Magmatism in the eastern Aleutian Arc: temporal characteristic of igneous activity on Akutan Island

Lavas from Akutan Island, located in the eastern Aleutian arc at the transition between continental and oceanic crust, show a gradual change in their petrologic and chemical characteristics over the last 4 million years. The oldest lavas exposed on the island, the Hot Springs Bay Volcanics (HSBV), range from magnesian basalt to dacite (45%–62% SiO₂). The most mafic basalts contain salitic clinopyroxene, Cr- and Al-rich spinel, and pargasitic amphibole suggesting that they were derived from relatively hydrous magmas at greater pressures than lavas from the younger Akutan Volcanics (AKV) and the modern volcano (MOD). AKV lavas also range between basalt and dacite (46%–63% SiO₂), but contain no hydrous phenocrysts and seem to have fractionated within a shallow level magma chamber. Lavas from the modern volcano are andesitic (52%–57% SiO₂) and have a mineral assemblage similar to that of AKV lavas of similar composition. With the exception of clinopyroxene and spinel in the most mafic lavas, the compositions of plagioclase (An_92?45), olivine (Fo_88?51), orthopyroxene (En_69?56), and titanomagnetite (15%–21% TiO₂) phenocrysts found in these lavas are within the range observed in lavas from other Aleutian volcanoes. Variations in the major element chemistry of the older lavas can be reproduced by fractional crystallization of the observed mineral assemblages, however closed system crystal fractionation models are inadequate to explain the trace element variations. During the last 4 million years, La/Yb ratios have decreased (6.5–3.3 for HSBV lavas and 2.9–1.9 for MOD lavas) whereas Ba/La ratios appear to have increased slightly (37–43 for HSBV and AKV, and 41–45 of MOD). The lower La/Yb ratios of MOD lavas correspond with lower total abundances of the REE and slightly higher Sr and Pb isotopic ratios. The increased⁸⁷Sr/⁸⁶Sr ratios and Pb isotopic ratios in the MOD lavas, the less enriched LREE, and the higher Ba/La ratios may result from partial melting of an arc source which has experienced previous melting events but has continued to be contaminated by a component from the subducting slab. It may also indicate a change in the degree of partial melting of the underlying mantle, which corresponds to a different percentage of a slab derived component being incorporated into the overlying mantle.     

Velocity-space maps and transforms of tracking observations for orbital trajectory state analysis

The orbital state of a satellite in a central force field can be uniquely described by its velocity hodograph, a circle, rather than the Keplerian conic. Also, its coordinate-frame rotation about the attracting center is definable, without singularity, by the four-parameter set of Euler parameters. A unified state model of orbital trajectory and attitude dynamics has previously been developed by use of state variables of the orbital velocity hodograph and Euler parameters. The dynamical constraint equations of this orbital state model are especially effective in advanced techniques of state estimation, used for orbit determination and prediction. External observations of orbital vehicles, such as provided by optical and radar sensors of tracking systems, are transformable into corresponding velocity state maps, as presented in this paper. These transformations and the consequent state maps are essential for development of the orbit observation matrix used with the unified state matrix, in recursive estimators such as the Kalman filters. Line-of-sight rays and range spheres (or hemispheres) of observations map conformally into orthogonal spherical surfaces in velocity space, as the result of the point-contact transformations. In bispherical coordinates, the field of observation maps for a ground-based tracking system site is shown to be a reduced (or degenerate) form of the general field of observation maps for a satellite-based tracking site. These orbital state maps and transforms are directly useful in development of observation matrices for candidate observation sets, such as range only, angle only, or range plus range-rate tracking schemes. Also, surface coverage patterns can be generated for proposed new tracking systems, in mission analysis and system synthesis studies.     

Fossil organic matrices of the Callovian aragonitic ammonites from Lukow (Poland): location and composition

The micro- and nanostructures of modern and fossil aragonitic nacreous layers of cephalopod shells were studied with scanning electron microscope (SEM) and atomic force microscope (AFM). The nacreous tablets are organized in sectors, composed of acicular units. The acicular units are composed of small granules. The fossil and modern shells show some differences in granule size, but the granules are surrounded by a thin envelope in both samples. Electrophoretic and amino-acid compositions show that organic matrices are present in the fossil shells. Thus, the organic nature of the granule envelopes can be inferred from the two analytical approaches. The AFM microscopy allows us to study the nanostructures of the recent and fossil hard tissues and to observe the diagenetic changes of both the mineral and organic components.     

Physical universals in problem of precursor soliton generation

Six physical universals and two general relations in the problem of locally forced precursor soliton generation are found thcoretically in terms of the AfKdV equation derived by authors. These six universals and two general relations are examined by experiment and numerical calculation of two-layer flow based on the canonical character of the coefficients of tlie fKdV equations. From comparisons among the theoretical, numerical and experimental results, it is shown that they are in good agreement. There is not any free parameter in this theory, so the theory of the present paper can be used to predict thc wave properties of locally forced precursor soliton generation. Project supported hy Foundation of the State Education Commission for The Dynamics of Upper Ocean and grants of Physical Oceanography Laboratory of Ocean University of Qingdao.     

