Mudstone lithogeochemistry and formation conditions of Vendian deposits in the Shkapovo-Shikhan Basin

Variation of geochemical modules and indices in mudstones from the Upper Vendian Kairovo and Shkapovo groups of the Shkapovo-Shikhan Basin provides the comprehensive information on changes in maturity of the fine aluminosiliciclastic material delivered in the basin, characterizes the redox environment in bottom water, and makes it possible to reconstruct the rock composition in provenance and its evolution through time. The generally moderate maturity of the fine terrigenous clastic material suggests that a nearly semiarid-semihumid climate dominated in paleodrainage area throughout the Late Vendian. It has been established that reducing environment did not exist in bottom water of the central Shkapovo-Shikhan Basin throughout the Late Vendian. Intermediate rocks prevailed in the paleodrainage area. More silicic rocks could occur only in the early Staropetrovo and late Salikhovo times. Data points of mudstones from the Kairovo and Shkapovo Groups plotted on the Cr-Ni, Co-V, Co/Hf-Ce/Cr, La-Th, and La/Sm-Sc/Th diagrams indicate that both Archean and more mature Paleoproterozoic crustal blocks existed in different proportions in the Late Vendian within source areas.     

Fine-Grained Aluminosiliciclastic Rocks of the Middle Riphean Stratotype Section in the Southern Urals: Formation Conditions,Composition and Provenance Evolution

General trends of the formation of Middle Riphean fine-grained aluminosiliciclastic rocks in the Bashkir Meganticlinorium are considered. It is shown that Yurmatinian shales do not contain any significant pyroclastic admixture. Judging from the relatively constant Th/Cr ratio throughout the Yurmatinian section, the tectonic regime in the study territory during the early Middle Riphean is suggested to be rather stable. The main paleoclimatic indices and indicators of the pelitic material maturity (CIA, CIW, IVC, PIA, and Ce/Y) suggest that paleodrainage systems in the early Middle Riphean were dominated by humid climate that gave way to the arid or semiarid type in the middle Yurmatinian. The low Mo/Mn ratio and some other indicators of redox conditions in shales from all Yurmatinian lithostratigraphic units show that no explicit reducing conditions existed in the basin during the early Middle Riphean. The shales were characterized by the increase in K₂O/Al₂O₃ ratio, gradual enrichment in REE, and growth of LREE/HREE and La_N/Yb_N ratios toward the middle Yurmatinian, indicating the gain of an appreciable amount of slightly weathered arkosic aluminosiliciclastic material in the sedimentary basin about 1220–1200 Ma ago. The REE distribution and the UCC- and AUC-normalized shale compositions suggest that the eroded upper crust was compositionally close to the UCC. The occurrence of mafic and ultramafic rocks is also inferred. Data points of Yurmatinian shales plotted in the Cr–Ni, Eu/Eu*–Gd_N/Yb_N, and (La/YB)_N–Yb_N diagrams are localized between the fields of Upper Archean and post-Archean rocks or within the latter field. Hence, post-Archean igneous and metamorphic complexes prevailed in paleodrainage systems of the early Middle Riphean. This is also confirmed by the model Nd ages.     

Peculiarities of the rare-earth element distribution in the modern bottom sediments of the White Sea and the lower reaches of the Severnaya Dvina River

