The beachwatch pollution monitoring programme: Changing priorities to recognize changed circumstances

Since the commissioning of the three major deepwater outfalls in Sydney, there has been a dramatic improvement in general beach water quality at Sydney's ocean beaches. This has required the NSW Environment Protection Authority's Beachwatch Programme to shift from assessing the impacts of gross sewage pollution due to nearshore outfalls to more diffuse pollution from stormwater and sewer overflows.

The visual indicators of gross sewage pollution originally used by Beachwatch for the daily assessment of bacterial water quality are now of limited value. General linear models (with multiple effects) were constructed to identify the secondary indicators which best describe the levels of bacterial contamination due to stormwater pollution. Data from four representative Sydney beaches were modelled separately due to the site-specific effects of pollution sources and hydrodynamics. Factors which were built into the models and were known on the day of prediction were rain amount, presence of stormwater material, the maximum daily stormwater rating, drain or lagoon flows at the time of sampling, and the drain/lagoon bacterial concentration two days before sampling.

Results indicate that there is a general linear relationship between visual indicators and bacterial density; however, the reliability of the prediction on a daily basis is poor and rainfall alone as a predictor is equivalent to or better than visual assessment alone. The primary source of information for the preparation of Beachwatch daily pollution bulletins now is rainfall reports from a telemetered network of rain gauges along the coast. This is a more cost-effective approach and has allowed the reallocation of resources to address more directly the problem of stormwater pollution at higher risk beaches.     

The geoarchaeology of Iron Age “moated” sites of the Upper Mae Nam Mun Valley,N.E. Thailand. I: Palaeodrainage,site–landscape relationships and the origins of the “moats”

The study focuses on the “moated” Iron Age sites of N.E. Thailand, first identified as significant prehistoric settlement sites in the 1940s from aerial photography. Two more recent photograph sets are used to map the surficial geology and prehistoric site distribution for a study area west of Phimai, N.E. Thailand, with a focus on site–landscape relationships and, in particular, relationships between site location and form and patterns of palaeodrainage. The derived record of the surficial geology reflects several phases of palaeodrainage, characterized by differing locations and types of former river channels. Of note is the differentiation between a recent period in which river channels, including those presently active, are single-string meandering channels, and an older period of broad belts of meandering multistring channels. The prehistoric site distribution correlates closely with the older drainage, and for many, the encircling channels (the “moats”) are closely associated with former river channels. These relationships provide a critical and novel model for site distribution; several implications arise, supported by emerging field evidence, and introducing issues for archaeological debate: (i) there is no need, as has been done in the past, to invoke prehistoric artificial forms of drainage associated with the sites; (ii) the definition of the encircling channels as “moats” is seriously called into question; and (iii) the inferred geomorphological evolution of the floodplain implies past changes in environmental parameters such as run-off, climate or biophysical environments. Since the sites are all located in or beside ancient meander belts, these parameters should now be introduced into archaeological discussions regarding the establishment, history, evolution, and abandonment of the Iron Age sites. Methodologically, this article illustrates the need to be aware of the complexity of aerial photograph interpretation in archaeological survey, showing that careful analysis of aerial photograph information may have a significant impact upon the modeling of prehistoric interpretations. Further stratigraphical studies will be reported subsequently, and will refine the models presented here. © 1999 John Wiley & Sons, Inc.     

Revised radiocarbon ages on woolly rhinoceros (Coelodonta antiquitatis) from western central Scotland: significance for timing the extinction of woolly rhinoceros in Britain and the onset of the LGM in central Scotland

Woolly rhinoceros bones, from a number of sites in Britain, have been AMS radiocarbon dated following ultrafiltration pre-treatment. These determinations give a coherent set of ages between >50 and c. 35 cal ka BP. The youngest (35,864–34,765 cal BP) come from the area around Bishopbriggs in western central Scotland and are derived from glaciofluvial sand and gravel overlain by till, both deposited during the Last Glacial Maximum (LGM) glaciation. A previous radiocarbon date from the site suggested that woolly rhinoceros lived c. 27 ¹⁴C ka BP and the region was ice-free at the time. This date has had significant influence on the timing of extinction of woolly rhinoceros and the onset of glaciation over Britain during the LGM. The new dates revise this earlier determination and confirm that woolly rhinoceros became extinct in Britain after c. 35 cal ka BP, that central Scotland was ice-free at this time, and glaciation extended across this region sometime after 35 cal ka BP.     

