An innovative priming system - emulsion-based booster

The mineral industry is leading towards a technology driven optimization process. Drilling and blasting are such unit operations in a mine, which can alter the balance sheet of the mine if not planned properly. The development, improvement and utilization of innovative technologies in terms of blast monitoring instruments and explosives technology are important for cost effectiveness and safety of mineral industries.

The ever-growing demand for minerals has compelled the industry to adopt large opencast projects using heavy equipment. This has necessitated use of a few hundred tonnes of explosives in each blast. The bulk delivered fourth generation explosives have solved the problem of explosive loading to a large extent as it provides improved safety in manufacturing, transportation and handling. Bulk delivered emulsion is non-explosive until gasification is complete and a large quantity of explosive can be transported and loaded into blast holes efficiently and with safety. The priming of bulk delivered explosives in Indian mines uses the conventional PETN/TNT-based boosters. The conventional booster possesses safety problems in terms of handling and use, so Indian Explosives Ltd has developed an emulsion-based booster (Powergel Boost).

This paper explores the potential of an emulsion-based booster used as a primer to initiate bulk delivered emulsion explosives used in mines. An attempt has been made at a comparative study between the conventional booster and the emulsion-based booster in terms of the initiation process developed and their capability of developing and maintaining a stable detonation process in the column explosives. The study has been conducted using a continuous velocity of detonation (VOD) measuring instrument, the VODMate two channel system manufactured by Instantel Inc. of Canada. During this study three blasts were monitored. In each blast two holes were selected for study, the first hole was initiated using a conventional booster while the other one used an emulsion-based booster. The findings of the study advocates that the emulsion-based booster is capable of the efficient priming of bulk delivered column explosive with a stable detonation process in the column.     

A sulfur isotope study of volcanogenic massive sulfide deposits of the Eastern Black Sea province,Turkey

Kuroko-type massive sulfide deposits of the Eastern Black Sea province of Turkey are related to the Upper Cretaceous felsic lavas and pyroclastic rocks, and associated with clay and carbonate alteration zones in the footwall and hangingwall lithologies. A complete upward-vertical section of a typical orebody consists of a stringer-disseminated sulfide zone composed mainly of pyrite and chalcopyrite; a massive pyrite zone; a massive yellow ore consisting mainly of chalcopyrite and pyrite; a black ore made up mainly of galena and sphalerite with minor amounts of chalcopyrite, bornite, pyrite and various sulfosalts; and a barite zone. Most of the deposits in the province are associated with gypsum in the footwall or hangingwall. The paragenetic sequence in the massive ore is pyrite, sphalerite, chalcopyrite, bornite, galena and various sulfosalts, with some overlap between the mineral phases. Massive, stringer and disseminated sulfides from eight kuroko-type VMS deposits of the Eastern Black Sea province have a ³⁴S range of 0–7 per mil, consistent with the ³⁴S range of felsic igneous rocks. Sulfides in the massive ore at Madenköy (4.3–6.1 per mil) differ isotopically from sulfides in the stringer zone (6.3–7.2 per mil) suggesting a slightly increased input of H₂S derived from marine sulfate with time. Barite and coarse-grained gypsum have a ³⁴S range of 17.7–21.5 per mil, a few per mil higher than the ³⁴S value of contemporaneous seawater sulfate. The deposits may, therefore, have formed in restricted basins in which bacterial reduction of sulfate was taking place. Fine-grained, disseminated gypsum at Kutlular and Tunca has ³⁴S values (2.6–6.1 per mil) overlapping those of ore sulfides, indicating sulfide oxidation during waning stages of hydrothermal activity.     

Petrogenesis of the ü?kap?l? Granitoid and its Mafic Enclaves in Elmal? Area (Ni?de, Central Anatolia, Turkey)

The Late Cretaceous ükapili Granitoid including mafic microgranular enclaves intruded into metapelitic and metabasic rocks, and overlain unconformably by Neogene ignimbrites in the Ni de area of Turkey. It is mostly granite and minor granodiorite in composition, whereas its enclaves are dominantly gabbro with a few diorites in composition. The ükapili Granitoid is composed mainly of quartz, K-feldspar, plagioclase, biotite, muscovite and minor amphibole while its enclaves contain mostly plagioclase, amphibole, minor pyroxene and biotite. The ükapili Granitoid has calcalkaline and peraluminous (A/CNK= 1.0-1.3) geochemical characteristics. It is characterized by high LILE/HFSE and LREE/HREE ratios ((La/Lu) N = 3-33), and has negative Ba, Ta, Nb and Eu anomalies, resembling those of collision granitoids. The ükapili Granitoid has relatively high 87Sr/86Sr (i) ratios (0.711189-0.716061) and low εNd (t) values (-5.13 to -7.13), confirming crustal melting. In contrast, the enclaves are tholeiitic and metaluminous, and slightly enriched in LILEs (K, Rb) and Th, and have negative Ta, Nb and Ti anomalies; propose that they were derived from a subduction-modified mantle source. Based on mineral and whole rock chemistry data, the ükapili granitoid is H-(hybrid) type, post-collision granitoid developed by mixing/mingling processes between crustal melts and mantle-derived mafic magmas.     

Late Ordovician climbing‐dune cross‐stratification: a signature of outburst floods in proglacial outwash environments?

