Depths of Partial Crystallization of H2O-bearing MORB: Phase Equilibria Simulations of Basalts at the MAR near Ascension Island (7 11{degrees}S)

Phase equilibria simulations were performed on naturally quenchedbasaltic glasses to determine crystallization conditions priorto eruption of magmas at the Mid-Atlantic Ridge (MAR) east ofAscension Island (7–11°S). The results indicate thatmid-ocean ridge basalt (MORB) magmas beneath different segmentsof the MAR have crystallized over a wide range of pressures(100–900 MPa). However, each segment seems to have a specificcrystallization history. Nearly isobaric crystallization conditions(100–300 MPa) were obtained for the geochemically enrichedMORB magmas of the central segments, whereas normal (N)-MORBmagmas of the bounding segments are characterized by polybariccrystallization conditions (200–900 MPa). In addition,our results demonstrate close to anhydrous crystallization conditionsof N-MORBs, whereas geochemically enriched MORBs were successfullymodeled in the presence of 0·4–1 wt% H₂O in theparental melts. These estimates are in agreement with direct(Fourier transform IR) measurements of H₂O abundances in basalticglasses and melt inclusions for selected samples. Water contentsdetermined in the parental melts are in the range 0·04–0·09and 0·30–0·55 wt% H₂O for depleted and enrichedMORBs, respectively. Our results are in general agreement (within±200 MPa) with previous approaches used to evaluate pressureestimates in MORB. However, the determination of pre-eruptiveconditions of MORBs, including temperature and water contentin addition to pressure, requires the improvement of magma crystallizationmodels to simulate liquid lines of descent in the presence ofsmall amounts of water. KEY WORDS: MORB; Mid-Atlantic Ridge; depth of crystallization; water abundances; phase equilibria calculations; cotectic crystallization; pressure estimates; polybaric fractionation     

Palaeoproterozoic A-type felsic magmatism in the Khetri Copper Belt, Rajasthan, northwestern India: petrologic and tectonic implications

Summary A number of small Palaeoproterozoic granitoid plutons were emplaced in the Khetri Copper Belt, which is an important Proterozoic metallogenic terrane in the northeastern part of Aravalli mountain range. Contiguous Biharipur and Dabla plutons are located about 15 km southeast of Khetri, close to a 170 km long intracontinental rift zone. The plutons are composed of amphibole-bearing alkali-feldspar granites, comprising microcline-albite granite, albite granite and late-stage microgranite. The albite granite in Biharipur is confined to the margins of the pluton, and shows extensive commingling with the synchronous mafic plutonics. Geochemically, the albite granites are characterised by low K₂O (∼0.5 wt.%) and elevated Na₂O (∼7.0 wt.%) abundances. By contrast, the microcline-albite granite does not show any significant mafic-granite interactions and shows normal concentrations of alkali elements. The granitoids display high concentrations of the rare earth (except Eu) and high field strength elements, high values of Ga/Al (>2.5), agpaitic index and Fe^*-number. These features together with their alkaline metaluminous and ferroan nature classify the rocks as typical A-type within-plate granites. All the granitoid facies display similar REE and incompatible element profiles indicating their cogenetic nature. These granitoids were emplaced in a shallow crustal chamber under relatively low pressures, high temperature (≥850 °C) and relatively oxidising conditions. The oxidised nature, HFSE concentrations and Nd isotope data (ɛNd = −1.3 to −2.9) favour derivation of these granitoid rocks from crustal protoliths. The generation of albite granite is attributed to the replacement of alkali feldspar and plagioclase of the original granite by pure albite as a consequence of pervasive infiltration of a high Na/(Na + K) fluid at the late-magmatic stage. This model may have wider significance for the generation of albite granites/low-K granites or albitites in other areas. The A-type plutonism under consideration seems to be an outcome of ensialic rifting of the Bhilwara aulacogen.     

An experimental study on the shallow-level migmatization of ferrogabbros from the Fuerteventura Basal Complex, Canary Islands

Spectacular shallow-level migmatization of ferrogabbroic rocks occurs in a metamorphic contact aureole of a gabbroic pluton of the Tierra Mala massif (TM) on Fuerteventura (Canary Islands). In order to improve our knowledge of the low pressure melting behavior of gabbroic rocks and to constrain the conditions of migmatization of the TM gabbros, we performed partial melting experiments on a natural ferrogabbro, which is assumed as protolith of the migmatites. The experiments were performed in an internally heated pressure vessel (IHPV) at 200 MPa, 930–1150 °C at relatively oxidizing conditions. Distinct amounts of water were added to the charge.

