Rare earth elements and yttrium in ferromanganese deposits from the South China Sea: distribution, composition and resource considerations

Ferromanganese nodules and crusts contain relatively high concentration of rare earth elements(REE) and yttrium(REY),with a growing interest in exploitation as an alternative to land-based REY resources.On the basis of comprehensive geochemical approach,the abundance and distribution of REY in the ferromanganese nodules from the South China Sea are analyzed.The results indicate that the REY contents in ferromanganese deposits show a clear geographic regularity.Total REY contents range from 69.1×10~(–6) to 2 919.4×10~(–6),with an average value of 1 459.5×10~(–6).Especially,the enrichment rate of Ce content is high,accounting for almost 60% of the total REY.This REE enrichment is controlled mainly by the sorption of ferromanganese oxides and clay minerals in the nodules and crusts.Moreover,the total REY are higher in ferromanganese deposits of hydrogenous origin than of diagenetic origin.Finally,Light REE(LREE) and heavy REE(HREE) oxides of the ferromanganese deposits in the study area can be classified into four grades: non-enriched type,weakly enriched type,enriched type,and extremely enriched type.According to the classification criteria of rare earth resources,the Xisha and Zhongsha platform-central deep basin areas show a great potential for these rare earth metals.     

Ibiza Absolute Calibration Experiment: Survey and Preliminary Results

Within the framework of a project comprising part of the Spanish Space Program related to the JASON-1 CNES (Centre National d'Etudes Spatiales)/NASA (National Aeronautics and Space Administration) mission, a campaign was conducted from June 9–17, 2003, on the Absolute Calibration Site of the island of Ibiza. The objective was to determine the local marine geoid slope under the ascending (187) and descending (248) Jason-1 ground tracks, in order to allow a better extrapolation of the open-ocean altimetric data with on-shore tide gauge locations, and thereby improve the overall precision of the calibration process. For this we have used a catamaran with two GPS antennas onboard, following the Corsica/Senetosa design (Bonnefond et al. 2003a Bonnefond, P., Exertier, P., Laurain, O., Menard, Y., Orsoni, A., Jeansou, E., Haines, B., Kubitschek, D. and Born, G. 2003a. Leveling Sea Surface using a GPS catamaran. Marine Geodesy, 26(3–4): 319–334. [Taylor &; Francis Online], [Web of Science ®] , [Google Scholar]). Five GPS reference stations were deployed in order to reduce the distance between the areas covered by the catamaran and the fixed GPS receiver used in the kinematic process. The geodetic activities (e.g., GPS, leveling) have enabled the building of a very accurate (few mm) network in a reference frame compatible with the satellite altimetry missions (ITRF 2000). The GPS kinematic data were processed using two different software programmes, allowing checking of the consistency of the solutions. If the standard deviation of the differences (3.3 cm) is close to the kinematic process precision, they exhibit some large values (up to 14 cm). These large discrepancies have been reduced using a weighting based on the crossover differences. Inasmuch as the distances between the tide gauges and the areas covered by the GPS catamaran were becoming large, we have used the MOG2D ocean model (Carrère and Lyard 2003 Carrère, L. and Lyard, F. 2003. Modelling the barotropic response of the global ocean to atmospheric wind and pressure forcing—comparisons with observations. Geophys. Res. Letters, 30(6) [Google Scholar]) to correct the sea surface from tides. In the farthest areas, the crossover differences show an improvement by a factor of two. Finally, we also present preliminary results on Jason-1 altimeter calibration using the derived marine geoid. From this analysis, the altimeter bias is estimated to be 120 ± 5 mm. The quality of this first result validates the whole GPS-based marine geoid processing, for which the accuracy is estimated to be better than 3 cm rms at crossovers.     

