Kimberlite petrogenesis: Insights from clinopyroxene-melt partitioning experiments at 6 GPa in the CaO-MgO-Al2O3-SiO2-CO2 system

In this experimental study, we examine the mineral-melt partitioning of major and trace elements between clinopyroxene and CO₂-rich kimberlitic melts at a pressure of 6 GPa and temperatures of 1410°C and 1430°C. The melts produced contain ∼ 28 wt% dissolved CO₂, and are saturated with olivine and clinopyroxene. To assess the effects of temperature, crystal and melt compositions on trace element partitioning, experiments were performed in the model CaO-MgO-Al₂O₃-SiO₂-CO₂ system. Our results reveal that all the elements studied, except Al, Mg, Si, and Ga, are incompatible in clinopyroxene. Partition coefficients show a considerable range in magnitude, from ∼ 10⁻³ for D_U and D_Ba to ∼ 2.5 for D_Si. The two experimental runs show similar overall partitioning patterns with the D values being lower at 1430°C. Rare earth elements display a wide range of partition coefficients, D_La (0.012-0.026) being approximately one order of magnitude lower than D_Lu (0.18-0.23). Partition coefficients for the 2+ and 3+ cations entering the M2-site exhibit a near-parabolic dependence on radius of the incorporated cations as predicted from the lattice strain model. This underlines the contribution made by the crystal structure toward controlling the distribution of trace elements. Using data obtained in this study combined with that in the published literature, we also discuss the effects that other important parameters, namely, melt composition, pressure, and temperature, could have on partitioning.Our partition coefficients have been used to model the generation of the Group I (GI) kimberlites from South Africa. The numerical modeling shows that kimberlitic melts can be produced by ∼0.5% melting of a MORB-type depleted source that has been enriched by small-degree melts originating from a similar depleted source. This result suggests that the source of GI kimberlites may be located at the lithosphere-asthenosphere transition. Percolation of small degree melts from the asthenosphere would essentially create a metasomatic horizon near the bottom of the non-convecting sublithospheric mantle. Accumulation of such small degree melts together with the presence of volatiles and conductive heating would trigger melting of the ambient mantle and subsequently lead to eruption of kimberlitic melts. Additionally, our model shows that the GI source can be generated by metasomatism of a 2 Ga old MORB source ca. 1 Ga ago. Assuming that MORB-type mantle is the most depleted source of magmas on earth, then this is the oldest age at which the GI source could have existed. However, this age most likely reflects the average age of a series of metasomatic events than that of a single event.     

Geochemistry of sedimentary rocks from Permian–Triassic boundary sections of Tethys Himalaya: implications for paleo-weathering,provenance, and tectonic setting

The geochemical characteristics of two sections—the Permian–Triassic boundary (PTB) Guryul Ravine section, Kashmir Valley, Jammu and Kashmir, India; and the Attargoo section, Spiti Valley, Himachal Pradesh, India—have been studied in the context of provenance, paleo-weathering, and plate tectonic setting. These sections represent the siliciclastic sedimentary sequence from the Tethys Himalaya. The PTB siliciclastic sedimentary sequence in these regions primarily consists of sandstones and shales with variable thickness. Present studied sandstones and shales of both sections had chemical index of alteration values between 65 and 74; such values reveal low-to-moderate degree of chemical weathering. The chemical index of weathering in studied samples ranged from 71 to 94, suggesting a minor K-metasomatism effect on these samples. Plagioclase index of alteration in studied sections ranged from 68 to 92, indicating a moderate degree of weathering of plagioclase feldspars. The provenance discriminant function diagram suggests that the detritus involved in the formation of present studied siliciclastic sedimentary rocks fall in quartzose sedimentary and felsic igneous provenances. These sediments were deposited in a passive continental margin plate tectonic setting according to their location on a Si₂O versus K₂O/Na₂O tectonic setting diagram.     

Bianchi Type I Bulk Viscous Stiff Fluid Tilted Cosmological Model in General Relativity

Bianchi Type I Bulk viscous fluid tilted cosmological model without shearviscosity is investigated. The behaviour of the model in presence andabsence of bulk viscosity is discussed. The physical and geometricalconsequences of the models are also discussed.     

A rare composite xenolith from Salt Lake Crater,Oahu: high-pressure fractionation and implications for kimberlitic melts in the Hawaiian mantle

