will not occur. The problem is formulated in several ways and control experiments are devised and applied in order to test the stability of the procedures and engender confidence in the results. Some of the combinations of geological features which the computer recognized as significant discriminants are discussed.     

A scaling law for the occurrence of aftershocks in southern California

A scaling law for the occurrence of aftershocks in southern California is proposed which suggests that the number of aftershocks is independent of the magnitude of the mainshock if aftershocks are counted in the magnitude interval from (Mm ? Δ) to Mm.     

A worldwide test of three long-term premonitory seismicity patterns—a review

Worldwide analysis of the clustering of earthquakes has lead to the hypothesis that the occurrence of abnormally large clusters indicates an increase in probability of a strong earthquake in the next 3–4 years within the same region. Three long-term premonitory seismicity patterns, which correspond to different non-contradictory definitions of abnormally large clusters, were tested retrospectively in 15 regions. The results of the tests suggest that about 80% of the strongest earthquakes can be predicted by monitoring these patterns.Most of results concern pattern B (“burst of aftershocks”) i.e. an earthquake of medium magnitude with an abnormally large number of aftershocks during the first few days. Two other patterns, S and Σ often complement pattern B and can replace it in some regions where the catalogs show very few aftershocks.The practical application of these patterns is strongly limited by the fact that neither the location of the coming earthquake within the region nor its time of occurrence within 3–4 years is indicated. However, these patterns present the possibility of increasing the reliability of medium and short-term precursors; also, they allow activation of some important early preparatory measures.The results impose the following empirical constraint on the theory of the generation of a strong earthquake: it is preceded by abnormal clustering of weaker earthquakes in the space-time-energy domain; corresponding clusters are few but may occur in a wide region around the location of the coming strong earthquake; the distances are of the same order as for the other reported precursors.     

Fluids migration and dynamics of a blocks-and-faults system

We explore the impact of fluids migrating through a fault network on the dynamics of lithosphere, both on slow movements and seismicity. For that purpose fluids in the fault zones are incorporated into modelling of blocks-and-faults systems, which takes into account driving forces and the system's geometry. Simulations have been performed for two-dimensional models: an idealised “brick wall” structure, and a coarse image of Sinai Subplate. Migrating fluids originating in different locations are considered, as well as fluids trapped in closed pockets. Basic features of the modelled and observed seismicity are in good accord, as shown by comparison with the earthquake catalog compiled by Geophysical Institute of Israel.