QUEST on DASI: a South Pole CMB polarization experiment

QUEST on DASI is a ground-based, high-sensitivity, high-resolution (ℓ_max2500) experiment designed to map CMB polarization at 100 and 150 GHz and to measure the power spectra from E-modes, B-modes from lensing of the CMB, and B-modes from primordial gravitational waves. The experiment comprises a 2.6 m Cassegrain optical system, equipped with an array of 62 polarization-sensitive bolometers (PSBs), located at the South Pole. The instrument is designed to minimize systematic effects; features include differencing of pairs of orthogonal PSBs within a single feed, a rotatable achromatic waveplate, and axisymmetric rotatable optics. In addition the South Pole location allows both repeatable and highly controlled observations. QUEST on DASI will commence operation in early 2005.     

Cycling of trace metals (Mn, Fe, Mo, U, V, Cr) in deep pore waters of intertidal flat sediments

Trace metals (Mn, Fe, Mo, U, Cr, V) were studied in pore waters of an intertidal flat located in the German Wadden Sea. The study system is an example of a permeable tidal flat system where pore water exchange is affected by tidal driven pressure gradients besides diffusion. Permanently installed in situ samplers were used to extract pore waters down to 5 m depth throughout one year. The samplers were either located close to the tidal flat margin or in central parts of the tidal flat. Despite dynamic sedimentological and hydrological conditions, the general trends with depth in deep tidal flat pore waters are remarkably similar to those observed in deep sea environments. Rates of trace metal cycling must be comparably large in order to maintain the observed pore water profiles. Trace metals further show similar general trends with depth close to the margin and in central parts of the tidal flat. Seasonal sampling revealed that V and Cr vary concurrent with seasonal changes in dissolved organic carbon (DOC) concentration. This effect is most notable close to the tidal flat margin where sulphate, DOC, and nutrients vary with season down to some metres depth. Seasonal variations of Mn, Fe, Mo, and U are by contrast limited to the upper decimetres of the sediment. Their seasonal patterns depend on organic matter supply, redox stratification, and particulate matter deposited on sediment surfaces. Pore water sampling within one tidal cycle provides evidence for pore water advection in margin sediments. During low tide pore water flow towards the creekbank is generated by a hydraulic gradient suggesting that deep pore waters may be seeping out of creekbank sediments. Owing to the enrichment of specific elements like Mn in pore water compared to sea water, seeping pore waters may have an impact on the chemistry of the open water column. Mass balance calculations reveal that the impact of deep pore waters on the Mn budget in the open water column is below 4%. Mn deep pore water discharge of the whole Wadden Sea is estimated to be about 9% of the total dissolved riverine Mn input into the Southern North Sea.     

The passivation of calcite by acid mine water. Column experiments with ferric sulfate and ferric chloride solutions at pH 2

Column experiments, simulating the behavior of passive treatment systems for acid mine drainage, have been performed. Acid solutions (HCl or H₂SO₄, pH 2), with initial concentrations of Fe(III) ranging from 250 to 1500 mg L⁻¹, were injected into column reactors packed with calcite grains at a constant flow rate. The composition of the solutions was monitored during the experiments. At the end of the experiments (passivation of the columns), the composition and structure of the solids were measured. The dissolution of calcite in the columns caused an increase in pH and the release of Ca into the solution, leading to the precipitation of gypsum and Fe–oxyhydroxysulfates (Fe(III)–SO₄–H⁺ solutions) or Fe–oxyhydroxychlorides (Fe(III)–Cl–H⁺ solutions). The columns worked as an efficient barrier for some time, increasing the pH of the circulating solutions from 2 to 6–7 and removing its metal content. However, after some time (several weeks, depending on the conditions), the columns became chemically inert. The results showed that passivation time increased with decreasing anion and metal content of the solutions. Gypsum was the phase responsible for the passivation of calcite in the experiments with Fe(III)–SO₄–H⁺ solutions. Schwertmannite and goethite appeared as the Fe(III) secondary phases in those experiments. Akaganeite was the phase responsible for the passivation of the system in the experiments with Fe(III)–Cl–H⁺ solutions.     

Assessment of the impact of the planetary scale on the decay of blocking and the use of phase diagrams and enstrophy as a diagnostic

It was shown that abrupt changes in the large-scale structure of atmospheric flows may lead to the rapid decay of blocking. Analysis of phase diagrams made it possible to identify when sharp changes occurred in the dynamics of the system. The connection of these changes to the decay of blocking was estimated for three blocking events in the Southern Hemisphere. In addition to phase diagrams, enstrophy was used as a diagnostic tool for the analysis of blocking events. From the results of this analysis, four scenarios for the decay mechanisms were determined: (i) decay with a lack of synoptic-scale support, (ii) decay with an active role for synoptic processes, and (iii–iv) either of these mechanisms in the interaction with an abrupt change in the character of the planetary-scale flow.     

Variability of organic δC and C/N in the Mersey Estuary, U.K. and its implications for sea-level reconstruction studies

Microfossil analysis (e.g. diatoms, foraminifera and pollen) represents the cornerstone of Holocene relative sea-level (RSL) reconstruction because their distribution in the contemporary inter-tidal zone is principally controlled by ground elevation within the tidal frame. A combination of poor microfossil preservation and a limited range in the sediment record may severely restrict the accuracy of resulting RSL reconstructions. Organic δ¹³C and C/N analysis of inter-tidal sediments have shown some potential as coastal palaeoenvironmental proxies. Here we assess their viability for reconstructing RSL change by examining patterns of organic δ¹³C and C/N values in a modern estuarine environment. δ¹³C and C/N analysis of bulk organic inter-tidal sediments and vegetation, as well as suspended and bedload organic sediments of the Mersey Estuary, U.K., demonstrate that the two main sources of organic carbon to surface saltmarsh sediments (terrestrial vegetation and tidal-derived particulate organic matter) have distinctive δ¹³C and C/N signatures. The resulting relationship between ground elevation within the tidal frame and surface sediment δ¹³C and C/N is unaffected by decompositional changes. The potential of this technique for RSL reconstruction is demonstrated by the analysis of part of an early Holocene sediment core from the Mersey Estuary. Organic δ¹³C and C/N analysis is less time consuming than microfossil analysis and is likely to provide continuous records of RSL change.     

