Phase Relations in the Fe-Ni-Cu-PGE-S System at Magmatic Temperature and Application to Massive Sulphide Ores of the Sudbury Igneous Complex

Experiments in the Fe–Ni–Cu–S system wereperformed to identify the role of the metal/S atomic ratio onmonosulphide–melt partition coefficients and closed-systemfractionation paths. In accord with previous work, D_Cu is     

Plume-Lithosphere Interaction and the Origin of Continental Rift-related Alkaline Volcanism--the Chyulu Hills Volcanic Province, Southern Kenya

Geochemical data are presented for primitive alkaline lavasfrom the Chyulu Hills Volcanic Province of southern Kenya, situatedsome 100 km east of the Kenya Rift Valley. In addition to theirprimitive compositions, a striking and ubiquitous feature isa strong but variable depletion in K relative to other highlyincompatible elements when normalized to primitive mantle values.Semi-quantitative models are developed that best explain thepetrogenesis of these lavas in terms of partial melting of asource that contained residual amphibole (but not phlogopite).The presence of amphibole implies a source in the subcontinentallithosphere rather than the asthenosphere. It is suggested thatthe amphibole is of metasomatic origin and was precipitatedin the lithospheric mantle by infiltrating fluids and/or meltsderived from rising mantle plume material. A raised geothermas a consequence of the continued ascent of the plume materialled to dehydration melting of the metasomatized mantle and generationof the Chyulu Hills lavas. It is proposed that the Chyulu HillsVolcanic Province represents an analogue for the earliest stagesof continental rift initiation, during which interaction betweena plume and initially refractory lithosphere may lead to thegeneration of lithospheric melts. KEY WORDS: rift-related alkaline volcanism; residual amphibole; subcontinental lithosphere     

The Geochemistry of Lavas from the Gomores Archipelago, Western Indian Ocean: Petrogenesis and Mantle Source Region Characteristics

New mineral and bulk-rock analyses, as well as Nd, Sr and Pbisotope compositions are presented for lavas from Grande Comore,Moheli and Mayotte, thru of the four main islands of the ComoresArchipelago in the western Indian Ocean, and these data an usedto evaluate the petrogenesis, evolution and mantle source regioncharacteristics of Comorean lavas. The typically silica-undersaturated,alkaline lavas from all three islands can be grouped into twodistinct types: La Grille-type (LGT) lavas, which display strongrelative depletions in K, and Karthala-type (KT) lavas, whichdo not. With the exception of the lavas erupted by La Grillevolcano on Grande Comore, which exhibit the petrographic andgeochemical characteristics expected of primary mantle-derivedmagmas, all Comorean lavas analysed have experienced compositionalmodifications after they segregated from their source regions.Much of this variation can be explained quantitatively by fractionalcrystallization processes dominated by the fractionation ofolivineand clinopyroxene. Semi-quantitative modelling shows that theconsistent and fundamental difference in composition betweenK-depleted LGT lavas and normal KT lavas can be attributed topartial melting processes, provided amphibole is a residualmantle phase after extraction of LGT magmas at low degrees ofmelting. Low absolute abundances of the heavy rare earth elementsin LGT magmas are interpreted to reflect partial melting withinthe garnet stability field In contrast, KT magmas, which donot show relative K depletions, are considered to be the productsof somewhat larger degrees of partial melting of an amphibolefreesource at comparatively shallower depths. Whereas the Nd andSr isotopic compositions of Comorean lavas (which show a significantrange: ⁸⁷Sr/⁸⁶Sr = 0.70319–0.70393; ¹⁴³Nd/Nd = 0.51263–0.51288)bear evidence for a time-averaged depletion in incompatibleelements, the high incompatible element abundances of the lavasare interpreted to reflect the effects of a recent mantle enrichmentevent. At depths well within the garnet stability field thismantle enrichment is interpreted to have taken the form of modalmetasomatism with the introduction of amphibole (giving riseto the source of LGT magmas), whereas cryptic metasomatism tookplace at shallower levels (giving rise to the source of KT lavas).The Nd, Sr and Pb isotope signature of the majority of Comoreanlavas (both LGT and KT) is proposed to be the result of predominant4contributions from a somewhat heterogeneous source4 4 4 presentativeof the ambient sub-Comorean mantle, comprising a mixture betweena HIMU component and a component on the depleted portion ofthe mantle array (possibly the source of Indian Ocean MORB),with only limited contributions from an EM I plume component.The lavas erupted by Karthala volcano (the youngest Comoreanlavas), however, have significantly different isotopic compositionsfrom all other Comorean lavas (lower ¹⁴³Nd/¹⁴⁴Nd and higher⁸⁷Sr/⁸⁶Sr), suggesting increased contributions from the EM Icomponent. KEY WORDS: basalt petrogenesis; Comores; mantle geochemistry; ocean island basalts ^*Telephone: 27-21-6502921. Fax: 27-21-6503781 e-mail: alr{at}geology.uct.ac.za.