滇西点苍山—哀牢山变质岩系锆石SHRIMP定年及其地质意义

滇西点苍山和哀牢山主体分别由下元古界苍山群和哀牢山群深变质岩系组成,被认为是前寒武纪结晶基底。选取点苍山的花岗闪长质糜棱岩(DCS-1)和哀牢山元江段黑云母花岗闪长质片麻岩(SM07-1)之中的锆石进行U-Pb SHRIMP定年。样品DCS-1和SM07-1测年结果分别为233±2.6Ma和239.8±2.8Ma。结合前人对滇西地区花岗质岩类所做的研究,揭示滇西地区在三叠纪经历一期在空间上广泛分布的岩浆事件,点苍山花岗质糜棱岩和哀牢山花岗质片麻岩的原岩为三叠纪侵位的花岗岩,其构造环境属于大陆裂谷,反映了滇西地区在三叠纪地壳物质的重新调整,而该变质岩系不是前寒武纪的结晶基底,其变质作用与山体出露地表过程和新生代构造作用有关。     

AN ANALYTICAL METHOD OF ULTRA-TRACE TELLURIUM FOR SAMPLES OF SEA-AND ENVIRONMENTAL-WATER

Tellurium is known to be a poisonous element to human health. In recent years,determination of trace tellurium has been attached great attention in connection with thewide application of its compounds and/or with environmental pollution. Literature citedreported the determination of ppb level tellurium in waste water and artificial watersamples by atomic-absorption spectrophotometry. As the tellurium content in naturalwater is extremely low, there is not yet any sensitive analytical method for determination ofits background value in various natural water. In chemical oceanography, data abouttellurium content in seawater are rather scarce. This paper will summarize and evaluate a series of our investigations on the analytical     

Design of Mooring System for Oil Storage Vessels

The floating oil storage system has been proposed as a new facility for Strategic Petroleum Reserve (SPR) in China. Mooring is one of the key technologies to ensure the safety, reliability, and performance of the oil storage system. This paper describes the concept, analysis, design and reliability of the mooring system. For mooring system design of these oil vessels, analysis is essential of the behavior of the vessel in connection with mooring facilities of nonlinear resilience. A nonlinear mathematical model for analyzing a moored vessel is established and solved. Some results of numerical simulations are presented. Assessment of the safety regarding the mooring system in terms of failure probability is carried out. Another simulation model for calculating the failure probability of the mooring system is proposed. The design parameters that have an influence on the characteristics of the failure probability have been identified. The simulation results show that the mooring system has an annual reliab     

乐亭发生特大渔业污染案渔民获赔1300多万元

2002年4月12日,天津海事法院对河北省乐亭特大渔业污染案做出一审判决,责令被告迁安第一造纸厂等9家单位连带赔偿原告乐亭18户渔民经济损失总计人民币1 365.97万元,立即停止侵害,不得再排放污水入海,消除继续污染原告养殖区域的危险。 接到判决书,原告对笔者表示说,他们“对     

湘西北渔塘地区寒武系清虚洞组风暴岩及其地质意义

在湘西北渔塘地区,下寒武统的清虚洞组下部发育一套地质特征典型、沉积序列特殊的风暴岩。其底面侵蚀构造清楚,覆盖于底面上的各层段厚度变化较大,在各层段内由下向上碎屑粒度依次变细,并相继出现叠加式丘状交错层理、平行层理和浪成沙纹层理等沉积构造,是典型的浅海风暴岩。该风暴沉积的发现,对建立湘西北地层的沉积学剖面、探讨该区风暴沉积模式的空间变化、明确成矿环境和成矿地质特征等具有重要意义。     

Structural Evolvement of Heating Treatment of Mg/AI-LDH and Preparation of Mineral Mesoporous Materials

Although hydrotalcite, or layered double hydroxides （LDHs）, is not a common mineral, it is an important material that can be easily synthesized in laboratory. In this study, structural evolvement and BET surface area changes of heat treated Mg/AI-LDH is evaluated by XRD, TEM and N2-BET analyses. The results indicate that the magnesium-aluminum LDH with carbonate as interlayer anion, periclase-like oxides was formed at temperatures of 400-800℃. Meanwhile, 2-3 nanometer mesoporous were formed during decomposition of LDH. However, the heat treated samples still preserve the morphology of the original LDH plates. Periclase-like formed from LDH heat treatment may re-hydrolyze and recover the structure of LDH. However, crystallinity of the recovered LDH is lower than that of the original LDH. This heat treatment will result in formation of （Mg, Al）-oxide nano-crystals and nanopores among the nano-crystals. When heating temperature exceeds 1000, the periclase-like （Mg, Al）-oxide is transformed into a composite with periclase （MgO） and spinel phases. The periclase can be re-hydrolyzed and dissolved in HCl solution. After acid treatment, the sample with a high surface area is composed of spinel nano-crystals and nanopores among them. Our results will provide a new and economic way to synthesize mesoporous materials through pathways of phase transformation of precursor materials with different composition.     

