Integration of zircon and apatite U–Pb geochronology and geochemical mapping of the Wude basalts(Emeishan large igneous province):A tool for a better understanding of the tectonothermal and geodynamic evolution of the Emeishan LIP

Radiogenic isotopic dating and Lu–Hf isotopic composition using laser ablation-inductively coupled plasma-mass spectrometry(LA-ICP-MS)of the Wude basalt in Yunnan province from the Emeishan large igneous province(ELIP)yielded timing of formation and post-eruption tectonothermal event.Holistic lithogeochemistry and elements mapping of basaltic rocks were further reevaluated to provide insights into crustal contamination and formation of the ELIP.A zircon U–Pb age of 251.3±2.0 Ma of the Wude basalt recorded the youngest volcanic eruption event and was consistent with the age span of 251-263 Ma for the emplacement of the ELIP.Such zircons hadε_Hf(t)values ranging from7.3 to+2.2,identical to those of magmatic zircons from the intrusive rocks of the ELIP,suggesting that crust-mantle interaction occurred during magmatic emplacement,or crust-mantle mixing existed in the deep source region prior to deep melting.The apatite U–Pb age at 53.6±3.4 Ma recorded an early Eocene magmatic superimposition of a regional tectonothermal event,corresponding to the Indian–Eurasian plate collision.Negative Nb,Ta,Ti and P anomalies of the Emeishan basalt may reflect crustal contamination.The uneven Nb/La and Th/Ta values distribution throughout the ELIP supported a mantle plume model origin.Therefore,the ELIP was formed as a result of a mantle plume which was later superimposed by a regional tectonothermal event attributed to the Indian–Eurasian plate collision during early Eocene.     

Geological, geochemical characteristics and isotope systematics of the Longqiao iron deposit in the Lu-Zong volcano-sedimentary basin, Middle-Lower Yangtze (Changjiang) River Valley, Eastern China

The Middle-Lower Yangtze (Changjiang) River Valley metallogenic belt is located on the northern margin of the Yangtze Craton of eastern China. Most polymetallic deposits in the Changjiang metallogenic belt are clustered in seven districts where magmatism of Mesozoic age (Yanshanian tectono-thermal event) is particularly extensive. From west to east these districts are: E-dong, Jiu-Rui, Anqing-Guichi, Lu-Zong, Tong-Ling, Ning-Wu and Ning-Zhen. World-class iron ore deposits occur in the Lu-Zong and Ning-Wu ore clusters, which are mainly located in continental fault-bound volcanic-sedimentary basins. One of these deposits is the Longqiao iron deposit, discovered in the northern part of the Lu-Zong Basin in 1985. This deposit consists of a single stratabound and stratiform orebody, hosted in sedimentary carbonate rocks of the Triassic Dongma'anshan Formation. A syenite pluton (Longqiao intrusion) is situated below the deposit. The iron ore is massive and disseminated and the ore minerals are mainly magnetite and minor pyrite. Wall rock alteration mostly consists of skarn minerals, such as diopside, garnet, potassic feldspar, quartz, chlorite, phlogopite and anhydrite. Thin sedimentary siderite beds of Triassic age occur as relict laminated ore at the top and the margin of the magnetite orebody. These sideritic laminae are part of Triassic evaporite-bearing carbonate deposits (Dongma'anshan Formation).Sulfur isotopic compositions show that the sulfur in the deposit was derived from a mixture of magmatic hydrothermal fluids and carbonate–evaporite host rocks. Similarly, the C and O isotopic compositions of limestones from the Dongma'anshan Formation indicate that these rocks interacted with magmatic hydrothermal fluids. The O isotopic compositions of the syenitic rocks and minerals from the deposit show that the hydrothermal magnetite and skarn minerals were formed from magmatic fluids. The Pb isotopic compositions of sulfides are similar to those of the Longqiao syenite. Phlogopite coexisting with magnetite in the magnetite ores yielded a plateau age of 130.5 ± 1.1 Ma (2σ), whereas the LA-ICP MS age of the syenite intrusion is 131.1 ± 1.5 Ma, which is slightly older than the age of phlogopite.The Longqiao syenite intrusion may have crystallized from a parental alkaline magma, generated by partial melting of lithospheric mantle, during extensional tectonics. The ore fluids were probably first derived from magma at depth, later emplaced in the sedimentary rocks of the Dongma'anshan Formation, where it interacted with siderite and evaporite-bearing carbonate strata, resulting in the formation of magnetite and skarn minerals. The Longqiao iron deposit is a skarn-type stratabound and stratiform mineral system, genetically and temporally related to the Longqiao syenite intrusion. The Longqiao syenite is part of the widespread Mesozoic intracontinental magmatism (Yanshanian event) in eastern China, which has been linked to lithospheric delamination and asthenospheric upwelling.     

