A 2000‐year lipid biomarker record preserved in a stalagmite from north‐west Scotland

Previous studies on lipid biomarkers preserved in Chinese stalagmites have indicated that ratios of low‐molecular‐weight (LMW) to high‐molecular‐weight (HMW) n‐alkanes, n‐alkan‐2‐ones, n‐alkanols and n‐alkanoic acids can be used as an index of vegetation versus microbial organic matter input to the system and, by extension, a marker of climatic changes, with increases in the proportion of LMW compounds coinciding with colder periods. Here we test whether this hypothesis is equally applicable to a different geographical region (north‐west Scotland), by examining a stalagmite record of the past 200 years, and a wider range of lipid markers. We also test the applicability of other lipid proxies in this context, including the use of n‐alkane ratios, to interpret vegetation changes, and unsaturated alkanoic acid ratios as climatic indicators. The results show that lipid proxies preserved in stalagmites, and especially those related to vegetation, are potentially extremely useful in palaeoenvironmental research. Of particular value is the use of C₂₇/C₃₁ n‐alkane ratios as a proxy for vegetation change, clearly indicating variations between herbaceous and arboreal cover. This proxy has now been successfully applied to samples from diverse environments, and can be considered sufficiently robust to be of use in analysing future stalagmite records. It will be of particular value in areas where reliable pollen records are not available, as is often the case with deeper cave deposits. However, the division between LMW and HMW aliphatic compounds is not a clear‐cut case of microbial versus plant activity, with the changes in LMW compounds relating more closely to those in their HMW analogues than in specific bacterial biomarkers. The use of unsaturated alkanoic acid ratios here gives conflicting results, with the observed variation through time depending on the isomer measured. The discrepancies between the findings of this study and previous work are likely to be due to the varying controls on the lipids (original organic matter input, and compound degradation), which in turn will be affected by whether the main climatic limiting factor on the soil is temperature or precipitation. This suggests that lipid proxies preserved in stalagmites must be interpreted with care, particularly in the case of bacterial compounds which may be derived from within the cave or from the soil. However, many of these issues can be resolved by the use of multi‐proxy studies. Copyright © 2011 John Wiley & Sons, Ltd.     

Relationships between lightning activity and various thundercloud parameters: satellite and modelling studies

The lightning frequency model developed by Baker et al. [Baker, M.B., Christian, H.J., Latham, J., 1995. A computational study of the relationships linking lightning frequency and other thundercloud parameters, Q. J. R. Meteorol. Soc., 121, 1525–1548] has been refined and extended, in an effort to provide a more realistic framework from which to examine computationally the relationships that might exist between lightning frequency f (which is now being routinely measured from a satellite, using the NASA/MSFC Optical Transient Detector (OTD)) and a variety of cloud physical parameters. Specifically, superior or more comprehensive representations were utilised of: (1) glaciation via the Hallett–Mossop (H–M) process; (2) the updraught structure of the model cloud; (3) the liquid-water-content structure of the model cloud; (4) the role of the reversal temperature T_rev in influencing lightning characteristics; (5) the critical breakdown field for lightning initiation; and (6) the electrical characteristics of the ice crystal anvil of the model cloud. Although our extended studies yielded some new insights into the problem, the basic pattern of relationships between f and the other parameters was very close to that reported by Baker et al. (1995). The more elaborate treatment of T_rev restricted somewhat the range of conditions under which reverse-polarity lightning could be produced if the cloud glaciated via H–M, but confirmed the earlier conclusion that such lightning would not occur if the glaciation was of the Fletcher type. The computations yielded preliminary support for the hypothesis that satellite measurements of f might be used to determine values of the ice-content of cumulonimbus anvils: a parameter of climatological importance. The successful launch and continuing satisfactory functioning of the OTD [Christian, H.J., Goodman, S., 1992. Global observations of lightning from space, Proc. 9th Int. Conf. on Atmospheric Electricity, St. Petersburg, pp. 316–321; Christian, H.J., Blakesee, R.J., Goodman, S.J., 1992. Lightning imaging sensor (LIS) for the earth observing system. NASA Tech. Memorandum, 4350] make it possible—with a high degree of precision—to measure lightning location, occurrence time and frequency f over extensive areas of the Earth's surface. Measured global distributions of lightning and associated lightning stroke radiance demonstrate that: lightning activity is particularly pronounced over the tropics, much greater over land than over the oceans, and exhibits great seasonal variability; lightning radiance tends to be greater over the oceans, less when lightning activity is high, and greater in the Northern Hemisphere winter than summer.     

