Comparison of the behaviour of rare earth elements in surface waters,overburden groundwaters and bedrock groundwaters in two granitoidic settings,Eastern Sweden

This work, which was done within the Swedish nuclear waste management program, was carried out in order to increase the understanding of the mobility and fate of rare earth elements (REEs) in natural boreal waters in granitoidic terrain. Two areas were studied, Forsmark and Simpevarp, one of which will be selected as a site for spent nuclear fuel. The highest REE concentrations were found in the overburden groundwaters, in Simpevarp in particular (median ∑REE 52 μg/L), but also in Forsmark (median ∑REE 6.7 μg/L). The fractionation patterns in these waters were characterised by light REE (LREE) enrichment and negative Ce and Eu anomalies. In contrast, the surface waters had relatively low REE concentrations. They were characterised either by an increase in relative concentrations throughout the lanthanide series (Forsmark which has a carbonate-rich till) or flat patterns (Simpevarp with carbonate-poor till), and had negative Ce and Eu anomalies. In the bedrock groundwaters, the concentrations and fractionation patterns of REEs were entirely different from those in the overburden groundwaters. The median La concentrations were low (just above 0.1 μg/L in both areas), only in a few samples were the concentrations of several REEs (and in a couple of rare cases all REEs) above the detection limit, and there was an increase in the relative concentrations throughout the lanthanide series. In contrast to these large spatial variations, the temporal trends were characterised by small (or non existent) variations in REE-fractionation patterns but rather large variations in concentrations. The Visual MINTEQ speciation calculations predicted that all REEs in all waters were closely associated with dissolved organic matter, and not with carbonate. In the hydrochemical data for the overburden groundwater in particular, there was however a strong indication of association with inorganic colloids, which were not included in the speciation model. Overall the results showed that within a typical boreal granitoidic setting, overburden groundwaters are enriched in REEs, organic complexes are much more important than carbonate complexes, there is little evidence of significant mixing of REEs between different water types (surface, overburden, bedrock) and spatial variations are more extensive than temporal ones.     

Millennial-scale climate changes on South Georgia, Southern Ocean

The location of South Georgia (54°S, 36°W) makes it a suitable site for the study of the climatic connections between temperate and polar environments in the Southern Hemisphere. Because the mass balance of the small cirque glaciers on South Georgia primarily responds to changes in summer temperature they can provide records of changes in the South Atlantic Ocean and atmospheric circulation. We use grey scale density, weight-loss-on-ignition, and grain size analyses to show that the proportion of glacially eroded sediments to organic sediments in Block Lake was highly variable during the last 7400 cal yr B.P. We expect that the glacial signal is clearly detectable above noise originating from nonglacial processes and assume that an increase in glacigenic sediment deposition in Block Lake has followed Holocene glacier advances. We interpret proglacial lake sediment sequences in terms of summer climate warming and cooling events. Prominent millennial-scale features include cooling events between 7200 and 7000, 5200 and 4400, and 2400 and 1600 cal yr B.P. and after 1000 cal yr B.P. Comparison with other terrestrial and marine records reveals that the South Georgian record captures all the important changes in Southern Hemisphere Holocene climate. Our results reveal a tentative coupling between climate changes in the South Atlantic and North Atlantic because the documented temperature changes on South Georgia are anti-phased to those in the North Atlantic.