Newtontoppen granitoid rocks, their geology, chemistry and Rb-Sr age

A post-tectonic Caledonian granite in southern Ny Friesland has been fully mapped and the following new names are proposed: the Chydeniusbreen granitoid suite, consisting of the Raudberget granitoid body in the north; the Newtontoppen granitoid body in the middle; and the Ekkoknausane granitoid body in the south
The contact relationships, internal structures and distribution of various rock types infer an asymmetric lopolith or a harpolith-like body, a large sickle-shaped intrusion stretched in the direction of general tectonic transport, for the Newtontoppen granitoid body.
Seven rock types are described in the Newtontoppen granitoid and four emplacement stages are recognised. The major rock types seem to have an alkali-calcic to alkalic bulk rock chemistry and show a transition between I- and S-type granite derived from anatectic melting of various protoliths under relatively high temperature conditions. Possible later K₂0 introduction modified the earlier formed rock types.
A Rb-Sr whole rock age of 432 ± 10 Ma has been obtained by a seven point isochron with MSDW = 2.59 and an initial Sr isotope ratio = 0.715. This age is approximately 30 Ma older than the previously obtained K-Ar whole rock and Rb-Sr biotite ages, ca. 400 Ma, which represents the period of cooling. The high initial Sr isotope ratio supports the interpretation of an anatectic origin.     

Rb-Sr whole rock and U-Pb zircon datings of the granitic-gabbroic rocks from the Skålfjellet Subgroup, southwest Spitsbergen

Recent remapping and new age determinations has shed light on the understanding of Precambrian rocks northwest of Hornsund, southwest Spitsbergen. The Skålfjellet Subgroup has been regarded as the eastern equivalent of the Vimsodden Subgroup, and both of these occur within the Precambrian Eimfjellet Group of southwest Spitsbergen. Although the Eimfjellet Group is considered to be older than the oldest unconformity in the area, the age of the rocks has not been known. The granitic-gabbroic rocks in the Skålfjellet Subgroup have been considered to be the products of granitisation for many years, but recent observations show that they are exotic blocks incorporated into the basic eruptive rocks which are the main constituents of the subgroup. These plutonic rocks have a wide range of compositions, from syenite via granite to gabbroic cumulates, which suggests the existence of a well-differentiated plutonic body at depth.
U-Pb zircon and Pb evaporation datings yielded magmatic ages of ca. 1,100 to 1,200 Ma, and a conformable age has been obtained by Rb-Sr whole rock dating. Detrital zircons from the micaceous schists of the Isbjørnhamna Group, which underlies the Skålfjellet Subgroup, show a poorly defined discordia with an upper intercept age of ca. 2,200 Ma and a lower intercept age of ca. 360 Ma. These dating results define the magmatic age of the granitic-gabbroic rocks as late Mesoproterozoic, early Grenvillian. This age is in broad agreement with that of the metavolcanic rock clasts of the Pyttholmen meta-pyroclastic-conglomeratic unit at Vimsodden, which is considered to be the westernmost occurrence of the Skålfjellet Subgroup.
A Rb-Sr whole rock age determination of the shaly phyllites from the Deilegga Group was performed in order to place constraints on the age of younger Precambrian event; however, no good isochron was obtained.     

PROJECTIONS OF CLIMATE CHANGE FOR THE CZECH REPUBLIC

The paper deals with a selection of the climatological baseline, GCM validity and construction of the climate change scenarios for an impact assessment in the Czech territory. The period of 1961–1990 has been selected as the climatological baseline. The corresponding database includes more than 50 monthly mean temperature and precipitation series, and 16 time series of daily meteorological data that contain also the solar radiation data. The 1× CO₂ outputs produced by four GCMs, provided by the CSMT (GISS, GFD30, GFD01, and CCCM), were compared with observed temperature and precipitation conditions in western and central Europe with a particular attention devoted to the Czech territory. The GCM ability to simulate annual cycles of temperature, precipitation and radiation was thoroughly examined. The GISS and CCCM were selected as a basis for constructing climate change scenarios as they simulated reasonably the observed patterns. According to the GISS variant, 2× CO₂ climate assumes a higher winter and lower summer warming, and an increase in annual precipitation amounts. A dangerous combination of the summer temperature increase and declining precipitation amounts is a specific feature of the CCCM scenario. An incremental scenario for temperature and precipitation is based on the combination of prescribed changes in both annual means and annual courses.     