Evinosponges in the Triassic Esino Limestone (Southern Alps): documentation of early lithification and late diagenetic overprint

A carbonate buildup of Middle Triassic age, the Esino Limestone, outcrops in the Southern Calcareous Alps of Lombardy (N Italy). Along its margin and within the open subtidal facies, the Esino Limestone contains calcite cement-filled cavities of cm to m size. These features, known as evinosponges, may form pervasive networks within the host rock. The filling consists of concentric, isopachous layers of fibrous low-Mg calcite crystals characterized by strong undulose extinction and bent cleavages. The cement crusts are non-luminescent under cathodoluminescence, but both cements and host rock are cross-cut by micro-fractures filled with bright-luminescent calcite, related to late void-filling sparite. Mixing of different carbonates is reflected in stable isotope data. On the hand specimen scale, the oxygen and carbon isotope compositions of cements and host rock show little variation. When compared on a regional scale, the values cover a broad range from δ¹⁸O(PDB)=?5‰ to ?12‰ and from δ¹³O =0‰ to +3‰. The linear covariant trends defined by the oxygen and carbon isotope data for different sampling regions reflect the admixture of late, isotopically depleted calcite with an isotopically enriched non-luminescent calcite of early diagenetic origin. The Esino Limestone fibrous cements, which were probably precipitated in the marine or marine-meteoric phreatic environment, were affected by late diagenetic processes that caused mineral deformation and isotopic depletion through recrystallization and the admixture of a later calcite. These later calcites precipitated from penetrative fluids possibly related to Late Triassic volcanic activity and/or to the Late Cretaceous/Early Palaeogene alpine orogeny.     

Styles of ice-marginal deformation at Hagafellsjökull-Eystri, Iceland during the 1998/99 winter-spring surge

This paper describes the internal architecture of a push moraine formed by a winter-spring surge of Hagafellsjökull-Eystri (Iceland) in 1998/99. The sedimentary architecture of this push moraine consists of a multilayered slab of glaciofluvial sediments with a monoclinal structure that has been displaced laterally by the advancing ice margin. The crest and ice-distal face of the moraine consist of subhorizontal sediment sheets, while the ice-proximal face dips steeply (45° to 90°) towards the ice margin. The core of the moraine consists of frozen sediment and thin slabs of glacier ice are embedded in its proximal face. The sediment slabs are characterized by both brittle and ductile styles of deformation. We argue that the observed variation in deformation style is dependent on whether the glacial foreland was frozen or unfrozen at the time of displacement. Frozen foreland would behave in a brittle fashion, while unfrozen foreland is likely to have deformed in a more ductile manner. The associated spatial variations in the degree of foreland freezing could be explained by variation in ice-marginal snow cover. We conclude that the thermal regime of the foreland, and the timing of the ice advance, is of importance to the style of internal deformation found within ice-marginal push moraines.     

Sediment transport and bedforms in a carbonate tidal inlet; Lee Stocking Island, Exumas, Bahamas

An active oolitic sand wave was monitored for a period of 37 days in order to address the relationship between the direction and strength of tidal currents and the resultant geometry, and amount and direction of migration of bedforms in carbonate sands. The study area is situated in a tidal channel near Lee Stocking Island (Exumas, Bahamas) containing an estimated 5.5 to 6 × 10⁵ m³ of mobile oolitic sand. Tidal ranges within the inlet are microtidal and the maximum current velocity at the studied site is 0.6 m s^?1. At least 300–400 m³ of mostly oolitic sand are formed within, or brought into, the channel area every year. The tidal inlet is subdivided into an ocean-orientated segment, in which sand waves are shaped by both flood and ebb tides, and a platform-orientated segment, where sand waves are mainly shaped by flood tides. The studied sand wave lies on the platformward flood-tide dominated segment in a water depth of 3.5.4.5 m. During the 37 days of observation, the oolitic and bioclastic sand wave migrated 4 m in the direction of the dominant flood current. The increments of migration were directly related to the strength of the tide. During each tidal cycle, bedforms formed depending on the strength of the tidal current, tidal range and their location on the sand wave. During flood tides, a steep lee and a gentle stoss side formed and current ripples and small dunes developed on the crest of the sand wave, while the trough developed only ripples. The average lee slope of the sand wave is 24.2°, and therefore steeper than typical siliciclastic sand waves. During ebb tides, portions of the crest are eroded creating a convex upward ebb stoss side, covered with climbing cuspate and linguoid ripples and composite dunes. The area between the ebb-lee side and the trough is covered with fan systems, sinuous ripples and dunes. The migration of all bedforms deviated to a variable degree from the main current direction, reflecting complex flow patterns in the tidal inlet. Small bedforms displayed the largest deviation, migrating at an angle of up to 90° and more to the dominant current direction during spring tides.     