The study of the rare-earth element (REE) systematics in the modern bottom sediments of the White Sea and the lower reaches of the Severnaya Dvina River showed that they were derived by the simple mixing of the detrital material from two geochemically contrasting provenances: the Kola-Karelian geoblock almost completely consisting of Archean rocks and the northwestern Mezen syneclise made up of the Upper Vendian, Paleozoic, and Mesozoic rocks. This is best manifested by the changes in ?_Nd(0). In terms of the Gd_N/Yb_N and Eu/Eu*, most of the studied samples are comparable with the Post-Archean craton complexes, some of which resemble the average composition of the Archean mudstone. Based on the ΣREE and La_N/Yb_N, the modern bottom sediments are subdivided into two groups: (1) those close to basalts and granites and (2) those approximating common sedimentary rocks. From the lower reaches of the Pinega River to the Tersky coast, the maximal average (La/Yb)_RPSC, (Gd/Yb)_RPSC, La_N/Yb_N, and Gd_N/Yb_N ratios were determined in the samples taken at the boundary of Dvina Bay with the Basin, i.e., in the sediments with the highest content of the pelitic component. In general, the geochemical composition of the modern bottom sediments of almost the entire White Sea area was defined by input of the eroded products of the mature continental crust with the Severnaya Dvina River, the main river of the region. Such a setting, when the formation of the sediments in a peri- or intracontinental marine basin is controlled by one large river system, presumably may be propagated to the sedimentation in the Laptev Sea, the eastern Kara Sea, the Bay of Bengal, and other basins.     

Geochemistry of Riphean terrigenous rocks in the Southern Urals and Siberia and variations of the continental-crust maturity

We consider the general and specific features of the evolution of the composition of fine-grained terrigenous rocks in the Riphean sedimentary megasequences of the Southern Urals, Uchur-Maya region, and Yenisei Ridge. It has been established that the crust on the southwestern (in the modern frame of references) periphery of the Siberian craton was geochemically the most mature segment of the Riphean continental crust. For example, the fine-grained clastic rocks and metapelites of all Riphean lithostratigraphic units of the Yenisei Ridge have higher median contents of Th than the most mature Paleoproterozoic crust, and in median contents of Y and Cr/Th values they are the most similar to it. In the Southern Urals and Uchur-Maya region, some units of the Riphean sedimentary sequences show median contents of Y and Th and Cr/Th values close to those of primitive Archean crust. Analysis of Cr/Th variations in the fine-grained terrigenous rocks of all three megasequences shows that the minimum Cr/Th values, evidencing a predominance or the abundance of felsic rocks in provenances, are typical of the Riphean argillaceous shales and metapelites of the Yenisei Ridge. The distinct Cr/Th and Cr/Sc increase in the fine-grained clastic rocks of the Chingasan Group of the ridge reflects the large-scale destruction of continental crust during the formation of rift troughs as a result of the Rodinia breakup in the second half of the Late Riphean. The Cr/Th variations in the Lower and Middle Riphean argillaceous shales and mudstones of the Bashkirian mega-anticlinorium and Uchur-Maya region are in agreement, which evidences the subglobal occurrence of rifting in the early Middle Riphean (so-called “Mashak rifting”).     

The first data on the Early Proterozoic sialic basement in the eastern West Siberian Platform (studies of the Tyn'yar rhyolite–granite pluton)

Despite the long history of research, the presence of Precambrian complexes in the West Siberian basement has not been proven. The Tyn'yarskaya 100 and Tyn'yarskaya 101 wells were drilled in the Vakh–Elogui interfluve, in the eastern West Siberian Plate (eastern Khanty-Mansi Autonomous District). At a depth of 1790 m, they stripped a rhyolite extrusion, which graded into A-type alkali granitoids with rare-metal and REE mineralization (thorite, thorogummite, pitchblende, REE-carbonates, chevkinite, and others) downsection. This volcanoplutonic complex is Early Permian (K–Ar age, ～ 270 Ma; Rb–Sr age, 275.7 Ma; Sm–Nd age, 276 Ma; U–Pb age, 277 Ma). Some zircon grains from granites are much older (2049 ± 23 Ma, SHRIMP II), suggesting a relationship between the Early Permian granitic magma and the ancient matter. This might have been a granite-metamorphic basement, the partial melting of which produced the Tyn'yar rhyolite–granite body. The Sm–Nd model ages also suggest the participation of a Precambrian substratum in the formation of the rocks under study. Thus, it is quite possible that the Tyn'yar area is underlain by a Proterozoic (～ 2 Ga) sialic basement, which is an edge of the Siberian Platform thinned by Late Proterozoic–Early Paleozoic rifting and extension.     