Ruby–sapphire–spinel mineralization in marble of the middle and southern Urals: Geology,mineralogy, and genesis

Ruby and spinel occurrences hosted in marble on the eastern slope of the Urals are considered. Ruby- and spinel-bearing marble is a specific rock in granite-gneiss complexes of the East Ural Megazone, which formed at the Late Paleozoic collision stage of the evolution of the Urals. Organogenic marine limestone is the protolith of the marble. No relict sedimentary bedding has been retained in the marble. The observed banding is a secondary phenomenon related to crystallization and is controlled by flow cleavage. Magnesian metasomatism of limestone with the formation of fine-grained dolomite enriched in Cr, V, Ti, Mn, Cu, Zn, Ga, and REE took place at the prograde stage of metamorphism. Dedolomitization of rocks with the formation of background calcite marble also developed at the prograde stage. Mg-calcite marble with spinel and ruby of the first type formed in the metamorphic fluid circulation zone. Magnesian metasomatism with the formation of bicarbonate marble with ruby, pink sapphire, and spinel of the second type developed at the early retrograde stage. The formation of mica-bearing mineralized zones with corundum and spinel of the third type controlled by cleavage fractures is related to the pneumatolytic–hydrothermal stage. The data on ruby-bearing marble in the Urals may be used for forecasting and prospecting of ruby and sapphire deposits hosted in marble worldwide.     

Fluid regime and origin of gold-bearing rodingites from the Karabash alpine-type ultrabasic massif,Southern Ural

The rodingites of the Karabash Massif are distinguished by the presence of native cupriferous gold. This zonal hydrothermal-metasomatic complex was formed in three stages. The inner zone of rodingite proper is made up of chlorite-andradite-diopside rocks of stage 1, which are cut by diopside veinlets of stage 2 and calcite veinlets of stage 3. The intermediate zone consists of chloritolites, which give way to the antigorite and chrysotile-lizardite serpentinites of the outer zone. Thermometric and cryometric studies and gas chromatography showed that the gold-bearing rodingites of stages 1 and 2 were formed at t = 420–470°C, P = 2–3 kbar, and \(X_{CO_2 } \) = 0.001–0.02, i.e., under conditions typical of rodingite formation. The final stage was accompanied by a decrease in P-T parameters (0.5–1.0 kbar and 230–310°C) and an increase in \(X_{CO_2 } \) up to 0.04. The rodingite-forming fluid was extremely rich in water (\(X_{H_2 O} \) = 0.942–0.981) and contained hydrogen as the major gas component (\(X_{H_2 } \) = 0.012–0.023); its composition was essentially chloride-magnesium with minor amounts of CaCl₂ and FeCl₂ and a low salinity of 2.6–8.0 wt % NaCl equiv. The rodingite minerals showed the following isotopic characteristics (‰): δ¹⁸O from 5.5 to 6.6 and δD from 42.8 to ?44.3 for chlorite, δ¹⁸0 from 2.0 to 3.8 for andradite, δ¹⁸O from 6.0 to 6.6 for diopside, and δ¹⁸O from 10.6 to 11.4 and δ¹³C from 0.1 to ?1.8 for calcite. The chloritolite is characterized by δ¹⁸O from 5.9 to 6.6 and δD from ?49.8 to ?64.4; the antigorite serpentinite shows δ¹⁸O=6.5 and δD=?65.2; and the antigoritized chrysotile-lizardite serpentinite shows δ¹⁸O from 6.8 to 6.9 and δD from ?127 to ?128. The calculated isotopic composition of fluid in equilibrium with various rocks suggested its metamorphic origin. It was formed from the water released during dehydration of oceanic serpentinites, from the components of ultrabasic and basic magmatic rocks, and, at the final stage, from marine carbon.     

Sources of Matter and Ore-Producing Fluid of the Tamunyer Gold–Sulfide Deposit (Northern Urals): Isotope Results

The Tamunyer deposit is a typical example of gold–sulfide mineralization located in the lower lithologic–stratigraphic unit (S₂–D₁) of the Auerbach volcanic–plutonic belt. The latter comprises island–arc andesitic volcano–sediments, volcanics, and comagmatic intrusive formations. Carbonates have demonstrated intermediate values of δ¹³C between marine limestone and mantle. The quartz δ¹⁸O is in the range of 15.3–17.2‰. The δ³⁴S of sulfides from the beresitized volcano-sedimentary rocks and ores varies widely from –7.5 to 12‰. The calculated isotope compositions of H₂O, CO₂, and H₂S of the ore-bearing fluid imply two major sources of matter contributing to ore genesis: local rocks and foreign fluid. The ore-bearing fluid was formed by interaction and isotope equilibration between a deep magmatic fluid and marine carbonates (W/R ~ 1), with the contribution of sulfur from the volcano-sedimentary rocks.