Integrated geophysical and geochemical study on AMD generation at the Haveri Au–Cu mine tailings,SW Finland

The Haveri tailings area contains 1.5 Mt of sulfide-bearing waste from the Au–Cu mine that operated during 1942–1961. Geophysical and geochemical methods were used to evaluate and characterize the generation of acid mine drainage (AMD). Correlations were examined among the electrical resistivity tomography (ERT) data, the total sulfide content and concentrations of sulfide-bound metals (Cu, Co, Fe, Mn, Ni, Pb and Zn) of tailings samples, and the resistivity and geochemistry of surface water. The resulting geophysical–geochemical model defines an area in the vadose tailings, where a low resistivity anomaly (<10 Ohm m) is correlated with the highest sulfide content, extensive sulfide oxidation and low pH (average 3.1). The physical and geochemical conditions, resulting from the oxidation of the sulfide minerals, suggest that the low resistivity anomaly is associated with acidic and metal-rich porewater (i.e., AMD). The lower resistivity values in the saturated zone of the central impoundment suggest the formation of a plume of AMD. The natural subsoil layer (silt and clay) and the bedrock surface below the tailings area were well mapped from the ERT data. The detected fracture zones of the bedrock that could work as leakage pathways for AMD were consistent with previous geological studies. The integrated methodology of the study offers a promising approach to fast and reliable monitoring of areas of potential AMD generation and its subsurface movement over large areas (ca. 9 ha). This methodology could be helpful in planning drill core sampling locations for geochemical and mineralogical analysis, groundwater sampling, and choosing and monitoring remedial programs.     

Arsenic attenuation in tailings at a former Cu–W–As mine,SW Finland

Nearly half a century after mine closure, release of As from the Ylöjärvi Cu–W–As mine tailings in groundwater and surface water run-off was observed. Investigations by scanning electron microscopy (SEM), electron microprobe analysis (EMPA), synchrotron-based micro-X-ray diffraction (μ-XRD), micro-X-ray absorption near edge structure (μ-XANES) and micro-extended X-ray absorption fine structure (μ-EXAFS) spectroscopy, and a sequential extraction procedure were performed to assess As attenuation mechanisms in the vadose zone of this tailings deposit. Results of SEM, EMPA, and sequential extractions indicated that the precipitation of As bearing Fe(III) (oxy)hydroxides (up to 18.4 wt.% As₂O₅) and Fe(III) arsenates were important secondary controls on As mobility. The μ-XRD, μ-XANES and μ-EXAFS analyses suggested that these phases correspond to poorly crystalline and disordered As-bearing precipitates, including arsenical ferrihydrite, scorodite, kaňkite, and hydrous ferric arsenate (HFA). The pH within 200 cm of the tailings surface averaged 5.7, conditions which favor the precipitation of ferrihydrite. Poorly crystalline Fe(III) arsenates are potentially unstable over time, and their transformation to ferrihydrite, which contributes to As uptake, has potential to increase the As adsorption capacity of the tailings. Arsenic mobility in tailings pore water at the Ylöjärvi mine will depend on continued arsenopyrite oxidation, dissolution or transformation of secondary Fe(III) arsenates, and the As adsorption capacity of Fe(III) (oxy)hydroxides within this tailings deposit.     

GCM-based regional temperature and precipitation change estimates for Europe under four SRES scenarios applying a super-ensemble pattern-scaling method

Seasonal GCM-based temperature and precipitation projections for the end of the 21st century are presented for five European regions; projections are compared with corresponding estimates given by the PRUDENCE RCMs. For most of the six global GCMs studied, only responses to the SRES A2 and B2 forcing scenarios are available. To formulate projections for the A1FI and B1 forcing scenarios, a super-ensemble pattern-scaling technique has been developed. This method uses linear regression to represent the relationship between the local GCM-simulated response and the global mean temperature change simulated by a simple climate model. The method has several advantages: e.g., the noise caused by internal variability is reduced, and the information provided by GCM runs performed with various forcing scenarios is utilized effectively. The super-ensemble method proved especially useful when only one A2 and one B2 simulation is available for an individual GCM. Next, 95% probability intervals were constructed for regional temperature and precipitation change, separately for the four forcing scenarios, by fitting a normal distribution to the set of projections calculated by the GCMs. For the high-end of the A1FI uncertainty interval, temperature increases close to 10°C could be expected in the southern European summer and northern European winter. Conversely, the low-end warming estimates for the B1 scenario are ~ 1°C. The uncertainty intervals of precipitation change are quite broad, but the mean estimate is one of a marked increase in the north in winter and a drastic reduction in the south in summer. In the RCM simulations driven by a single global model, the spread of the temperature and precipitation projections tends to be smaller than that in the GCM simulations, but it is possible to reduce this disparity by employing several driving models for all RCMs. In the present suite of simulations, the difference between the mean GCM and RCM projections is fairly small, regardless of the number or driving models applied.     