From 930 to 1000 °C, the observed experimental phases are plagioclase (An_60–70), clinopyroxene, amphibole (titanian magnesiohastingsites), two Fe–Ti oxides, and a basaltic, K-poor melt. Above 1000 °C, amphibole is no longer stable. The first melts are very rich in normative plagioclase (>70 wt.%). This indicates that at the beginning of partial melting plagioclase is the major phase which is consumed to produce melt. In the experiments, plagioclase is stable up to high temperatures (1060 °C) showing increasing An content with temperature. This is not compatible with the natural migmatites, in which An-rich plagioclase is absent in the melanosomes, while amphibole is stable. Our results show that the partial melting of the natural rocks cannot be regarded as an “in-situ” process that occurred in a closed system. Considerable amounts of alkalis probably transported by water-rich fluids, derived from the mafic pluton underplating the TM gabbro, were necessary to drive the melting reaction out of the stability range of plagioclase. A partial melting experiment with a migmatite gabbro showing typical “in-situ” textures as starting material supports this assumption.

Crystallization experiments performed at 1000 °C on a glass of the fused ferrogabbro with different water contents added to the charge show that generally high water activities could be achieved (crystallization of amphibole), independently of the bulk water content, even in a system with very low initial bulk water content (0.3 wt.%). Increasing water contents produce plagioclase richer in An, reduces the modal proportion of plagioclase in the crystallizing assemblage and extends the melt fraction. High melt fractions of >30 wt.% could only be observed in systems with high bulk water contents (>2 wt.%). This indicates that the migmatites were generated under water-rich conditions (probably water-saturated), since those migmatites, which are characterized as “in-situ” formations, show generally high amounts of leucosomes (>30 wt.%).     

Model for UV irradiance on arbitrarily oriented surfaces

Summary Erythemal weighted solar UV irradiances, responsible for damage to human skin, need to be known for arbitrarily oriented surfaces, since human skin has various orientations to the sun. A model for determining such irradiances is presented with the results in good agreement with measurements. The model gives spectral or biologically weighted irradiances for any user-defined orientation of a flat receiver and for selectable atmospheric and surface conditions.     

Gravity reduction with three-dimensional atmospheric pressure data for precise ground gravity measurements

The redistribution of air masses induces gravity variations (atmospheric pressure effect) up to about 20 μgal. These variations are disturbing signals in gravity records and they must be removed very carefully for detecting weak gravity signals. In the past, different methods have been developed for modelling of the atmospheric pressure effect. These methods use local or two-dimensional (2D) surface atmospheric pressure data and a standard height-dependent air density distribution. The atmospheric pressure effect is consisting of the elastic deformation and attraction term. The deformation term can be well modelled with 2D surface atmospheric pressure data, for instance with the Green's function method. For modelling of the attraction term, three-dimensional (3D) data are required. Results with 2D data are insufficient.From European Centre for Medium-Range Weather Forecasts (ECMWF) 3D atmospheric pressure data are now available. The ECMWF data used here are characterised by a spacing of Δ and Δλ = 0.5°, 60 pressure levels up to a height of 60 km and an interval of 6 h. These data are used for modelling of the atmospheric attraction term. Two attraction models have been developed based on the point mass attraction of air segments and the gravity potential of the air masses. The modelling shows a surface pressure-independent part of gravity variations induced by mass redistribution of the atmosphere in the order of some μgal. This part can only be determined by using 3D atmospheric pressure data. It has been calculated for the Vienna Superconducting Gravimeter site.From this follows that the gravity reduction can be improved by applying the 3D atmospheric attraction model for analysing long-periodic tidal waves including the polar tide. The same improvement is expected for reduction of long-term absolute gravity measurements or comparison of gravity measurements at different seasonal times. By using 3D atmospheric pressure data, the gravity correction can be improved up to some μgal.     

Ukinrek Maars, Alaska, II. Deposits and formation of the 1977 craters

The initial phase of the eruption forming Ukinrek Maars during March and April 1977 were explosions from the site of West Maar. These were mainly phreatomagmatic and initially transitional to strombolian. Activity at West Maar ceased after three days upon the initiation of the East Maar. The crater quickly grew by strong phreatomagmatic explosions. During the first phases of phreatomagmatic activity at East Maar, large exotic blocks derived from a subsurface till were ejected. Ballistic studies indicate muzzle velocities for these blocks of 80–90 m s⁻¹.Phreatomagmatic explosions ejected both juvenile and non-juvenile material which formed a low rim of ejecta (< 26 mhigh) around the crater and a localized, coarse, wellsorted (σ_φ = 1−1.5) juvenile and lithic fall deposit. Other fine ash beds, interstratified with the coarse beds, are more poorly sorted (σ_φ = 2−3) and are interpreted as fallout of wet, cohesive ash from probably milder phases of activity in the crater. Minor base surge activity damaged trees and deposited fine ash, including layers plastered on vertical surfaces. Viscous basalt lava appeared in the center of the East Maar crater almost immediately and a lava dome gradually grew in the crater despite phreatomagmatic eruptions adjacent to it.The development of these maars appears to be mainly controlled by gradual collapse of crater and conduit walls, and blasting-out of the slumped debris by phreatomagmatic explosions when rising magma contacted groundwater beneath the regional water table and a local perched aquifer.Ballistic analysis on the ejected blocks indicates a maximum muzzle velocity of 100–150 m s^-1, values similar to those obtained from other ballistic studies on maar ejecta.     