A review and comparison of fracture mineral investigations and their application to radioactive waste disposal

A compilation and comparison of fracture mineral studies from the Canadian and Fennoscandian Shields and the French Massif Central shows many similarities indicating larger external control over fracture mineral deposition, with different rock types exerting local controls. The sites investigated represent a wide range of geological settings, and host rock types ranging from felsic intrusive and extrusives to ultramafic intrusives and volcanics that span an age range from 2.5 to 0.36 Ga. Typical fracture minerals found at Canadian Shield sites include calcite, quartz, chlorite and clays, and these do not appear to be dependant on age, erosional depth or geological environment. The Fennoscandian Shield has a much larger variety of fracture filling minerals with epidote, zeolites, prehnite, fluorite, pyrrhotite, Fe oxides, serpentine, graphite, magnesite and barite in addition to the minerals typically found at Canadian Shield sites. The major control on fracture mineral type is most likely variations in rock type, and fluid chemistry and temperature.     

Climatic and geographic patterns of river runoff formation in Northern Eurasia

Siberian rivers are of global importance as they impact on the freshwater budget of the Arctic Ocean, which affects the Thermo-Haline circulation in the North Atlantic Ocean. Siberian rivers, in particular the tributaries to the larger rivers, are under-represented in the international river-regime databases. The runoff of three Russian rivers in the Central Siberian taiga (Kureyka, Karabula and Erba) is modelled to analyse the relative influence of climate. In addition three rivers (Rhine, Maas and Odra) in Western Europe are similarly assessed as a control. The results show that the role of precipitation and autocorrelation as factors in the formation of river runoff is stronger under oceanic climate conditions, increasing from the central regions of Northern Eurasia towards the Arctic Ocean in the North and the Atlantic in the West. At the same time the influence of summer temperatures is weakened. The formation of Northern Eurasian river runoff appears to be influenced by periodically thawing top horizons of permafrost soil. Time served as an indicator for land use change after inclusion of meteorological data in the models. Maas and Erba showed a significant influence of the time factor. For the Erba the onset of agricultural land use in the catchment coincides with a drop in runoff. A similar causal relationship is suggested for the Maas. Land use can change the formation of runoff, which in turn can be used as an environmental indicator for sustainable land use.     

The Effect of Orography on Evaporation

The effect of orography on the spatial variability of surface evaporation is studied numerically for two hill heights and two prescribed forms of surface resistance. A numerical model of the planetary boundary layer carrying scalars of temperature and specific humidity, and with a surface energy balance scheme, is employed. It is found that the difference in mean evaporation between model runs with hills and analogous runs for flat terrain may be explained primarily by an increase in surface area and adiabatic cooling at the hill surface.     

Defining area-average parameters in meteorological models for land surfaces with mesoscale heterogeneity

After a brief review of existing methods developed to describe the subgrid variability of soil and vegetation at large scale, the paper summarizes aggregation results obtained in the framework of the Hapex-Mobilhy and EFEDA field experiments. The parameter aggregation method is based on the estimation of effective parameters for the soil and for the vegetation, representative of the large area. In conditions of moderate land-surface variability, the effective surface fluxes computed using a single column model forced by effective surface parameters are close to the areally-averaged turbulent fluxes estimated by a mesoscale model. A simple method for accounting for the subgrid variability of intercepted rain is tested.     

Evaporation and energy balance of a sub‐Arctic hillslope in northern Finland

This paper presents measurements of the energy balance (radiation, sensible heat flux, evaporation) from a sub‐arctic hillside in northern Finland for a summer season. Comparisons are also made with a nearby wetland site. The hillslope measurements show an equal partition of the radiant energy into sensible and latent heat flux. The evaporative ratio of just over one half was remarkably constant throughout the season, despite very large day‐to‐day and diurnal variations of temperature, humidity deficit and radiation input. This conservative behaviour of the evaporation was caused by a strong rise in effective surface resistance to evaporation with increasing vapour pressure deficit. This suggests a strong physiological control on the evaporation, with stomata closing at times of high evaporative demand. There was no obvious impact of soil‐water stress on the evaporation. However, a comparison with the evaporation measured at a nearby mire site in 1997 suggests that the mire has a significantly lower surface resistance, even when the impact of a significantly lower humidity deficit in the earlier year is taken into account. The measurements are used to test, off‐line, the performance of MOSES (Meteorological Office Surface Exchange Scheme), a simple, but comprehensive, land surface model. The sensitivity of the energy exchanges to the thermal properties of the top soil layer (a surrogate for the upper soil/vegetation layer) is investigated with the use of the model. It is found that the evaporation is insensitive to these properties; they do, however, influence the partition of energy between the sensible heat flux and the ground heat flux (and hence the soil temperatures). It is suggested that the model needs to represent the thermal properties of the canopy more realistically. Copyright © 2002 John Wiley & Sons, Ltd.