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ABSTRACTThe October 2011 sinking of the container ship MV Rena on Astrolabe Reef, New Zealand, provided a rare opportunity to examine the fate of shipwreck-derived contaminants on an offshore rocky reef and food chain. Analyses of trace metals, polycyclic aromatic hydrocarbons (PAHs) and organotins indicated significant but localised contamination of Astrolabe Reef but not of nearby Mōtītī Island. Three years after the grounding, PAH concentrations were greater in sediments at Astrolabe (up to 131?mg kg?1) than at control locations, while organotins from the ship's antifouling hull paint were found exclusively in Astrolabe Reef sediments and biota. Over 80% of Astrolabe sediment samples contained tributyltin at concentrations above guideline sediment levels (>0.07?mg kg?1). Tributyltin and its decomposition products were also recorded in sea urchins, gastropods, lobster and fishes at concentrations up to 0.2?mg kg?1. Wreck and cargo-derived metals, particularly copper, tin and zinc, were present in some Astrolabe sediment samples above Australia and New Zealand Environment and Conservation Council guideline concentrations. However, there appeared to be only limited transmission of metals through the food chain. Copper, tin and zinc were recorded at greater concentrations in Astrolabe sea urchins and gastropods compared to control specimens, while metal concentrations in other biota were comparable across impact and control sites. Despite over 3 years having passed since the Rena grounding, the data series does not show any upward or downward trends in contaminant concentrations on Astrolabe Reef. Consequently, there is uncertainty about the long-term implications of the Rena grounding for the ecology of Astrolabe Reef. 相似文献
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PM Ross RM Fairweather DP Culliford S Park CA Pilditch CN Battershill 《新西兰海洋与淡水研究杂志》2016,50(1):56-69
ABSTRACTTo investigate the uptake and depuration of polycyclic aromatic hydrocarbons associated with the Rena oil spill we sampled the surf clam Paphies subtriangulata at two open coast locations (6?km apart) just prior to oil coming ashore (7 October 2011), then at 1–3 week intervals for the next 4 months. Total polycyclic aromatic hydrocarbons (tPAH) increased at both sites from 1 to 96–124?µg?kg?1 (wet weight) by 18 October before declining to low levels (<4?µg?kg?1) by February 2012. Ongoing sampling throughout 2012–2014 included three additional sites to the north east (up to 30?km away) and a site 5?km to the south east revealing tPAH levels generally <10?µg?kg?1 except in October 2013 where levels ranged between 39–45?µg?kg?1 at all sites. A comparison of PAH component profiles with oil-contaminated beach sediment indicated that the high levels observed in surf clams between October–December 2011 were clearly associated with the Rena spill. However, the October 2013 peak had a PAH profile inconsistent with weathered Rena oil, suggesting an alternative source of contamination. Our results highlight the potential for P. subtriangulata as a PAH monitoring tool but recognise more study is needed to better quantify baseline levels and uptake and depuration dynamics. 相似文献
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Magnetoacoustic gravity (MAG) waves have been studied for some time. In this article, we investigate the effect that a shear flow at a tangential discontinuity embedded in a gravitationally stratified and magnetised plasma has on MAG surface waves. The dispersion relation found is algebraically analogous to the relation of the non-flow cases obtained by Miles and Roberts (Solar Phys. 141, 205, 1992), except for the introduction of a Doppler-shifted frequency for the eigenvalue. This feature, however, introduces rather interesting physics, including the asymmetric presence of forward- and backward-propagating surface waves. We find that increasing the equilibrium flow speed leads to a shift in the permitted regions of propagation for surface waves. For most wave number combinations this leads to the fast mode being completely removed, as well as more limited phase speed regimes for slow-mode propagation. We also find that upon increasing the flow, the phase speeds of the backward propagating waves are increased. Eventually, at high enough flow speeds, the wave’s direction of propagation is reversed and is in the positive direction. However, the phase speed of the forward-propagating wave remains mainly the same. For strong enough flows we find that the Kelvin–Helmholtz instability can also occur when the forward- and backward-propagating modes couple. 相似文献
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Volcanic lightning, perhaps the most spectacular consequence of the electrification of volcanic plumes, has been implicated in the origin of life on Earth, and may also exist in other planetary atmospheres. Recent years have seen volcanic lightning detection used as part of a portfolio of developing techniques to monitor volcanic eruptions. Remote sensing measurement techniques have been used to monitor volcanic lightning, but surface observations of the atmospheric electric Potential Gradient (PG) and the charge carried on volcanic ash also show that many volcanic plumes, whilst not sufficiently electrified to produce lightning, have detectable electrification exceeding that of their surrounding environment. Electrification has only been observed associated with ash-rich explosive plumes, but there is little evidence that the composition of the ash is critical to its occurrence. Different conceptual theories for charge generation and separation in volcanic plumes have been developed to explain the disparate observations obtained, but the ash fragmentation mechanism appears to be a key parameter. It is unclear which mechanisms or combinations of electrification mechanisms dominate in different circumstances. Electrostatic forces play an important role in modulating the dry fall-out of ash from a volcanic plume. Beyond the local electrification of plumes, the higher stratospheric particle concentrations following a large explosive eruption may affect the global atmospheric electrical circuit. It is possible that this might present another, if minor, way by which large volcanic eruptions affect global climate. The direct hazard of volcanic lightning to communities is generally low compared to other aspects of volcanic activity. 相似文献