Problems with radiocarbon dating the Middle to Upper Palaeolithic transition in Italy

Radiocarbon dating of material from Late Pleistocene archaeological sites is challenging. Small amounts of modern ¹⁴C-labelled contamination will significantly affect the reliability of dates from the period, producing erroneous results. Recent developments in sample pre-treatment chemistry have shown that problems in reliable age determination during this period are surmountable. In this paper we provide an example of one such case, from the Middle to Upper Palaeolithic transitional site of the Grotta di Fumane, in northern Italy. We AMS dated two fractions of the same charcoal samples derived from a series of superimposed Mousterian, Aurignacian and Gravettian levels excavated at the site. One fraction was treated using the routine acid–base–acid (ABA) method, the other with the more rigorous acid–base-oxidation/stepped combustion (ABOx–SC) method. The latter method produced consistently older, and almost certainly more reliable, results. The eruption of the known-age Campanian Ignimbrite from the Phlegrean Fields near present-day Naples at 39.3 ka yr BP seals Ulluzzian and Proto Aurignacian levels in the south of Italy. Equivalent cultural levels are present at Fumane and the results obtained with the ABOx–SC methods are consistent with the ages inferred for sites in the south of Italy based on the presence of the Campanian Ignimbrite. New results from a sample found beneath the Campanian Ignimbrite at the Russian site of Kostenki, obtained using both the ABA and ABOx–SC, methods are also presented. They support the conclusion reached at Fumane by demonstrating that, in many cases, the ABOX–SC treatment effectively removes contamination where the ABA treatment does not. The results of the work offer a sobering examination of the problems inherent in the current radiocarbon database relating to the period, and highlight the dangers of an uncritical use of the corpus of ¹⁴C results obtained over the last few decades. Based on our results, we predict that more than 70% of the 53 previously available determinations from Fumane are erroneously young. A way forward is suggested, using these improved chemical preparation methods, applying analytical methods to characterise the material dated, and testing existing site chronologies to establish which previous determinations are liable to be inaccurate.     

New dates and palaeoenvironmental evidence for the Middle to Upper Palaeolithic occupation of Higueral de Valleja Cave,southern Spain

A research programme has been set up at Higueral de Valleja Cave in southern Spain to investigate the late survival and eventual extinction of the southern Iberian Neanderthals and the arrival of modern humans. Of key interest in the first phase of research was to understand the depositional environment in the entrance chamber of the cave and to establish whether palaeoenvironmental and dating samples could be retrieved from the Middle and Upper Palaeolithic sequences. The outcome is a series of OSL, TL and radiocarbon dates showing that the cave was occupied by Neanderthal populations in Marine Isotope Stage (MIS) 3, if not earlier, and by modern human Solutrean populations during the last glacial maximum. Cave sediments provisionally indicate that the lower Middle Palaeolithic sequence (X–VIII) formed in warm and humid environments and the upper sequence (VIII–V) formed when the climate was cooler and drier. The presence of long grass phytoliths and of the small mammals Microtus duodecimcostatus, Microtus brecciensis and Apodemus sylvaticus in the upper sequence indicates that a range of habitat types persisted near the cave including grassland, scrubby vegetation, patchy tree cover and ponds. This raises the possibility that environmental factors were key factors in the late survival of Neanderthal populations at the cave.     

