Phosphorus fractionation in surface sediments of the Amazon continental shelf

The aim of this study is to separate various fractions of phosphorus in surface sediments of the Amazon continental shelf and compare them with other areas of the Brazilian shelf. Surface sediments were collected from the river-mouth transect (RMT) and open-self transect (OST). The extraction techniques available in the literature have been used to separate the following forms: Fe-PO₄, Al-PO₄, Ca-PO₄, and associated organic matter. The results indicate that the concentrations of phosphorus are uniform in the study area and may be compared with many other nonpolluted environments. Among the inorganic forms, Ca-PO₄ is dominant in all the samples, and Fe-PO₄ is present in lower concentrations. Al-PO₄ is more significant on the Amazon continental shelf than other parts of the Brazilian coast and other coastal environments of the world.     

Preliminary investigations on the occurrence of diagenetic dolomite in surface sediments of Lagoa Vermelha,Brazil

Studies on the precipitation of carbonates in a hypersaline lagoon revealed the presence of diagenetic dolomite at very shallow sediment depths. The relation of magnesium to calcium concentration both in interstitial and surface waters are within the range predicted in the literature for this occurence. Lower values encountered in some samples were linked to interactions with fresh groundwater.     

Pyritization of trace metals in mangrove sediments

The present study investigates the levels of Mn, Zn, Ni, and Co pyritization in mangrove sediments along distinct sedimentary zones in Enseada das Gra?as, a lagoon-type estuary located on the southeastern coast of Brazil. The coastal geology is characterized by intense interactions of trace metals, forming pyrite minerals. Specific orders of DOP (degree of pyritization) and DTMP (degree of trace-metal pyritization) are shown: supratidal flat?<?mangrove forest?<?mud flat. Distinct changes in content along the sediment profiles are noted, where a supratidal flat presented low levels of DOP and DTMP with little variance along the sedimentary depths. The mangrove forest showed relatively high values of DOP and DTMP in the lower depths, while the mud flat showed the highest levels of DOP and DTMP.     

Sediment accumulation rates along the inner eastern Brazilian continental shelf

Box cores were collected close to river mouths along the eastern Brazilian shelf at water depths of 10–30 m. One core was taken from more than 1000 m depth at the shelf slope. ²¹⁰Pb and ²²⁶Ra activities were measured to establish sediment accumulation rates. Seven of the 10 cores exhibited an exponential decrease with depth of excess ²¹⁰Pb activities. The sediments from the sheltered Sudeste Channel off Caravelas revealed the highest sediment accumulation rate of 0.81 cm yr⁻¹. The sediments at the shelf slope seaward of the Rio Doce revealed the lowest accumulation rate of 0.13 cm yr⁻¹. Sediment accumulation rates increased towards the Caravelas Bank. Current patterns and the morphology of the seabed favor sediment deposition in this area.     

Mercury flux to estuarine sediments, derived from Pb-210 and Cs-137 geochronologies (Guaratuba Bay, Brazil)

A sediment core from Guaratuba Bay was used to indicate possible Hg modifications to this coastal environment brought about by growing agricultural activity. Sedimentation rates were estimated to be 6.1 mm/year and 5.2 mm/year through 210Pb and 137Cs geochronologies, respectively. Mercury concentrations and organic matter ratios in the surface layers are greater than in the older sediments, supporting the hypothesis of anthropogenic enrichment. Results show that the Hg flux has raised more than twofold during the second half of the 20th century. These results point to the need for further studies to substantiate the hypothesis of anthropogenic enrichment and to quantify point sources of Hg to this estuary.     

Contrasting mercury and manganese deposition in a mangrove-dominated estuary (Guaratuba Bay, Brazil)

Sediment cores were taken at seven sites along the mangrove-bound Guaratuba Bay estuary (southern Brazil), with the purpose of assessing conditions controlling Hg deposition along a horizontal estuarine sediment gradient. The data suggest contrasting depositional patterns for Hg and Mn in this relatively pristine setting. Total Hg contents of bulk sediments ranged from 12 to 36 ng/g along the estuary, the highest values being found in muddier organic-rich sediments of the upper estuary (the corresponding mud gradient is 12 to 42 wt.%, and the organic matter gradient 4 to 10 wt.%). Thus, the deposition of fine sediments relatively enriched in mercury occurs primarily in closer proximity to the freshwater source. The data also indicate a reverse gradient in reactive Mn contents, ranging from 29 to 81 μg/g, and increasing seaward. This implies that reactive Mn is mobilized from fine-grained reducing mangrove forest sediments in the upper estuary, and deposited downstream in sandier, oxygen-rich nearshore sediments. These results suggest that mangrove-surrounded estuaries may act as barriers to mercury transport to coastal waters, but as a source of manganese. The present findings also imply that reactive Mn may be used as an indication of Hg depositional patterns in other similar coastal sedimentary settings.     