Site occupation and electric field gradient in acentric neptunite-measurements and evaluations concerning powder- and single crystal – Mössbauer spectroscopy and x-ray diffractometry

Mössbauer measurements on neptunite (KNa₂Li(Fe,Mn,Mg)₂Ti₂Si₈O₂₄) at 400?K reveal the distribution of Fe-ions on the crystallographic sites in agreement with neutron diffraction results published elsewhere. Even the previously postulated small amount of Fe-ions on the Ti(2) site has been detected, combined with a charge transfer which is in agreement with optical absorption investigations by other authors. A qualitative site occupation model is able to explain the different features of our observations. Single crystal Mössbauer measurements with the k-vector of incident γ-rays parallel to the crystallographic b-axis (space group Cc) of neptunite at different temperatures yield the angle β between the main component of the electric field gradient (EFG), V _zz and b. This angle is in close accordance with a calculated value of β for the Fe(1) position from electron density maps. The latter also reveal an absolute value of V _zz which is in satisfactory agreement with V _zz derived from Mössbauer spectroscopy.     

Geo–ecology and management of sensitive montane landscapes

Montane (alpine) areas are generally of high value for nature conservation. Such environments and the habitats they support are dynamic and often fragile. They are vulnerable to disturbance from a range of human activities and are responsive to climate changes over short and long timescales. Biodiversity and conservation values are closely linked to geological history, geomorphological processes and soils, and it is crucial that management systems are based on understanding these links.
There are many similarities between the Cairngorm Mountains (Scotland), the Giant Mountains (Czech Republic) and Abisko Mountains (Sweden) in terms of geology, geomorphology, ecology, links with biodiversity and high conservation importance. Comparable pressures and management issues involve, to varying degrees, a history of human use and impacts from deforestation, pasturing, grazing, recreation and atmospheric pollution. Landscape change therefore involves a complex interplay between natural and anthropogenic factors. Managing such change requires better understanding of the geo–ecological processes involved and the factors that determine landscape sensitivity. This is illustrated through a simple framework and examples from the three areas. Comparison of landscape sensitivity between similar montane areas, but in different geographic locations and climatic environments, should allow more informed management planning and a precautionary approach in advance of further changes in human activity and from predicted global warming scenarios.     

探测冰盖和多年冻土层的融冰探头研发

The exploration of ice sheets by melting vertical holes into the ground has some tradition in terrestrial glaciology. Such probes have been used since the 1960's to investigate the vertical structure of the ice in Greenland and Antarctica and in alpine glaciers. In this paper we look into the possibility to develop similar devices for use on extraterrestrial icy bodies, like e.g. the polar areas on Mars or the icy satellites of the outer solar system. We report on some basic experiments performed in the cryo-vacuum laboratory of the Space Research Institute of the Austrian Academy of Sciences, Graz. In these experiments the penetration of a simple melting probe into compact and porous water ice (with a snow-like texture) was monitored, both under vacuum conditions and under air pressure. The observed penetration speeds for a given power supply are compared with a simple mathematical model. We conclude that a miniature melting probe with small overall dimensions and a reasonable power demand could well be part of the payload of a future planetary mission, for example to the poles of Mars. Such missions are currently under discussion in several space agencies. Moreover such probes could also e? ectively be used in terrestrial environments. A possible design is presented at the end of the paper.     

Diatom-inferred depth models in 8 Canadian boreal lakes: inferred changes in the benthic:planktonic depth boundary and implications for assessment of past droughts

Assessment of past drought in boreal regions, a region predicted to be strongly affected by climate warming, can provide insights into future availability of water. However, limited instrumental data and paleoclimatic data are available for this assessment. To address this lack of data in the boreal region of northwest Ontario, a regional study of lakes in the Winnipeg River Drainage Basin was initiated. Diatom-inferred (D-I) depth models were developed based on surface samples collected along a depth gradient within 8 small boreal lakes. Weighted-averaging and modern analog approaches provided robust within-lake depth models for each of the study lakes, with bootstrapped r² values ranging from 0.90 to 0.98, and root-mean-squared-errors of prediction (RMSEP) between 1.1 and 2.5 m. Large differences in the estimated depth optima for three representative, but common diatom species across our 8 study lakes suggested that within-lake calibration datasets are more appropriate for inferring past drought based in depth models than a regional multi-lake calibration dataset, and that light and related variables are controlling factors governing the maximum depth of benthic taxa. A down-core application of the D-I depth models on a near-shore core from Meekin Lake, retrieved near the present-day ecotone between the benthic and planktonic diatom assemblages indicated highly similar trends in inferred depth (r = 0.96). The models have significant correlations with other metrics of changes in depth including diatom species richness (r = 0.74–0.78) and evenness (r = 0.76–0.8), thereby allowing a check on the strength and direction of the depth inferences down-core. Near-shore cores located near the benthic:planktonic transition is a sensitive region that can provide estimates of past droughts in lakes where such inferences have been difficult to estimate.