Barriers in the science-policy-practice interface: Toward a knowledge-action-system in global environmental change research

This paper presents the results of a case study analysis from the knowledge domains of vulnerability and resilience. We analyzed 20 scientific assessments to provide empirical evidence for successes and failures in collaborative knowledge production, i.e., the joint creation of assessments reports by researchers and decision makers in policy and practice. It became clear that the latter typically use insufficiently the research-based knowledge available and researchers typically produce insufficiently knowledge that is directly usable. We found a number of functional, structural, and social factors inhibiting a joint problem identification and framing of knowledge producers and potential users: divergent objectives, needs, scope, and priorities; different institutional settings and standards, as well as differing cultural values, understanding, and mistrust. Combining understanding from multiple sources and providing mechanisms for linking solutions proposed by research with articulated needs and problems of practitioners would reduce the discrepancies in activities of different actors and result in more timely and context-appropriate solutions. In the concluding section we argue for a more locally embedded and socially contingent production of actionable knowledge and make suggestions about ways to enhance effectiveness of research-based knowledge.     

Evaluating along‐strike variation using thin‐bedded facies analysis,Upper Cretaceous Ferron Notom Delta,Utah

Thin‐bedded delta‐front and prodelta facies of the Upper Cretaceous Ferron Notom Delta Complex near Hanksville in southern Utah, USA, show significant along‐strike facies variability. Primary initiation processes that form these thin beds include surge‐type turbidity currents, hyperpycnal flows and storm surges. The relative proportion of sedimentary structures generated by each of these depositional processes/events has been calculated from a series of measured sedimentological sections within a single parasequence (PS6–1) which is exposed continuously along depositional strike. For each measured section, sedimentological data including grain size, lithology, bedding thickness, sedimentary structures and ichnological suites have been documented. Parasequence 6–1 shows a strong along‐strike variation with a wave‐dominated environment in the north, passing abruptly into a fluvial‐dominated area, then to an environment with varying degrees of fluvial and wave influence southward, and back to a wave‐dominated environment further to the south‐east. The lateral facies variations integrated with palaeocurrent data indicate that parasequence 6–1 is deposited as a storm‐dominated symmetrical delta with a large river‐dominated bayhead system linked to an updip fluvial feeder valley. This article indicates that it is practical to quantify the relative importance of depositional processes and determine the along‐strike variation within an ancient delta system using thin‐bedded facies analysis. The wide range of vertical stratification and grading sequences present in these event beds also allows construction of conceptual models of deposition from turbidity currents (i.e. surge‐type turbidity currents and hyperpycnal flows) and storm surges, and shows that there are significant interactions and linkages of these often paired processes.     

Encounters with an unearthly mudstone: Understanding the first mudstone found on Mars

The Sheepbed mudstone forms the base of the strata examined by the Curiosity rover in Gale Crater on Mars, and is the first bona fide mudstone known on another planet. From images and associated data, this contribution proposes a holistic interpretation of depositional regime, diagenesis and burial history. A lake basin probably received sediment pulses from alluvial fans. Bed cross‐sections show millimetre to centimetre‐scale layering due to distal pulses of fluvial sediment injections (fine‐grained hyperpycnites), fall‐out from river plumes, and some aeolian supply. Diagenetic features include mineralized synaeresis cracks and millimetre‐scale nodules, as well as stratiform cementation. Clay minerals were initially considered due to in situ alteration, but bulk rock chemistry and mineralogy suggests that sediments were derived from variably weathered source rocks that probably contained pre‐existing clay minerals. X‐ray diffraction analyses show contrasting clay mineralogy in closely spaced samples, consistent with at least partial detrital supply of clay minerals. A significant (ca 30 wt%) amorphous component is consistent with little post‐depositional alteration. Theoretical modelling of diagenetic reactions, as well as kinetic considerations, suggest that the bulk of diagenetic clay mineral formation occurred comparatively late in diagenesis. Diagenetic features (synaeresis cracks and nodules) were previously thought to reflect early diagenetic gas formation, but an alternative scenario of synaeresis crack formation via fabric collapse of flocculated clays appears more likely. The observed diagenetic features, such as solid nodules, hollow nodules, matrix cement and ‘raised ridges’ (synaeresis cracks) can be explained with progressive alteration of olivine/glass in conjunction with centrifugal and counter diffusion of reactive species. Anhydrite‐filled fractures in the Sheepbed mudstone occurred late in diagenesis when fluid pressures built up to exceed lithostatic pressure. Generating fluid overpressure by burial to facilitate hydraulic fracturing suggests a burial depth of at least 1000 m for the underlying strata that supplied these fluids.