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Despite uncertainties in our understanding of early Earth volcanism and atmospheric composition, thermodynamic modelling is able to offer estimates of the global production of reactive trace species (NO, OH, SO3, Cl, Br and I) from early Earth volcanism, and thereby to shed light on processes which may have been different in Earth’s early atmosphere. Model results show that thermal decomposition of magmatic H2O, CO2 and SO2 in high-T mixtures of magmatic and atmospheric gases (at T > 1400 °C) generate high levels of reactive trace gas species. Production of these reactive trace species is insensitive to atmospheric CO2 in mixtures where the atmospheric gas is the minor component and will hence continue during periods of low atmospheric CO2. Fluxes of NO, OH, Cl, Br and I from early Earth volcanism are predicted to exceed those from modern Earth volcanism as the higher temperature of early Earth emissions compensates for lower levels of O2 in the atmosphere, compared to the modern Earth. Under certain conditions, the volcanic NO flux from early Earth volcanism is found to be comparable to other sources of reactive N such as lightning NO and photochemical HCN. This is one possible source of fixed nitrogen which may alleviate any postulated Archean nitrogen crisis. Our thermodynamic model reveals that production of SO3 (a potential precursor for near-source volcanic sulphate and hence ‘primary’ volcanic aerosol) is likely to be significantly lower from early Earth volcanism. Uncertainty in the pathway to near-source sulphate in modern volcanism (i.e., the reaction of SO3 with water or direct emission) introduces a large uncertainty into the production rate of near-source volcanic sulphate on the early Earth. 相似文献
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Austin H. Becker Michele Acciaro Regina Asariotis Edgard Cabrera Laurent Cretegny Philippe Crist Miguel Esteban Andrew Mather Steve Messner Susumu Naruse Adolf K. Y. Ng Stefan Rahmstorf Michael Savonis Dong-Wook Song Vladimir Stenek Adonis F. Velegrakis 《Climatic change》2013,120(4):683-695
With 80 % of world trade carried by sea, seaports provide crucial linkages in global supply-chains and are essential for the ability of all countries to access global markets. Seaports are likely to be affected directly and indirectly by climatic changes, with broader implications for international trade and development. Due to their coastal location, seaports are particularly vulnerable to extreme weather events associated with increasing sea levels and tropical storm activity, as illustrated by hurricane “Sandy”. In view of their strategic role as part of the globalized trading system, adapting ports in different parts of the world to the impacts of climate change is of considerable importance. Reflecting the views of a diverse group of stakeholders with expertise in climate science, engineering, economics, policy, and port management, this essay highlights the climate change challenge for ports and suggests a way forward through the adoption of some initial measures. These include both “soft” and “hard” adaptations that may be spearheaded by individual port entities, but will require collaboration and support from a broad range of public and private sector stakeholders and from society at large. In particular, the essay highlights a need to shift to more holistic planning, investment and operation. 相似文献
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Quaternary catchments in the south of the Sorbas Basin, SE Spain have been affected by two regionally significant river captures. The river captures were triggered by changes in regional gradients associated with sustained Quaternary uplift in the region of 160 m Ma−1. The first capture occurred in the early Pleistocene and re-routed 15% of the original Sorbas Basin drainage into the Carboneras Basin to the south. The second occurred in the late Pleistocene and re-routed 73% of the original Sorbas Basin drainage to the east. This latter capture had dramatic consequences for base-level in the Sorbas Basin master drainage. Local base-level was lowered by 90 m at the capture site, 50 m at 7 km upstream and 25 m at 13 km upstream of the site. The base-level change instigated a complex re-organisation of the drainage networks in systems tributary to the master drainage over the ensuing period (some 100 ka). After the capture, drainage systems closer to the capture site experienced a tenfold increase in incision rates over most of their network. Those located some 13 km upstream of the capture site experienced a fivefold increase in incision, although in this instance, the changes do not appear to have propagated to the headwater regions of the drainage nets. The sensitivity of individual catchments was largely governed by geological controls (structure and lithology). The detailed network evolution in the most sensitive areas can be traced by reconstructing former drainage pathways using abandoned drainage cols and the alignment and degree of incision of the drainage networks. Three main stages of evolution can be identified which record the progressive spread of base-level changes from the master drainage. These are Stage 1 (pre-capture): original south-to-north consequent drainage; Stage 2 (early stage, post capture): aggressive subsequent southwest-to-northeast and east–west drainage developed along structural lineaments first in the east of the area (Stage 2a), and later in the west of the area (Stage 2b); and Stage 3 (late stage, post capture): obsequent drainage developing on the topography of the Stage 2 drainage. All stages of the network evolution are associated with drainage re-routing as a function of river capture at a variety of scales. The results highlight the complex response of the fluvial system, and the very different geomorphological histories of adjacent catchments, emphasising the need for regional approaches for examining long-term changes in fluvial systems. 相似文献