Direct determination of organic carbon in modern reef sediments and calcareous organisms after dissolution of carbonate

An improved method for the direct determination of organic carbon in calcareous marine sediments, organisms and particulate matter is described. Samples are dissolved in phosphoric acid to remove carbonates, purged with oxygen to remove CO₂, and the resulting acidic solution is analysed for total (dissolved and particulate) organic carbon. The method is rapid, involves minimal sample manipulation, and is both accurate (better than ± 2%) and precise (better than ± 0.2 mg organic carbon/g sediment). The method is especially suitable for modern carbonate sediments which have low levels of predominantly acid-soluble organic carbon.     

Bayesian Spatial Modelling of Gamma Ray Count Data

Gamma ray logging is a method routinely employed by geophysicists and environmental engineers in site geology evaluations. Modelling of gamma ray data from individual boreholes assists in the local identification of major lithological changes; modelling these data from a network of boreholes assists with lithological mapping and spatial stratigraphic correlation. In this paper we employ Bayesian spatial partition models to analyse gamma ray data spatially. In particular, a spatial partition is defined via a Voronoi tessellation and the mean intensity is assumed constant in each cell of the partition. The number of vertices generating the tessellation as well as the locations of vertices are assumed unknown, and uncertainty about these quantities is described via a hierarchical prior distribution. We describe the advantages of the spatial partition modelling approach in the context of smoothing gamma ray count data and describe an implementation that may be extended to the fitting of a more general model than a constant mean within each cell of the partition. As an illustration of the methodology we consider a data set collected from a network of eight boreholes, which is part of a geophysical study to assist in mapping the lithology of a site. Gamma ray logs are linked with geological information from cores and the spatial analysis of log data assists with predicting the lithology at unsampled locations.     

Smoothing and Change Point Detection for Gamma Ray Count Data

Gamma ray detectors are used to measure the natural radioactivity of rocks. For a number of boreholes drilled at a site the gamma ray detector is lowered into each borehole and counts of gamma ray emissions at different depths are recorded as the instrument is gradually raised to ground level. The profile of gamma counts can be informative about the geology at each location. The raw count data are highly variable, and in this paper we describe the use of adaptive smoothing techniques and change point models in order to identify changes in the geology based on the gamma logs. We formulate all our models for the data in the framework of the class of generalized linear models, and describe computational methods for Bayesian inference and model selection for generalized linear models that improve on existing techniques. Application is made to gamma ray data from the Castelreagh Waste Management Centre which served as a hazardous waste disposal facility for the Sydney region between March 1974 and August 1998. Understanding the geological structure of this site is important for further modelling the transport of pollutants beneath the waste disposal area.     

Long-term drainage evolution in the shoalhaven catchment,southeast highlands,Australia

The long-term evolution of streams in the Shoalhaven catchment of southeast New South Wales has been a contentious issue for decades. Several authors have suggested that the Shoalhaven River was captured at the sharp eastward bend near Tallong: this has been used as evidence for the westward migration of the east Australian divide in this area. Other workers, however, have argued that capture did not occur and that the location of the divide has been stable throughout the Tertiary. A vast sheet of sediments which spread across and infill a palaeovalley network cut into a broad undulating plain in the middle Shoalhaven catchment provides a record of stream behaviour since at least the start of the Tertiary. This record shows that the Shoalhaven River and many of its tributaries have maintained almost the same courses since at least the very Early Tertiary. This provides strong evidence against the capture hypothesis. The record further suggests that during the Paleogene these streams were graded to a level within the southeast Australian highlands; their depths of incision thus cannot be used as evidence for the extent of uplift of the southeast Australian highlands during this time.     