Granitoids of the Ufalei block (South Urals): Sr-Nd isotope systematics, geodynamic position and genetic reconstructions

Petrogeochemical and isotopic-geochronological signatures in granitoids developed in structures with complex geological history represent an important feature for reconstructing paleogeodynamic settings. Granitoids are widespread in the western slope of the Urals, where the Uralian Orogen contacts via a collage of different-age blocks of the east European Platform. The Ufalei block located in the Central Urals megazone at the junction between the South and Middle Urals’ segments represents one such boundary structure with multistage geological evolution. The isotopic ages obtained by different methods for acid igneous rocks range from 1290 to 245 Ma. We determined close Rb-Sr and Sm-Nd ages (317 Ma) for granites of the Nizhnii Ufalei Massif. By their petrochemical parameters, granitoids and host granite-gneisses differ principally from each other: the former are close to subduction-related, while the latter, to continental-riftogenic varieties. The primary ratio (⁸⁷Sr/8⁶Sr)₀ = 0.70428 and ?_Nd ≈ +4 values indicate significant contribution of oceanic (island-arc?) material to the substrate, which served as a source for granites of the Nizhnii Ufalei Massif. Model Nd ages of granites vary from 641 to 550 Ma. Distinct oceanic rocks and varieties with such ages are missing from the surrounding structures. New isotopic dates obtained for ultramafic and mafic rocks from different zones of the Urals related to the Cadomian cycle imply development of unexposed Upper Riphean-Vendian “oceanic” rocks in the central part of the Ufalei block, which played a substantial role in the formation of the Nizhnii Ufalei granitoids. Such rocks could be represented, for example, by fragments of the Precambrian Timanide-type ophiolite association. The analysis of original materials combined with published data point to the heterogeneous composition and structure of the Ufalei block and a significant part of the western segment of the Central Uralian Uplift and extremely complex geological history of the region coupling the Uralian Orogen with the East European Platform in the present-day structure.     

Specific features of the distribution of trace and rare earth elements in recent bottom sediments in the lower course of the Severnaya Dvina River and White Sea

The paper discusses results of the lithogeochemical examination of recent bottom sediments in the lower course of the Severnaya Dvina River and White Sea. It has been established that the average concentration of several trace elements (Hf, Sc, Co, Y, Ni, V, Cr, Zr, Ba, and others) therein correlates with the content of the silt-pelite fraction. Maximal concentrations of the majority of above elements are confined to the silty-clayey sediments at the Basin/Dvina Bay boundary. They localized near the coastal zone only for some clastophile (Zr, Cr, and others). Typical values of the hydrolyzate module, chemical index of alteration, and Al₂O₃/SiO₂ ratio in the aleuropelitic and pelitic sediments of the Severnaya Dvina River delta, Dvina Bay, and the Dvina Bay Basin boundary suggest that these sediments are confined to sufficiently cold climate settings. Data points of sediment composition in discriminant paleotectonic diagrams are scattered over a large field probably due to high contents of the weakly weathered plagioclases, micas, and amphiboles, as well as the hydrogenic process promoting the accumulation of Fe and Mn. The PAAS-normalized spectra of rare earth elements (REE) in bottom sediments of the Pinega and Severnaya Dvina rivers, marginal filter of the latter river, Dvina Bay, and the Dvina Bay Basin boundary are similar to the REE distribution in clayey rocks of the ancient platform cover (except for a slight positive Eu anomaly). The REE systematics and distribution pattern of compositional data points of recent bottom sediments in the Gd_N/Yb_N-Eu/Eu* and Eu/Eu*-Cr/Th diagrams and values of several indicator ratios of trace elements suggest that the studied rocks were formed by the mixing of clastic materials from geochemically contrast provenances: northwestern provenance (Kola-Karelia geoblock), which is mostly composed of the Archean and Early Proterozoic crystalline complexes, and the southeastern provenance (northwestern periphery of the Mezen syncline), which is almost totally composed of Phanerozoic sedimentary rocks. The latter provenance likely played a crucial role in the geochemical signature of recent bottom sediments over a significant area of the White Sea.