Probing the wind–wind collision in γ2 Velorum with high-resolution Chandra X-ray spectroscopy: evidence for sudden radiative braking and non-equilibrium ionization

We present a new analysis of an archived Chandra HETGS X-ray spectrum of the WR+O colliding wind binary γ² Velorum. The spectrum is dominated by emission lines from astrophysically abundant elements: Ne, Mg, Si, S and Fe. From a combination of broad-band spectral analysis and an analysis of line flux ratios we infer a wide range of temperatures in the X-ray-emitting plasma (∼4–40 MK). As in the previously published analysis, we find the X-ray emission lines are essentially unshifted, with a mean FWHM of  1240 ± 30 km s⁻¹  . Calculations of line profiles based on hydrodynamical simulations of the wind–wind collision predict lines that are blueshifted by a few hundred  km s⁻¹  . The lack of any observed shift in the lines may be evidence of a large shock-cone opening half-angle (>85°), and we suggest this may be evidence of sudden radiative braking. From the R and G ratios measured from He-like forbidden-intercombination-resonance triplets we find evidence that the Mg  xi emission originates from hotter gas closer to the O star than the Si  xiii emission, which suggests that non-equilibrium ionization may be present.     

Combining in situ isotopic, trace element and textural analyses of quartz from four magmatic-hydrothermal ore deposits

This study couples in situ ¹⁶O, ¹⁷O and ¹⁸O isotope and in situ trace element analyses to investigate and characterize the geochemical and textural complexity of magmatic-hydrothermal quartz crystals. Euhedral quartz crystals contemporaneous with mineralization were obtained from four magmatic-hydrothermal ore deposits: El Indio Au–Ag–Cu deposit; Summitville Au–Ag–Cu deposit; North Parkes Cu–Au deposit and Kingsgate quartz-Mo–Bi–W deposit. The internal features of the crystals were imaged using cathodoluminescence and qualitative electron microprobe maps. Quantitative isotopic data were collected in situ using 157 nm laser ablation inductively coupled plasma mass spectrometry (for 40 trace elements in quartz) and sensitive high-resolution ion microprobe (for 3 isotopes in quartz). Imaging revealed fine oscillatory zoning, sector zoning, complex “macromosaic” textures and hidden xenocrystic cores. In situ oxygen isotope analyses revealed a δ¹⁸O range of up to 12.4 ± 0.3 ‰ in a single crystal—the largest isotopic range ever ascribed to oscillatory zonation in quartz. Some of these crystals contain a heavier δ¹⁸O signature than expected by existing models. While sector-zoned crystals exhibited strong trace element variations between faces, no evidence for anisotropic isotope fractionation was found. We found: (1) isotopic heterogeneity in hydrothermal quartz crystals is common and precludes provenance analysis (e.g., δD–δ¹⁸O) using bulk analytical techniques, (2) the trace element signature of quartz is not an effective pathfinder toward noble metal mineralization and (3) in three of the four samples, both textural and isotopic data indicate non-equilibrium deposition of quartz.     

Solubility of gold in hydrothermal chloride solutions

The solubility of gold has been determined in chloride solutions in the temperature range 300–500°C corresponding to the inferred range for the formation of “hypothermal” gold deposits. The solutions were buffered with respect to HC1 by a K-feldspar-muscovite-quartz assemblage, and to oxygen by the assemblage haematite-magnetite. Solubilities increased rapidly with temperature from about 10 p.p.m. at 300°C, to 500 and 1000 p.p.m. at 500°C at 1000 and 2000 bar, respectively.These results are discussed in terms of possible solution species in this high-temperature region where molecular behaviour predominates in the solution equilibria. It is suggested that gold and other metals may be transported to the site of ore-deposition in undersaturated high-temperature solutions. Ore deposition may take place at lower temperatures where ionic gold chloride or sulfide species dominate the chemistry of the ore solutions.     

Chemical and isotopic changes in the hydrology of the tauhara geothermal field due to exploitation at wairakei

Depressurisation of the Tauhara field due to massive withdrawal of deep chloride water from the adjacent Wairakei field for geothermal power has caused considerably hydrological and chemical changes at Tauhara. In the undisturbed state (1962), deep chloride water discharged as hot and boiling dilute chloride springs on the east and west flanks of the field (the Terrace and Spa areas, respectively), while steam from the two-phase zone of the deep system produced by absorption into near-surface groundwater, steam-heated sulphatebicarbonate waters and by mixing with chloride water, chloride-sulphate waters. By 1978–1981 the chloride waters had stopped discharging on the western flank, the steam flow towards the surface had greatly increased (by 5–10 fold) increasing the volume and temperature of the steam-heated waters, but the dilute chloride waters of the Terrace area had changed very little. Silica concentrations in the near-surface waters appear to be controlled by the solubility of amorphous silica, which is present in the surface zone rocks (e.g., Taupo pumice breccias). The increased steam flow led to enrichment in the ¹³O and D contents of the steam-heated waters by loss of secondary steam and enlargement of the area and intensity of steaming ground, the latter accompanied by hydrothermal eruptions in 1974 and 1981. Generation of the steam-heated waters has been modelled using mass, heat and isotope balances. The model is consistent with observed heat and cold groundwater flows and requires that a large proportion of the heat from adsorbed primary steam is released as secondary steam. Tritium contents show that the steam-heated waters have a mean residence time of 50–100 years. In the future, invasion of the deep system by cooler surface waters may reduce steam flow and lower surface aquifer temperatures.     

Peat extraction, conservation and the rural economy in Northern Ireland

Northern Ireland has a tradition of peat cutting; 78 per cent by area of remaining lowland bogs and 46 per cent of blanket bogs have been cut in the past. Since the early 1980s, machine peat extraction for fuel and horticulture has increased, against a background of changing economic support for agriculture, high rural unemployment and agricultural underemployment. Cutting fuel peat can reduce household fuel costs and some peat fuel is sold to gain income. Horticultural peat is cut mainly for sale. Expansion of machine extraction, with possible environmental impacts, occurred as interest in peatland conservation increased. Potential conflict arises between local economic needs and conservation. Machine cutting for fuel is widespread, but affects only 2.6 per cent of the blanket peat area; horticultural extraction is more localized and is only one-fifth of the extent of fuel extraction. Altitude, distance from roads, land ownership and rights, turbary, religious affiliation, local economic needs and the role of government departments all contribute to explaining the distribution and extent of extraction.     

Biogenic hydrocarbons in fluid inclusions from the aberfoyle tin-tungsten deposit, Tasmania, Australia

Trace components in fluid inclusions from the Aberfoyle tin-tungsten deposit in Tasmania, Australia, were examined by thermal decrepitation-mass spectrometry. The technique involves the decrepitation of fluid inclusions by stepwise heating in the source of a mass spectrometer. In addition to water, other species identified were carbon dioxide and hydrocarbons. Detailed analysis of these hydrocarbons showed that they ranged in carbon number from C₁ up to at least C₃₃ and probably comprised, in part, biological marker compounds, previously unreported in such high-temperature environments. Their presence suggests that the fluid responsible for mineralisation was not entirely magmatic but contained a non-magmatic component evolved through fluid-rock interaction in the sedimentary country rocks.