Spatially varied soil erosion under different climates

Abstract

The spatial variability of the factors of the universal soil loss equation is examined on the mediterranean basin of Conca de Tremp covering 43.1 km² in Spain. The evaluation of the rainfall erosivity R and the soil erodibility K is relatively straightforward and spatially-averaged values of these parameters can be applied to the entire basin. Conversely, the spatial variability of annual soil erosion losses on large basins depends primarily on the factors L, S and C describing topographic, vegetation and land use parameters. A grid size analysis of soil erosion losses from the Conca de Tremp basin under mediterranean climatic conditions in Spain shows excellent agreement with the earlier results on the Chaudière basin in Canada. It is concluded for both basins that unbiassed estimates of soil erosion losses are obtained for grid sizes less than about 0.125 km². The analysis of the Conca de Tremp basin validates the use of the grid size factor proposed by Julien & Frenette (1987). It is also found that the grid size factor primarily depends on the average slope gradient which decreases with increasing grid size or drainage area. On the other hand, the grid size factor does not depend on the spatial variability of the factors R, K, L and C.     

Climate variability in the SE Alps of Italy over the past 17 000 years reconstructed from a stalagmite record

Stalagmite SV1 from Grotta Savi, located at the SE margin of the European Alps (Italy), is the first Alpine speleothem that continuously spans the past c . 17kyr. Extension rate and δ¹⁸O_c record for the Lateglacial probably reflect a combination of temperature and rainfall, with rainfall exerting the dominant effect. Low speleothem calcite δ¹⁸ O_c values were recorded from c . 14.5 and 12.35 kyr, during GI-1 (Bølling— Allerød) interstadial, which in our interpretation, was warm and wet. The GS-1 (Younger Dryas) was characterized by a shift to heavier δ¹⁸ O_c, coinciding with δ¹³C_c enrichment and extremely low extension rate (<8 μm/year). These characteristics indicate that GS-1 climate was cool and dry in the SE Alps. Calibration using historical data revealed that there is a positive δ¹⁸O_c/dT relationship. A 1°C rise in mean annual temperature should correspond to c . 2.85% increase of SV-1 δc¹⁸O_c. We reconstructed a slow and steady temperature rise of c . 0.5°C since 10 kyr BP, in broad agreement with reconstructions from pollen data for SE Europe. Stalagmite SV1 indicates that climate variability in the SE Alps has been influenced by the Mediterranean Sea for the past c . 17 kyr.     

COMPARISON AMONG EMPIRICAL PROBABILITY DENSITY FUNCTIONS OF THE VERTICAL VELOCITY IN THE SURFACE LAYER BASED ON HIGHER ORDER CORRELATIONS

Vertical velocity fluctuations were measured in theatmospheric surface layer by means of an ultrasonic anemometer andhigher order correlations were calculated on two time series, recordedin unstable and neutral conditions, and selected for the wholemeasurement period on the basis of the inversion test (stationaritytest). Comparisons have been made between observed and predictedcorrelations by considering Gaussian joint-PDF and Gram-Charlierseries expansions truncated to the fourth and sixth order as doneearlier by Frenkiel and Klebanoff. A bi-Gaussian PDF, given by amixture of two Gaussian PDFs, has also been considered. This lasthas been constructed assuming that either the first three or the firstfour moments are given, and the relationships between correlationfunctions of different order are derived. The departure from Gaussianbehaviour in both stability conditions is derived. Though Gram-Charlier series expansions show a good correspondence toexperimental reality, their use as non-Gaussian probabilitydistributions cannot be suggested in theoretical approaches andshould be considered with care in practical applications, due topossible occurrences of small negative probabilities. The resultsshown in this paper support the applicability of the bi-Gaussian PDFcreated using up to the fourth moment.