Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

Isolation of resonance in acoustic backscatter from elastic targetsusing adaptive estimation schemes

It has been shown that at certain frequencies the acoustic backscatter from elastic targets exhibits certain resonance behavior which closely relates to the physical properties of the target such as dimension, thickness, and composition. The purpose of this paper is to develop an automated approach for identifying the presence of resonance in the acoustic backscatter from an unknown underwater target by isolating the resonance part from the specular contribution. An adaptive transversal filter structure is used to estimate the specular part of the backscatter and consequently the error signal would provide an estimate of the resonance part. An important aspect of this scheme lies in the fact that it does not require an underlying model for the elastic return. The adaptation rule is based upon fast recursive least squares (RLS) learning. The approach taken in this paper is general in the sense that it can be applied to targets of unknown geometry and thickness and, further, does not require any a priori information about the target and/or the environment. Test results on acoustic data are presented which indicate the effectiveness of the proposed approach     

Asteroid families: evidence of ageing of the proper elements

In recent times it has been emphasized that the present kinematical structures of asteroid families should be evolved with respect to the original post-impact situations, according to numerical simulations performed taking into account also the previously neglected Yarkovsky effect. In this paper we show that also a “classical” approach based on an analysis of the current kinematical properties of families leads to conclude that the distributions of proper eccentricities and semimajor axes of family members exhibit evidence of an evolution. The importance of this approach is that it yields a fully independent and quantitative estimate of an evolutionary spreading of the proper elements. In particular, we find that the original post-impact families had to be on the average about twice more compact than the families we observe now, when considering family members down to about 5 km in size. This result can be used in future analyses to derive estimates of the ages of different families, and to better constrain the typical values of the ejection velocities of the fragments in family-forming events.     

Kinematics of stars in Kovalsky-Kapteyn figures. II

Rostov State Pedagogical Institute; All-Union Scientific Research Institute Gradient. Translated from Astrofizika, Vol. 33, No. 3, pp. 379–393, November–December, 1990.