Mangrove forest sedimentation and its reference to sea level rise,Cananeia, Brazil

The stability of a mangrove ecosystem in Cananeia, Brazil, is assessed based on investigations of the site-specific temporal rise in relative sea level during the past 50 years, 100-year sediment accumulation rates (SAR) and sources of organic matter (OM). Addressing this, three sediment cores were collected in a transect, intertidal mud flat, mangrove margin and well into the forest. The net SAR, as estimated by the age–depth relationships of ²¹⁰Pb and ¹³⁷Cs, is between 2.5 and 3.9 mm year⁻¹. These rates are comparable to the estimates based on the Pb and Zn contaminant markers corresponding to mining initiation in the region in 1918. Further, the SARs are lower than the rate of regional relative sea level rise (4 mm year⁻¹) as indicated by the past 50-year tide gauge record, but the rate is higher than the eustatic sea level rise (1.7 ± 0.3 mm year⁻¹). The stratigraphies of TOC/TN, δ¹³C_(OC), OP and δ¹⁵N indicate site-specific mangal vegetal litter, which is the predominant source of OM at all core sites, during the past century and reflects a stable mangal system over that time span.     

Polycyclic aromatic hydrocarbons in recent sediments from a subtropical estuary in Brazil

The scope of this work was to evaluate the levels of polycyclic aromatic hydrocarbons (PAHs) and their possible sources in two shallow sediment cores from an estuarine area located in the south region of Brazil, the Guaratuba Bay. The estuary is encompassed by an Environmental Protection Area (EPA) of 1306 km², which is still considered to be pristine, despite recent urban growth. To assess levels of 14 selected PAHs in the sediments, among those listed as “priority pollutants” by the US Environmental Protection Agency, the cores were divided in several sections, followed by extraction, clean-up, fractionation and subsequent analysis using HPLC coupled to a fluorescence detector. Among the PAHs detected, phenanthrene and fluoranthene showed the highest concentrations. PAHs with more than four rings were usually present in low concentrations or were undetectable. To assist in the identification of possible sources, the ratios An/(An + Phe) and Flt/(Flt + Py) (anthracene to anthracene plus phenanthrene and fluoranthene to fluoranthene plus pyrene) and a PCA model were also used. Total concentrations of PAHs ranged between 1.5 and 3130 ng/g (mean 495) dry weight for the core collected in the inner part of the estuary, and between 78.5 and 3270 ng/g (mean 899) dry weight for the other core, collected in the outer part. Compared to values found in other studies in coastal zones along South American eastern margin, this area can be considered to range from low polluted to moderately polluted. From the data, it was also possible to conclude that there is predominance of petroleum sources, and essentially close to the more urbanised areas. Combustion sources have only minor contribution and are episodic, when compared to the latter.     

Preferential settling of smectite on the Amazon continental shelf

Seventy-five surface and subsurface sediment samples collected on the Amazon continental shelf were analyzed by X-ray diffraction (XRD) in the grain-size fractions smaller than 2 μm. The groups of clay minerals thus identified were smectite, kaolinite, illite, and mixed-layer illite/smectite. Calculation of relative abundance shows a predominance of smectite (37%) in the whole area, followed by kaolinite (27%), illite (23%), and a small percentage of mixed-layer illite/smectite (12%). The distal, northwest region of the continental shelf is characterized by a high abundance of smectite (41%), high salinity values, and high sediment accumulation rates (10 cm year⁻¹), whereas the proximal region is characterized by a comparatively low abundance of smectite (30%), low salinity values, and low sediment accumulation rates (<1 cm year⁻¹). This trend of increasing abundance northwestwards documents a preferential settling of smectite in the distal and more saline regions of this estuarine system. Received: 17 September 1999 / Revision accepted: 17 January 2000