Changing grading of soil: effect on critical states

Examples of situations are presented where the grading of a soil changes during its lifetime either by crushing of particles leading to an increase of fine material or by slow transport of fine particles with seepage leading to a decrease of fine material. Such grading changes influence the basic constitutive properties of the soil, in particular properties such as critical states which are dependent on the available range of densities of packing. Discrete element modelling is used to show the dependence of critical state conditions on grading and the way in which the particle assembly seeks out new critical state conditions as the grading changes.     

K-Ar Ages of Granitic Magmatism and Related Pegmatite Formation at the Umanotani-Shiroyama Mine, Shimane Prefecture, SW Japan and Their Bearings on Cooling History

Abstract. The Umanotani-Shiroyama pegmatite deposits, the largest producer of K-feldspar and quartz in Japan, are of typical granitic pegmatite. Ilmenite-series biotite granite and granite porphyry, hosting the ore deposits, and biotites separated from these rocks yielded K-Ar ages ranging from 89.0 to 81.4 Ma and 95.2 to 93.7 Ma, respectively. Muscovite and K-feldspar separated from the ore zone yielded K-Ar ages with the range of 96.2 to 93.1 Ma and 87.3 to 80.7 Ma, respectively. Muscovites from quartz-muscovite veins in the ore zone and in the granite porphyry yielded K-Ar ages of 90.4 and 76.3 Ma, respectively. K-feldspar is much younger in age than coexisting muscovite. It is noted that the K-Ar ages of biotite separates and the whole-rock ages are identical to those of muscovite and K-feldspar in the ore zone, respectively. These time relations, as well as field occurrence, indicate that the formation of the pegmatite deposits at the Umanotani-Shiroyama mine is closely related in space and time to a series of granitic magmatism of ilmenite-series nature. Using closure temperatures of the K-Ar system for biotite and K-feldspar (microcline), cooling rate of the pegmatite deposits is estimated to be about 82C/m.y. at the beginning, but slowed down to about 15C/m.y. in the later period.     

Seasonal variations of the surface currents in the Tsushima Strait

Seasonal variations of the surface currents in the Tsushima Strait were investigated by analyzing the monthly mean surface currents measured with HF radar. Several new features of the surface currents have been found. One notable feature is the large, complicated seasonal variation in the current structure in the eastern channel of the strait. For example, in the southeastern and northwestern regions of the channel, southwestward countercurrents are found in summer while southeastward acrossshore currents are found in autumn and winter. The wind-driven flow (Ekman flow) as well as surface geostrophic currents are responsible for these complicated variations of the surface currents. To quantify each variation of the flow and current, the wind-driven flow was calculated from the monthly wind (more precisely, the friction velocity) using the monthly speed factor and deflection angle estimated in our previous study, and the surface geostrophic currents were then estimated by subtracting the wind-driven flow from the measured surface currents. It was found that the acrossshore currents are the wind-driven flow, and that the surface geostrophic currents flow almost in the along-shore direction, indicating the validity of the decomposition of the surface velocity into the wind-driven flow and the geostrophic currents using the speed factor and deflection angle. A real-vector empirical orthogonal function (EOF) analysis of the surface geostrophic currents shows a pair of eddies in the lee of Tsushima and Iki Islands as the first mode, which indicates that the southwestward countercurrents in the eastern channel are formed primarily by the incoming Tsushima Warm Current.     

Numerical study of the oxidation process of dimethylsulfide in the marine atmosphere