Epithermal deposits in North Xinjiang, NW China

The North Xinjiang region (NW China) is an important part of the Central Asia Orogenic Belt, situated at the junction of Siberia, Tarim and Kazakhstan plates. It is an area characterized by multiple stages of Phanerozoic continental growth, during which several porphyry and epithermal systems were formed. The relationship of these mineral systems to the geodynamic evolution of the region has not yet been well understood. In this paper, we list the main geological characteristics of 21 significant epithermal precious and base metal deposits in North Xinjiang, and classify them into high-sulfidation and low-sulfidation styles, with the latter being predominant. We have selected seven epithermal deposits representing different styles formed under different tectonic regimes and discuss their geology and geochemistry in some detail. The deposit-scale geology and geochemistry of epithermal systems in North Xinjiang are essentially similar to those in other parts of the world. All epithermal deposits in North Xinjiang are hosted in volcanic rocks with ages ranging from Devonian to Triassic, with the Early Carboniferous volcanic sequences being the most important, followed by the Permian and Triassic. The Devonian–Early Carboniferous host rocks belong to the calc-alkaline series that developed in pre-collisional arc-back-arc basin systems; whereas the Permian–Triassic host volcanic rocks of shoshonite series formed in post-subduction regimes. Available isotopic ages of these epithermal systems cluster in two periods: Early Carboniferous (>320?Ma) and Late Carboniferous–Triassic (320–220?Ma), reflecting two metallogenic episodes that occurred during subduction-related accretion and post-subduction collision regimes, respectively. Accordingly, three groups of epithermal deposits in North Xinjiang can be recognized as (1) pre-collisional deposits without or with negligible collisional-related modification, (2) deposits formed in collision regime and (3) ore systems strongly overprinted by fluid flow in post-subduction collision regime.     

Isotope geochemistry of the Tieluping silver-lead deposit, Henan, China: A case study of orogenic silver-dominated deposits and related tectonic setting

The Tieluping silver deposit, which is sited along NE-trending faults within the high-grade metamorphic basement of the Xionger Terrane in the Qinling orogenic belt, is part of an important, recently discovered Mesozoic orogenic-type Ag-Pb belt. Ore formation includes three stages: an early barren quartz-pyrite stage (E), an intermediate polymetallic sulfide ore stage (M), and a late barren carbonate stage (L). Carbon, sulfur and lead isotope systematics indicate that the E-stage fluids are deeply sourced; the L-stage fluids are shallow-sourced meteoric water; whereas the M-stage fluids are a mix of deep-sourced and shallow-sourced fluids. Sulfur and lead isotope data show that the ore-forming fluids must have originated from a source with elevated radiogenic lead and low ³⁴S values, that differs significantly from exposed geologic units in the Xionger Terrane, the lower crust and the mantle. This supports the view that the carbonate-shale-chert sequences of the Guandaokou and Luanchuan Groups south of the Machaoying fault might be the favorable sources, although little is known about their isotopic compositions. A tectonic model that combines collisional orogeny, metallogeny and hydrothermal fluid flow is proposed to explain the formation of the Tieluping silver deposit. During the Mesozoic collision between the North China Craton and South China Block (Early-Mid Triassic Indosinian Orogeny), crustal slabs containing the carbonate-shale-chert sequences of the Guandaokou and Luanchuan Groups, locally rich in organic matter (carbonaceous shale), were thrust northwards beneath the Xionger Terrane along the Machaoying fault. Metamorphic devolatilisation of this underthrust slab probably provided the ore-forming fluids to develop the Ag-Pb ore belt, which includes the Tieluping silver deposit. Fluids and magmas were emplaced during extensional stages related to the Jurassic-Cretaceous Yanshanian Orogeny.Editorial Handling: B. Lehmann     

Chemostratigraphy of Flood Basalts in the Garze-Litang Region and Zongza Block: Implications for Western Extension of the Emeishan Large Igneous Province, SW China

The Late Permian Emeishan Large Igneous Province (ELIP) is commonly regarded as being located in the western part of the Yangtze craton, SW China, with an asymmetrical shape and a small area. This area, however, is just a maximum estimation because some parts of the ELIP were not recognized or dismembered and destroyed during the Triassic to Cenozoic tectonism. In this paper, the chemostratigraphical data of the Zongza block, the Garze-Litang belt and the Songpan-Garze block suggest that the Late Permian basalts in these areas have remarkable similarities to the ELIP basalts in petrography and geochemistry. Flood basalts in the Sanjiangkou area are composed of the lower part of the low-Ti (LT) tholeiite and the upper part of the high-Ti (HT) tholeiite, which is the same as the flood basalts on the western margin of the Yangtze craton. Flood basalts in the Zongza and Songpan-Garze areas, which are far from the Yangtze craton, consist of HT tholeiite only. This is the same as the flood basalts within the Y     

Copper–gold occurrences in the Palaeoproterozoic Inglefield mobile belt, northwest Greenland: a new mineralisation style?