Fast solar electrons,interplanetary plasma and km-wave type-III radio bursts observed from the IMP-6 spacecraft

IMP-6 spacecraft observations of low frequency radio emission, fast electrons, and solar wind plasma are used to examine the dynamics of the fast electron streams which generate solar type-III radio bursts. Of twenty solar electron events observed between April, 1971 and August, 1972, four were found to be amenable to detailed analysis. Observations of the direction of arrival of the radio emission at different frequencies were combined with the solar wind density and velocity measurements at 1 AU to define an Archimedean spiral trajectory for the radio burst exciter. The propagation characteristics of the exciter and of the fast electrons observed at 1 AU were then conpared. We find that: (1) the fast electrons excite the radio emission at the second harmonic; (2) the total distance travelled by the electrons was between 30 and 70% longer than the length of the smooth spiral defined by the radio observations; (3) this additional distance travelled is the result of scattering of the electrons in the interplanetary medium; (4) the observations are consistent with negligible true energy loss by the fast electrons.     

Enzymatic microbial Mn(II) oxidation and Mn biooxide production in the Guaymas Basin deep-sea hydrothermal plume

Microorganisms play important roles in mediating biogeochemical reactions in deep-sea hydrothermal plumes, but little is known regarding the mechanisms that underpin these transformations. At Guaymas Basin (GB) in the Gulf of California, hydrothermal vents inject fluids laden with dissolved Mn(II) (dMn) into the deep waters of the basin where it is oxidized and precipitated as particulate Mn(III/IV) oxides, forming turbid hydrothermal “clouds”. Previous studies have predicted extremely short residence times for dMn at GB and suggested they are the result of microbially-mediated Mn(II) oxidation and precipitation. Here we present biogeochemical results that support a central role for microorganisms in driving Mn(II) oxidation in the GB hydrothermal plume, with enzymes being the primary catalytic agent. dMn removal rates at GB are remarkably fast for a deep-sea hydrothermal plume (up to 2 nM/h). These rapid rates were only observed within the plume, not in background deep-sea water above the GB plume or at GB plume depths (∼1750-2000 m) in the neighboring Carmen Basin, where there is no known venting. dMn removal is dramatically inhibited under anoxic conditions and by the presence of the biological poison, sodium azide. A conspicuous temperature optimum of dMn removal rates (∼40 °C) and a saturation-like (i.e. Michaelis-Menten) response to O₂ concentration were observed, indicating an enzymatic mechanism. dMn removal was resistant to heat treatment used to select for spore-forming organisms, but very sensitive to low concentrations of added Cu, a cofactor required by the putative Mn(II)-oxidizing enzyme. Extended X-ray absorption fine structure spectroscopy (EXAFS) and synchrotron radiation-based X-ray diffraction (SR-XRD) revealed the Mn oxides to have a hexagonal birnessite or δ-MnO₂-like mineral structure, indicating that these freshly formed deep-sea Mn oxides are strikingly similar to primary biogenic Mn oxides produced by laboratory cultures of bacteria. Overall, these results reveal a vigorous Mn biogeochemical cycle in the GB hydrothermal plume, where a distinct microbial community enzymatically catalyzes rapid Mn(II) oxidation and the production of Mn biooxides.     

Tropical cyclone contribution to extreme rainfall over southwest Pacific Island nations

Southwest Pacific nations are among some of the worst impacted and most vulnerable globally in terms of tropical cyclone (TC)-induced flooding and accompanying risks. This study objectively quantifies the fractional contribution of TCs to extreme rainfall (hereafter, TC contributions) in the context of climate variability and change. We show that TC contributions to extreme rainfall are substantially enhanced during active phases of the Madden–Julian Oscillation and by El Niño conditions (particularly over the eastern southwest Pacific region); this enhancement is primarily attributed to increased TC activity during these event periods. There are also indications of increasing intensities of TC-induced extreme rainfall events over the past few decades. A key part of this work involves development of sophisticated Bayesian regression models for individual island nations in order to better understand the synergistic relationships between TC-induced extreme rainfall and combinations of various climatic drivers that modulate the relationship. Such models are found to be very useful for not only assessing probabilities of TC- and non-TC induced extreme rainfall events but also evaluating probabilities of extreme rainfall for cases with different underlying climatic conditions. For example, TC-induced extreme rainfall probability over Samoa can vary from ~ 95 to ~ 75% during a La Niña period, if it coincides with an active or inactive phase of the MJO, and can be reduced to ~ 30% during a combination of El Niño period and inactive phase of the MJO. Several other such cases have been assessed for different island nations, providing information that have potentially important implications for planning and preparing for TC risks in vulnerable Pacific Island nations.