A box model, involving simple heterogeneous reaction processes associated with the production of non-sea-salt sulfate (nss-SO ₄ ^2– ) particles, is used to investigate the oxidation processes of dimethylsulfide (DMS or CH₃SCH₃) in the marine atmosphere. The model is applied to chemical reactions in the atmospheric surface mixing layer, at intervals of 15 degrees latitude between 60° N and 60° S. Given that the addition reaction of the hydroxyl radical (OH) to the sulfur atom in the DMS molecule is faster at lower temperature than at higher temperature and that it is the predominant pathway for the production of methanesulfonic acid (MSA or CH₃SO₃H), the results can well explain both the increasing tendency of the molar ratio of MSA to nss-SO ₄ ^2– toward higher latitudes and the uniform distribution with latitude of sulfur dioxide (SO₂). The predicted production rate of MSA increases with increasing latitude due to the elevated rate constant of the addition reaction at lower temperature. Since latitudinal distributions of OH concentration and DMS reaction rate with OH are opposite, a uniform production rate of SO₂ is realized over the globe. The primary sink of DMS in unpolluted air is caused by the reaction with OH. Reaction of DMS with the nitrate radical (NO₃) also reduces DMS concentration but it is less important compared with that of OH. Concentrations of SO₂, MSA, and nss-SO ₄ ^2– are almost independent of NO _x concentration and radiation field. If dimethylsulfoxide (DMSO or CH₃S(O)CH₃) is produced by the addition reaction and further converted to sulfuric acid (H₂SO₄) in an aqueous solution of cloud droplets, the oxidation process of DMSO might be important for the production of aerosol particles containing nss-SO ₄ ^2– at high latitudes.     

Zinc-rich Pyrite from the TAG Active Mound, the TAG Hydrotherma Field, Mid-Atlantic Ridge

Abstract: Pyrite rich in Zn, up to 3.1 wt%, was found in the TAG active mound of the TAG hydrothermal field, the slow-spreading Mid-Atlantic Ridge at 26°08'N and 44°49'W. The Zn-rich pyrite is characterized by an optical homogeneity, a homogeneous distribution of Zn in the back-scattered electron images, both at a magnification of about 500, a negative correlation between Fe and Zn contents of the pyrite and a rather small unit cell edge (a₀ = 5.4117 ± 0.0008Å), strongly indicating that the detected Zn is present in the pyrite in solid solution. Such Zn concentrations are observed exclusively in dendritic pyrite, suggesting that the Znrich pyrite grew from hydrothermal fluids of a high degree of supersaturation due to quenching on the seafloor.     

Simulations of seasonal variations of sulfur compounds in the remote marine atmosphere

A photochemical box model is used to simulate seasonal variations in concentrations of sulfur compounds at latitude 40° S. It is assumed that the hydroxyl radical (OH) addition reaction to sulfur in the dimethyl sulfide (DMS) molecule is the predominant pathway for methanesulfonic acid (MSA) production, and that the rate constant increases as the air temperature decreases. Concentration of the nitrate radical (NO₃) is a function of the DMS flux, because the reaction of DMS with NO₃ is the most important loss mechanism of NO₃. While the diurnally averaged concentration of OH in winter is a factor of about 8 smaller than in summer, due to the weak photolysis process, the diurnally averaged concentration of NO₃ in winter is a factor of about 4–5 larger than in summer, due to the decrease of DMS flux. Therefore, at middle and high latitudes in winter, atmospheric DMS is mainly oxidized by the reaction with NO₃. The calculated ratio of the MSA to SO₂ production rates is smaller in winter than in summer, and the MSA to non-sea-salt sulfate (nssSO₄ ^2-) molar ratio varies seasonally. This result agrees with data on the seasonal variation of the MSA/nssSO₄ ^2- molar ratio obtained at middle and high latitudes. The calculations indicate that during winter the reaction of DMS with NO₃ is likely to be a more important sink of NO_x (NO+NO₂) than the reaction of NO₂ with OH, and to serve as a significant pathway of the HNO₃ production. If dimethyl sulfoxide (DMSO) is produced through the OH addition reaction and is heterogeneously oxidized in aqueous solutions, half of the nssSO₄ ^2- produced in summer may be through the oxidation process of DMSO. It is necessary to further investigate the oxidation products by the reaction of DMS with OH, and the possibility of the reaction of DMS with NO₃ during winter.     