Hydropyrolysis as a new tool for radiocarbon pre-treatment and the quantification of black carbon

The first results concerning the potential of hydrogen pyrolysis (hypy) as a new tool for the quantification and isolation of Black Carbon (BC) for radiocarbon analysis are reported. BC is a highly stable form of carbon, produced during pyrolysis of biomass to materials such as charcoal. Isolation and quantification of this component is therefore of great interest in radiocarbon measurement, particularly for more ancient samples, where contamination issues become more critical. Hypy has been demonstrated to reliably separate labile and refractory carbonaceous sample components for engineering and geological applications, but its potential in ¹⁴C geochronological investigation has previously been unexplored. Here, we test the hypy technique using a selection of soil standard samples and ancient charcoals from deposits of geological and archaeological significance. The results show that hypy can effectively and reproducibly isolate different carbon fractions within a variety of sample types and thus has the potential to provide a rapid and robust pre-treatment technique for radiocarbon analysis. Hypy has the additional advantage that the non-BC fraction removed from a sample can be quantitatively collected for subsequent further analysis. The technique represents a promising new approach not only for ensuring reliable decontamination of pyrogenic carbon samples prior to radiocarbon dating, but also for BC quantification in a variety of environmental matrices.     

The early Lateglacial re-colonization of Britain: new radiocarbon evidence from Gough's Cave, southwest England

Gough's Cave is still Britain's most significant Later Upper Palaeolithic site. New ultrafiltered radiocarbon determinations on bone change our understanding of its occupation, by demonstrating that this lasted for only a very short span of time, at the beginning of the Lateglacial Interstadial (Greenland Interstadial 1 (GI-1: Bølling and Allerød)). The application of Bayesian modelling to the radiocarbon dates from this, and other sites from the period in southwest England, suggests that re-colonization after the Last Glacial Maximum took place only after 14,700 cal BP, and is, therefore, more recent than that of the Paris Basin and the Belgian Ardennes. On their own, the radiocarbon determinations cannot tell us whether re-colonization was synchronous with, just prior to, or after, Lateglacial warming. Isotopic studies of humanly-modified mammalian tooth enamel may be one way forward.     

The influence of pretreatment chemistry on the radiocarbon dating of Campanian Ignimbrite-aged charcoal from Kostenki 14 (Russia)

The presence of an independently dated marker in an archaeological site offers rare opportunities for assessing the reliability of radiocarbon dates, especially when these are close to the age limit of the technique. Two different pretreatment protocols (routine ABA and more rigorous ABOx-SC) were employed in the chemical preparation of the same charcoal sample from a layer closely associated to the Campanian Ignimbrite tephra at the Russian Palaeolithic site of Kostenki 14 (Markina Gora). The ABA-treated fraction gave an age of ∼33 ¹⁴C ka BP, comparable to a previous determination from the same layer, whereas the ABOx-SC produced an older age of ∼35 ¹⁴C ka BP. This is the first radiocarbon determination of an archaeological sample to provide an age consistent with the “calendar” age for the CI tephra marker.     

Assessment of oxygen plasma ashing as a pre-treatment for radiocarbon dating

This study investigates the potential of low-temperature oxygen plasma ashing as a technique for decontaminating charcoal and wood samples prior to radiocarbon dating. Plasma ashing is demonstrated to be rapid, controllable and surface-specific. Different organic materials clearly ash at different rates, however, the ability of plasma ashing to selectively ash different organic components is limited in heterogeneous sample matrices. This is because oxidation is confined to the immediate sample surface. Comparison of radiocarbon dates obtained from identical aliquots of contaminated ancient charcoal pre-treated by acid–base–acid (ABA), acid–base-oxidation-stepped combustion (ABOx-SC) and plasma ashing suggests that the technique performs as well as the ABA pre-treatment but does not remove as much contamination as the ABOx-SC technique. Plasma ashing may be particularly useful in cases where sample size is limiting.