Politicians and geomorphological blunders. Some examples relating to rivers and coasts from Queensland,Australia

Editors' Note: The following is the eighth in the Singapore Journal of Tropical Geography Lecture Series. It is based on the plenary presentation of 10 July at the 7th International Conference on Geomorphology held in Melbourne in 2009. Geomorphologists have an important role to not just understand and interpret the nature of processes operating within the physical landscape, but also to communicate this information to those who can use it to benefit society. Policy makers and legislators often develop documents relating to the management and use of landforms and landscapes that contain little or no input from geomorphologists, which can and do have undesirable consequences for governments, communities and the natural environment. Examples relating to rivers and coasts from Queensland, Australia highlight inadequacies in policies and legislation because of a lack of input from geomorphologists. In one instance the definition of a stream channel has been reinterpreted by the legal system because of a poorly developed definition within the legislation. The outcome is a legal definition of a stream channel based on the Q3 month flow (3‐month average recurrence interval discharge or flow). In another instance, people and property are being placed at risk from coastal erosion and impact from tropical cyclone generated marine inundations (waves and surge) because a lack of understanding of geomorphic processes operating along the coast has been inscribed into policies and legislation. These are examples from one region but similar situations will exist elsewhere globally. Both politicians and geomorphologists have a role to communicate better with each other about these matters. Geomorphologists in particular need to be more proactive in advising politicians on issues in which they have expertise.     

A 6000 year tropical cyclone record from Western Australia

This study provides the first long-term tropical cyclone record from the Indian Ocean region. Multiple shore parallel ridges composed entirely of one species of marine cockle shell (Fragum eragatum) standing between 3 and 6 m above mean sea level occur at Hamelin Pool, Shark Bay, Western Australia. The ridges record a tropical cyclone history between approximately 500 cal BP and 6000–7000 cal BP. Numerical storm surge and shallow water wave modelling techniques have been applied to determine the intensity (central pressure with uncertainty margins) of the storms responsible for deposition of the ridges, which has occurred approximately every 190–270 years. The ridges also record a 1700 year gap in tropical cyclone activity, between approximately 5400 cal BP and 3700 cal BP, where ridges deposited prior to this time were buried by a substantial deposit of aeolian fine-grained terrestrial sediment. The presence of this sedimentary unit suggests that this 1700 year period was characterised by a very dry climate; possibly the driest phase experienced in this region since the mid-Holocene. The absence of tropical cyclones at this time and the occurrence of this mega-drought may be linked.     

Pyrolysis GC-MS as a rapid screening tool for determination of peat-forming plant composition in cores from ombrotrophic peat

Peat cores provide decadal to centennial records of climatic and environmental change, including evidence for human/environment interaction. Existing palaeoenvironmental proxies (macrofossils, pollen, humification, testate amoebae, lipid composition) require multiple laboratory preparation steps and may be subject to differential preservation that can limit production of a continuous time series. The potential for pyrolysis gas-chromatography-mass-spectrometry (Py-GC-MS) to be applied to bulk peat samples is investigated here. The only preparatory step required was freeze drying. Analysis of a range of important peat-forming plants demonstrates that Sphagnum moss species are unique in containing the pyrolysis product of sphagnum acid, 4-isopropenylphenol. In contrast, non-Sphagnum species are rich in lignin pyrolysis products, which are absent from Sphagnum. The presence of these pyrolysis markers is reflected in bulk peat composition and tested here using archives from Bolton Fell Moss and Butterburn Flow (UK), Kontolanrahka (Finland) and Bissendorfer Moor (Germany). A ratio between 4-isopropenylphenol and two lignin pyrolysis products is proposed as a proxy for total Sphagnum input to peat archives and shows potential for use as a rapid screening tool for characterising bulk peat composition before more intensive analysis.     

Evolution of drainage patterns on Cape York Peninsula,northeast Queensland

Drainage patterns along passive continental margins are often hypothesised to be the result of drainage disruption following highland uplift and downwarping of the highland flank. Several studies of stream catchments throughout southeast Australia have demonstrated that the opposite tends to be the case in this region because the field evidence favours stream and continental drainage‐divide stability. While significant advances have been made towards understanding this phenomenon in the southeastern corner of the continent, little is known of the evolution of streams and highlands in northeast Australia. Our study examines palaeochannels and fluvial sedimentary units close to the continental drainage divide in six stream catchments along the length of Cape York Peninsula. The results show that four of the catchments (Barron‐Mitchell and Stewart‐Holroyd) have experienced continental divide and drainage stability, whereas the Pascoe‐Wenlock system appears to have experienced westward migration of the continental drainage divide and diversion of the Pascoe River. River diversion here is likely to be a result of the raising of base‐level and flooding of stream channels during the Cretaceous marine transgression and subsequent stream incision by the Pascoe River along structural weaknesses in the underlying strata, following cessation of marine conditions.