Governance of disaster emergency wells in three cities in Japan affected by earthquakes

Concern has grown regarding how public and private sectors should make effective use of local groundwater to alleviate negative impacts of water-supply cutoff following an earthquake event, which can be regarded as an emergency groundwater governance problem. Existing literature on groundwater governance, however, is based on the tacit assumption of groundwater utilization under normal social conditions, and scant consideration has been given to the role of groundwater following occurrence of a natural disaster. This study conducted questionnaire surveys to reveal how groundwater was used in three cities (Kumamoto, Sapporo, and Sendai) in Japan struck by large earthquakes between 2010 and 2020. Results revealed substantial differences between these cities in terms of groundwater utilization following earthquake occurrence. The time between the restoration of the electricity supply and restoration of the waterworks, and the social capital accumulated by local governments, are indicated as possible reasons for such differences. Analysis also identified policy challenges for improved groundwater governance in an emergency: (1) establishment of a strategy for emergency water supply through combined use of groundwater and other water sources, (2) enhancement of methods for timely inspection of groundwater quality following occurrence of a disaster, (3) maintenance of records of the number of registered disaster emergency wells (DEWs), (4) creation of methods for publicizing locational information on DEWs with adequate regard for the privacy of well owners, and (5) recognition of the importance of making DEWs part of overall disaster preparedness.

     

Nutrients,light and phytoplankton production in the shallow,tropical coastal waters of Bandon Bay,Southern Thailand

Phytoplankton primary production and its regulation by light and nutrient availability were investigated in the shallow, tropical coastal waters of Bandon Bay, Southern Thailand. The bay was meso‐eutrophicated and highly turbid, receiving river water discharge. Water column stratification was consistently weak during both rainy and dry seasons. Dissolved inorganic nitrogen (DIN) was higher off the river mouth than in the other regions, suggesting that river water discharge was a main source of DIN. By contrast, dissolved inorganic phosphorus (DIP) showed a significant negative correlation with total water depth, implying that regeneration around the sea floor was an important source of DIP. Surface DIN and DIP showed positive correlations with surface primary production (PP) and water column primary productivity (ΣPP*), respectively. The combined correlation and model analyses indicate that total water depth had an ambivalent influence on water column primary production (ΣPP); shallower water depth induced more active regeneration of nutrients, but it also caused higher turbidity and lower light availability as a result of enhanced resuspension of sediments. Furthermore, there was a vertical constraint for phytoplankton during the rainy season: total water depth tended to be shallower than euphotic zone depth. In conclusion, light limitation and vertical constraint owing to shallow water depth appear to be more important than nutrient limitation for water column primary production in Bandon Bay.     

Effects of deforestation and weather on diurnal frost heave processes on the steep mountain slopes in south central Japan

Freezing and thawing processes play an important role for the gravitational transport of surface materials on steep mountain slopes in Japan. The effects of deforestation on frost heave activity were observed through the 2012/2013 winter season in Ikawa University Forest, a southern mountainous area in central Japan (1180–1310 m above sea level). During periods without snow cover, needle ice development prevailed at a clear‐cut site, and the downslope sediment movement of upper soil was 10 to 15 cm through the winter season. At a non‐cut site, rise and fall in the ground surface level prevailed on a weekly scale, with no evident downslope movements at the surface; ice lens formation in the soil layer is assumed. Abrupt changes in the radiation budget, such as the strengthening of nighttime radiative cooling and increases in daytime direct insolation, induced frequent development/deformation of needle ice at the clear‐cut site. In snow‐free periods, the day‐to‐day variability in needle ice growth length and in nighttime averaged net radiation showed significant correlations; cloudy weather with warmer and moist air intrusion associated with synoptic disturbances prevented the occurrence of needle ice. Namely, day‐to‐day weather changes directly affected the mass movement of the upper soil after deforestation. Shallow snow cover occurred discontinuously through the winter and is likely an important factor in keeping the soil moisture sufficiently high in the upper soil layer for initiating needle ice during snow‐free periods. We also discuss contributions of coastal extratropical cyclone activities providing both snow cover and cloudy weather in the southern mountain areas of central Japan to the intra‐seasonal variability in frost heave and its indirect effect on soil creep and landslides on the deforested steep slopes. Copyright © 2015 John Wiley & Sons, Ltd.