Uraniferous bitumen nodules in the Talvivaara Ni–Zn–Cu–Co deposit (Finland): influence of metamorphism on uranium mineralization in black shales

In the central part of the Fennoscandian Shield, the Talvivaara Ni–Zn–Cu–Co deposit, hosted by Palaeoproterozoic metamorphosed black schists, contains low uranium concentrations ranging from 10 to 30 ppm. The Talvivaara black schists were deposited 2.0–1.9 Ga ago and underwent subsequent metamorphism during the 1.9–1.79 Ga Svecofennian orogeny. Anhedral uraninite crystals rimmed by bitumen constitute the main host of uranium. U–Pb secondary ion mass spectrometry dating indicates that uraninite crystals were formed between 1,878?±?17 and 1,871?±?43 Ma, during peak metamorphism. Rare earth element patterns and high Th content (average 6.38 wt%) in disseminated uraninite crystals indicate that U was concentrated during high temperature metamorphism (>400 °C). The formation of bitumen rims around uraninite may be explained by two distinct scenarios: (a) a transport of U coincident with the migration of hydrocarbons or (b) post-metamorphic formation of bitumen rims, through radiolytic polymerization of gaseous hydrocarbons at the contact with uraninite.     

Probing the high latitude ionosphere from ground-based observations: The state of current knowledge and capabilities during IPY (2007–2009)

During the International Polar Year (IPY), one area of great interest is co-coordinated, multi-instrument probing of the ionosphere at high latitudes. This region is important not only for the applications that rely upon our understanding of it, but also because it contains the footprints of processes that have their origin in the interplanetary space. Many different techniques are now available for probing the ionosphere, from radar measurements to the analysis of very low frequency (VLF) wave paths. Combining these methods provides the ability to study the ionosphere from high in the F-region to the bottom of the D-layer. Thus, coupling processes from the magnetosphere and to the neutral atmosphere can be considered. An additional dimension is through comparisons of the response of the two polar ionospheres to similar (or the same) geomagnetic activity. With more instruments available at the South Pole inter-hemispheric, studies have become easier to accomplish such that a fuller picture of the global response to Sun–Earth coupling can be painted.This paper presents a review of the current state of knowledge in ionospheric probing. It cannot provide a comprehensive guide of the work to date due to the scale of the topic. Rather it is intended to give an overview of the techniques and recent results from some of the instruments and facilities that are a part of the IPY cluster 63—Heliosphere Impact on Geospace. In this way it is hoped that the reader will gain a flavor of the recent research performed in this area and the potential for continuing collaboration and capabilities during the IPY (2007–2009).     

The contribution to IHY from the COST296 Action MIERS: Mitigation of Ionospheric Effects on Radio Systems

The objective of the COST296 Action MIERS (Mitigation of Ionospheric Effects on Radio Systems) is to develop an increased knowledge of the effects imposed by the ionosphere on practical radio systems, and for the development and implementation of techniques to mitigate the deleterious effects of the ionosphere on such systems (http://www.cost296.rl.ac.uk). The COST296 Community contributes to the international efforts of IHY with scientific and outreach activities as well. After the realization of a web site hosted by Istituto Nazionale di Geofisica e Vulcanologia (INGV), developed also to promote the ionospheric physics to the open public, the COST296 Community supported an initiative addressed to the pupils of the primary school of several European Countries: the realization of a school-calendar dedicated to the Sun and to the Sun-Earth connections.     

Groundwater and surface water contamination in the area of the Hitura nickel mine, Western Finland

Tailings-derived mine drainage water that is neutral in character, has a high electrical conductivity and contains elevated sulphate, chloride and nickel concentrations, has caused deterioration in groundwater and surface water quality in the mining area of Hitura in Western Finland. This deterioration, and thereby the location of the contaminant plume, was recognized in the water chemistry in the form of a gradual change in ion composition from Ca-HCO₃-type water towards a Mg-SO₄-rich type. It was possible to define the extent of the pollution by using cluster analysis to distinguish between hydrochemically different regimes and performing an electrical sounding survey. The results indicated that contamination is most intense close to the tailings impoundment and is related to an esker complex running across this area. Nevertheless, the water in the eastern and southern parts of the area upgradient of the hydraulic head is uncontaminated and suitable for water supply purposes.     

Glacial history, Holocene shoreline displacement and palaeoclimate based on radiocarbon ages in the area of Bockfjorden, north-western Spitsbergen, Svalbard

Age determinations of bivalve shells indicate that Bockfjorden, a fjord in north-western Spitsbergen, Svalbard, was deglaciated shortly before 10 Kya, and that the upper marine limit in this area, with an altitude of about 50 m a.s.l., has the same age. During most of the Holocene, the glaciers in Bockfjorden were less extensive than they are today. Their maximum Holocene extension occurred during the Little Ice Age. The initial shoreline emergence after the deglaciation was rapid, and former shorelines younger than 8.5 Ky are below the present sea level. A mid-Holocene transgression of the sea is traced as well as a transgression during the last thousand years.