A composite xenolith of olivine-bearing garnet clinopyroxenite wall rock intruded by two spinels + garnet veins is described. Vein minerals exhibit textural evidence of a reaction relationship with the mineral phases in the wall rock. Wall rock clinopyroxene contains exsolved blebby garnet and very fine lamellar exsolution of orthopyroxene, indicating that this xenolith had undergone considerable subsolidus cooling. Garnet-clinopyroxene thermometry suggests that the xenolith last equilibrated in the mantle at a temperature of about 1,060 (ᆭ °C). The spinels in the veins are of two kinds: pleonaste (that occurs with vein garnet) and a high-Mg, high-Al titanomagnetite (MAT spinels). Intriguingly, the MAT spinels are chemically very similar to the spinels found as groundmass in kimberlites, are moderately subhedral to euhedral, have a weakly developed cumulate texture, and, at places, show a reaction relation with the pleonaste + garnet (cumulate?) assemblage in the vein. Based on petrographic, chemical, and phase equilibrium considerations, we propose the following evolutionary history of this composite xenolith. (1) In the first stage the olivine-bearing garnet clinopyroxenite formed as crystal extracts (cumulates) as a result of high pressure fractionation of an alkaline melt in the deepest levels of Hawaiian lithosphere/uppermost asthenosphere (100-110 km). (2) In the second stage, igneous veining (the melt composition of this vein is not precisely known but could be kimberlitic) occurs in the already existing wall rock resulting in the precipitation of pleonaste + garnet. A reaction relation between the igneous veins and the wall rock also characterizes this stage. (3) The last igneous episode in this xenolith is recorded by MAT spinels in the wall rock and their precipitation close to the previous pleonaste + garnet veins. The last igneous stage could well be due again to high pressure fractionation of a kimberlitic melt (the residual melt after precipitation of pleonaste + garnet). The time relationship between exsolution and the later igneous veining stages is not known. The MAT spinels are not a result of sub-solidus solvus processes as partial reaction (melt present) between the pleonaste + garnet (from the second igneous stage) and MAT spinel exists, pointing to the igneous nature of the MAT spinel. Based on striking similarity between the MAT spinels in our xenolith and those found as groundmass in kimberlites, we propose that the veining stages could well have been kimberlitic. Thus, even though kimberlitic melts are not seen on the Koolau shield, this particular xenolith clearly shows the existence of such melts at great depths beneath Hawaii. We also propose that the initial wall rock, which represents crystal extracts (even though it does not exhibit definitive cumulate texture) as a result of high-pressure fractionation of an alkaline melt and subsequent veining episodes, are of pre-Koolau age. This implies that the Koolau shield volcano may have had a pre-shield alkalic stage.     

On precursors to the Italy earthquake M.6.2 using VLF signal of NSY(45.9 kHz) received at Kiel Longwave Monitor

On August 24, 2016, an earthquake of magnitude 6.2 struck Central Italy (42.706°N and 13.223°E) at 1:36 UT. We present the results obtained from the US Navy VLF Transmitter’s NSY signal of 45.9 kHz transmitted from Niscemi, in the province of Sicily, Italy and received at the Kiel Longwave Monitor, Germany for 2016. We analysed the terminator times and their individual differences. We also analysed trends, dispersion and night time fluctuation which gave us a possible precursor the Italy earthquake. We found ionospheric perturbations in these parameters on 14th, 19th and 22nd of August, few days prior. Moreover, we filtered the possible effects due to lightning, storms and auroras if any.     

A quantum chemical study on the formation of ethanimine (CH<Subscript>3</Subscript>CHNH) in the interstellar ice

Ethanimine (CH₃CHNH) is an important prebiotic molecule since it is a precursor of amino acid \(\alpha \)-alanine in Strecker synthesis. Two isomers (E and Z) of ethanimine were detected in the molecular cloud Sagittarius B2 north during GBT-PRIMOS survey. A possible radical-molecule reaction pathway has been proposed for the formation of ethanimine in the interstellar medium (ISM) from some previously detected interstellar molecules like methylene (both triplet CH₂ (³B₁) and singlet CH₂ (¹A₁)) and methyenimine (CH₂NH). The mechanism has been studied in the gas phase and in water ice with the help of density functional theory at B2PLYPD/6-311++G (2d, p) level of theory. It is observed that E-ethanimine forms efficiently in gas phase but ice reactions are favorable only in the hot core of molecular clouds. Same is true for the formation of Z-ethanimine which forms only at the surface of water cluster as the height of entrance barrier for formation of Z-ethanimine is similar to that of E-ethanimine. Isomerization from E to Z form is also studied and found to be forbidden due to large entrance barrier. Out of the two reaction system CH₂ (³B₁) + CH₂NH and CH₂ (¹A₁) + CH₂NH, later is more favorable then the former one due to the small entrance barrier. Still, much of the detected abundance of ethanimine comes from the reaction of CH₂ (³B₁) with CH₂NH as since CH₂ (¹A₁) has very low abundance compared to the CH₂ (³B₁) in ISM. The proposed pathway seems to be a promising candidate for the ethanimine formation in ISM.     

Anthropogenic, Climatic, and Hydrologic Trends in the Kosi Basin, Himalaya

A great debate exists concerning theinfluence of land-use and climatic changes onhydrology in the Himalayan region and its adjacentplains. As a representative basin of the Himalayas, westudied basinwide land-use, climatic and hydrologictrends over the Kosi Basin (54,000 km²) in themountainous area of the central Himalayan region. Theassessment of anthropogenic inputs showed that thepopulation of the basin grew at a compound rate ofabout one percent per annum during the past fourdecades. The comparison of land-use data between thesurveys made during the 1960s and 1978–1979 did notreveal noticeable trends in land-use change. Theanalysis of meteorological and hydrological timeseries from 1947 to 1993 showed some increasingtendency of temperature and precipitation. Thestatistical tests of hydrologic trends indicated anoverall decrease in discharge on the Kosi River andits major tributaries. The decreasing trends ofstreamflow were more significant during the low-flowmonths. The statistical analysis of homogeneityshowed that the climatic as well as the hydrologictrends were more localized in nature lacking adistinct basinwide significance.     

Tilted Bianchi Type I Models with Heat Conduction Filled with Disordered Radiations of Perfect Fluid in General Relativity

In this paper, we have investigated some tilted Bianchi Type I models with heat conduction filled with disordered radiation of perfect fluid. To get a determinate solution, we have assumed a condition A =(BC) ⁿ between metric potentials. Alternatively we have discussed the case A=(BC) ^1/3 for which tilted nature of the model is preserved. The various and geometrical features with singularities in the models are also discussed. This revised version was published online in July 2006 with corrections to the Cover Date.