Climbing dune‐scale cross‐statification is described from Late Ordovician paraglacial successions of the Murzuq Basin (SW Libya). This depositional facies is comprised of medium‐grained to coarse‐grained sandstones that typically involve 0·3 to 1 m high, 3 to 5 m in wavelength, asymmetrical laminations. Most often stoss‐depositional structures have been generated, with preservation of the topographies of formative bedforms. Climbing‐dune cross‐stratification related to the migration of lower‐flow regime dune trains is thus identified. Related architecture and facies sequences are described from two case studies: (i) erosion‐based sandstone sheets; and (ii) a deeply incised channel. The former characterized the distal outwash plain and the fluvial/subaqueous transition of related deltaic wedges, while the latter formed in an ice‐proximal segment of the outwash plain. In erosion‐based sand sheets, climbing‐dune cross‐stratification results from unconfined mouth‐bar deposition related to expanding, sediment‐laden flows entering a water body. Within incised channels, climbing‐dune cross‐stratification formed over eddy‐related side bars reflecting deposition under recirculating flow conditions generated at channel bends. Associated facies sequences record glacier outburst floods that occurred during early stages of deglaciation and were temporally and spatially linked with subglacial drainage events involving tunnel valleys. The primary control on the formation of climbing‐dune cross‐stratification is a combination between high‐magnitude flows and sediment supply limitations, which lead to the generation of sediment‐charged stream flows characterized by a significant, relatively coarse‐grained, sand‐sized suspension‐load concentration, with a virtual absence of very coarse to gravelly bedload. The high rate of coarse‐grained sand fallout in sediment‐laden flows following flow expansion throughout mouth bars or in eddy‐related side bars resulted in high rates of transfer of sands from suspension to the bed, net deposition on bedform stoss‐sides and generation of widespread climbing‐dune cross‐stratification. The later structure has no equivalent in the glacial record, either in the ancient or in the Quaternary literature, but analogues are recognized in some flood‐dominated depositional systems of foreland basins.     

Lentil Straw: A Novel Adsorbent for Removing of Hazardous Dye – Sorption Behavior Studies

Sorption behavior of Lanaset Red (LR) G on lentil straw (LS) was studied as a function of particle size, adsorbent dose, initial pH value, initial dye concentration, and contact time. Sorption kinetics data was well described by logistic model. Modified logistic equation can be used to explain effects of initial dye concentrations and contact time on the sorption of LR G with high R² value. Freundlich model was found to be excellent in representing the equilibrium data. Thermodynamic parameters like free energy (ΔG⁰), enthalpy (ΔH⁰), and entropy (ΔS⁰) were calculated by the use of Langmuir constant. Thermodynamic data showed that the sorption processes were spontaneous and endothermic in nature. Desorption process suggested that strong binding and weak interactions could be formed between adsorbent surface and dye molecules. Results revealed that LS has a remarkable potential for the sorption of LR G.     

Investigating Correlations and Variations of Air Pollutant Concentrations under Conditions of Rapid Industrialization – Kocaeli (1987–2009)

In this study, it was aimed to characterize temporal variations of air pollutants for determining contribution to pollution episodes and to obtain correlations between these pollutants. With this aim we used data analysis for measured sulfur dioxide (SO₂), particulate matter (PM, black fume and PM10), nitrogen oxides (NO_x), ozone (O₃), carbon monoxide (CO), methane (CH₄), and non‐methane hydrocarbons (NMHC) recorded in Kocaeli, one of the most industrilizated cities of Turkey. Pollutant concentrations were the results of continuous and semi‐automatic measurements. Semi‐automatic measurements of SO₂ and PM (black fume) were enclosing period from 1987 to 2008 whereas continuous monitoring of all pollutants included years of 2007–2009. In the first stage of the study daily, monthly, annual, and seasonal variations of pollution were researched. Annual average concentrations were compared with limits set by Air Quality Protection Regulation (AQPR), Air Quality Evaluation and Management Regulation (AQEMR), World Health Organization (WHO), European Union (EU), and National Ambient Air Quality Standards (USEPA). In the following stage relationships between pollutants such as NO₂–O₃, NO_x–CO, NO_x–NMHC, and NO_x–SO₂ were investigated and correlation coefficients were determined as 0.87, 0.56, 0.51, and 0.69, respectively. R² values of regression models developed from these correlations were 0.78, 0.56, 0.34, and 0.72, respectively. Vehicle density of the traffic was evaluated with NO_x–O₃ emissions and decrease was seen in NO_x emissions due to decreasing vehicle density at weekends whereas O₃ concentrations increased. These correlations enable prediction of the parameters that cannot be measured which is important for providing improvement in early warning systems.     

Stratigraphy of the sediment infill in Bosphorus Strait: water exchange between the Black and Mediterranean Seas during the last glacial Holocene

The sediment infill over the Paleozoic bedrock in the Bosphorus Strait consists of four sedimentary units which were deposited in the last 26,000 ¹⁴C years B.P. The stratigraphy of these units suggests that this part of the Bosphorus was a freshwater lake between 26,000 and 5,300 ¹⁴C years B.P., depositing sands with a freshwater mollusc fauna of Black Sea neo-euxinian affinity (Dreissena rostriformis, Dreissena polymorpha, and Monodacna pontica). The first appearance of euryhaline Mediterranean molluscs (e.g., Ostrea edulis, Mytilus edulis) was observed at 5,300 ¹⁴C years B.P. in this part of the Bosphorus. Deposition of coarse Mytilus-bank and Ostrea-bank units suggests that the establishment of the present dual-flow regime in the Bosphorus took place at about 4,400 ¹⁴C years B.P.