中国大陆及邻近海域的Rayleigh波群速度分布

利用Rayleigh波群速度资料反演得到中国大陆及其临近海域的(70°E-145°E,10°N-55°N)15-120s周期的群速度分布图像. 塔里木盆地在15s处清楚地显示为低速,在16-33s左右没有显示,但在36-5s显示为高速,说明塔里木盆地有较深的根. 青藏高原块体是44s至120s图像中最为突出的低速块体,南面与印度板块的分界线以及与北面的塔里木盆地、柴达木盆地的分界清晰,其块体中西部的速度低于东部. 泰国清迈附近存在一尺度为1000km左右的低速带,可能是青藏高原块体的物质向东南方向迁移造成上地幔物质上涌的结果. 南北地震带表现为强烈的速度梯度带,西面为低速,东面为高速. 中国南海的中央、日本海中央、菲律宾海表现为海洋性地壳. 菲律宾海的图像与地形及地震带完全吻合. 环绕菲律宾海及日本海存在400km左右宽的低速带,可能是岩浆活动带.     

中国西南低空急流活动的统计分析

参照北美研究低空急流气候特征的方法，对中国低空急流进行重新定义，实现了低空急流定义的统一，并在此基础上对低空急流活动特征进行了分析。结果表明：中国低空急流主要有两个活动中心，分别位于江南地区和东北地区；江南地区的低空急流活动主要有两个活跃期，分别为1-4月和6-7月；东北地区的低空急流活动主要表现为2月、8-9月两个活动较弱期；江南地区的低空急流主要在6-8月表现出独立的急流轴，东北地区则主要在8月份；汛期低空急流活动与长江流域区域性暴雨有伴随性，多雨年急流次数很多，少雨年则很少；长江中下游及两湖盆地附近急流活动有明显的日变化。     

滇西北贡山地块始新世花岗岩的成因及其构造意义

滇西三江地区发育古近纪花岗岩,记录了印度－欧亚大陆碰撞的岩浆活动信息。对贡山地块福贡花岗岩开展岩石地球化学及锆石U Pb Hf系统研究,结果表明,该花岗岩为钙碱性、过铝质特征的I S型花岗岩。锆石U Pb同位素分析表明,福贡马吉花岗岩侵位于55 Ma,并含有252~77 Ma的继承锆石。锆石Hf同位素分析表明,该区岩浆锆石具有与青藏高原及东其南缘同时代长英质侵入体相似的Hf同位素组成,暗示其相似的岩浆起源。微量元素和同位素组成模拟计算结果表明,马吉花岗岩的原生岩浆是由53%的新生地壳组分和47%古老地壳基底物质混合而成的原岩经 5%~15%(F=005~015)的部分熔融而成。贡山地块福贡马吉花岗岩与冈底斯地块和腾冲地块早始新世岩浆岩(约55 Ma)具相似的年龄及地球化学特征,暗示它们之间可能存在类似的成因机制,均为新特提斯洋俯冲板片断离引起的壳内减压熔融的产物。     

H_2O_2增效TiO_2/凹凸棒石光催化体系降解亚甲基蓝

以钛酸四丁酯为前驱体,天然凹凸棒石为载体,采用溶胶凝胶法制备了TiO_2/凹凸棒石复合光催化剂,并用XRD、TEM对其进行表征.以亚甲基蓝染料为模拟污染物,采用300 W汞灯为紫外光源,以光催化实验来评价该催化剂的活性,并研究了H_2O_2的引入对光催化活性的影响.实验结果表明,H_2O_2能显著提高染料的脱色效率:亚甲基蓝的初始浓度为50 mg/L,催化体系为2 mmol/L H_2O_2+0.5 g/L TiO_2/凹凸棒石+UV(紫外线),光催化10 min后其脱色率为95%,相对于单独的0.5 g/L TiO_2/凹凸棒石+UV催化体系,其脱色率提高了约50%.全波段扫描显示,加入H_2O_2后,亚甲基蓝在290 nm对应的苯环吸收蜂急剧下降,665 nm对应的最大吸收峰则近乎消失,且没有新的吸收峰产生.