Inglefield Land in northwest Greenland is an ice-free 7000 km² region underlain by the Palaeoproterozoic Inglefield mobile belt, composed of quartzo-feldspathic gneisses, meta-igneous and supracrustal rocks. These rocks are unconformably overlain by an unmetamorphosed cover of sedimentary and igneous rocks of the Mesoproterozoic Thule Basin and the Lower Palaeozoic Franklinian Basin. Mineralisation in Inglefield Land is characterised by a copper–gold metal association that can be classified in terms of the hosting rocks, namely: garnet–sillimanite paragneiss-hosted, orthogneiss-hosted and mafic–ultramafic-hosted. The paragneiss-hosted mineralisation, the topic of this paper, is essentially confined within a NE-trending structural corridor and consists of bands of sulphide±graphite-bearing, hydrothermally altered, quartzo-feldspathic gneiss, called “rust zones”. These are commonly parallel to the paragneiss main foliation, suggesting a close relationship. The rust zones have strike lengths from a few metres to more than 5 km, and widths ranging from a few centimetres to 200 m. Sulphides mainly include pyrrhotite, pyrite and chalcopyrite. The sulphides form disseminations, up to 30% by volume, but in places they form massive pods or lenses up to 20–30 m, and about 0.1–0.5 m wide. Graphite contents are up to 5 vol.%. Rust zones typically consist of a quartz–plagioclase mosaic associated with a late generation of red-brown biotite, sericite, chlorite and epidote. Mylonitic or cataclastic textures are locally recognisable. XRD analyses of graphite indicate temperatures of between 650 and 700 °C. Sulphur isotope analyses show δ³⁴S values ranging from −6.2‰ to +9.3‰.An ore genesis model is proposed in which the Palaeoproterozoic precursor sandstone–carbonaceous shale succession is polydeformed and polymetamorphosed to granulite facies quartzo-feldspathic and pelitic gneisses, with transposition of layering to axial plane of folds, followed by ductile shearing and mylonitisation, from which future rust zones were derived. The mylonitic zones were infiltrated by fluids, whose origin can be ascribed to deep-penetrating surface waters and/or external brines. In our ore genesis model, we envisage that brines derived from the overlying Lower Palaeozoic Franklinian succession infiltrated the basement into the structural channels provided by the shear/mylonitic zones. At the regional scale, this infiltration was facilitated by a NE-trending corridor, postulated to be a deep structure.     

Qiyugou auriferous breccia pipes:A low-sulphidation epithermal system linked with transition of tectonic regime from collisional compression to extension,Xiong'ershan,Henan,China

The Xiong’ershan area,as a part of a metallogenic province in cetral China,contains substantial Leimengou porphyry molybdenite deposit,Qiyugou breccia gold deposits and vein gold deposit occurred in fault zone,as well as previously refer to as orogenic gold deposit.Around or nearby the Mesozoic porphyry granite,the typical porphyry deposit,much more breccia pipes and breccia gold deposit are developed in the area.In this paper we focus on reporting preliminary results obtained from field,petrographic work on the Leimengou porphyry molybdenite and the Qiyugou breccia gold deposit,as well as laser Raman microspectroscopy and microprobe analyses carried out on samples from the Au-bearing Qiyugou breccia pipes.An adularia-calcite assemblage is reported in these breccia gold deposits.Two stages of hydrothermal alteration,pervasive and vein,are identified.The first stage consists of the alteration of the breccia clasts and rock flour by actinolite,green biotite,epidote,chlorite and minor sericite.This hydrothermal activity is likely to relate to the molybdenite mineralisation episode.The second stage is characterised by quartz veining and adularia and calcite filling open-spaces.Vein ores associated with quartz,sericite,and minor calcite alteration occur in NE-trending fault that cut the first stage of alteration.The adularia-calcite alteration is genetically associated with gold mineralization.The adularia-calcite assemblage in the area suggest that the Qiyugou pipes are of low-sulphidation epithermal in nature.The Qiyugou breccia pipes are coeval and spatially associated with the nearby Leimengou porphyry Mo deposit,which together conform to an alkalic mineralising system.We propose a model for the development and evolution of the breccia pipes in conjunction with a model that describes the genesis of the porphyry Mo and auriferous breccia pipes as a unified magmatic-hydrothermal system,which is linked with transition from collisional compressional to extensional geodynamic regime.